Influence of Sulfur-Containing Diamino Acid Structure on Covalently Crosslinked Copolypeptide Hydrogels.

Biologically occurring non-canonical di-α-amino acids were converted into new di-N-carboxyanhydride (di-NCA) monomers in reasonable yields with high purity. Five different di-NCAs were separately copolymerized with tert-butyl-l-glutamate NCA to obtain covalently crosslinked copolypeptides capable of forming hydrogels with varying crosslinker density. Comparison of hydrogel properties with residue structure revealed that different di-α-amino acids were not equivalent in crosslink formation. Notably, l-cystine was found to produce significantly weaker hydrogels compared to l-homocystine, l-cystathionine, and l-lanthionine, suggesting that l-cystine may be a sub-optimal choice of di-α-amino acid for preparation of copolypeptide networks. The di-α-amino acid crosslinkers also provided different chemical stability, where disulfide crosslinks were readily degraded by reduction, and thioether crosslinks were stable against reduction. This difference in response may provide a means to fine tune the reduction sensitivity of polypeptide biomaterial networks

TAP reactor investigation of methane coupling over samarium oxide catalysts

The adsorption and reaction characteristics of a Ba/Sr/Sm2O3 catalyst for methane coupling has been investigated using the TAP (Temporal Analysis of Products) reactor system. Pulsed adsorption experiments using methane, oxygen and krypton at temperatures ranging from 17°C to 800°C show that the transient response of methane is similar to that of Kr and is either not adsorbed, or weakly adsorbed on the catalyst. By contrast, oxygen is strongly adsorbed at temperatures above 500°C which suggests incorporation into the lattice with possible formation of surface anions. Pump-probe experiments in which methane and oxygen are introduced over the catalyst were also performed to investigate the effect of lifetimes of suspected surface intermediates on the relative yields of ethane and ethene. It is shown that the relative yields of both species increase with increasing values of the pulse valve time delay between introduction of the oxygen and methane. An explanation of these results using current knowledge and reasonable speculation of the mechanism is provided

Homogeneous cooling of rough, dissipative particles: Theory and simulations

We investigate freely cooling systems of rough spheres in two and three dimensions. Simulations using an event driven algorithm are compared with results of an approximate kinetic theory, based on the assumption of a generalized homogeneous cooling state. For short times $t$, translational and rotational energy are found to change linearly with $t$. For large times both energies decay like $t^{-2}$ with a ratio independent of time, but not corresponding to equipartition. Good agreement is found between theory and simulations, as long as no clustering instability is observed. System parameters, i.e. density, particle size, and particle mass can be absorbed in a rescaled time, so that the decay of translational and rotational energy is solely determined by normal restitution and surface roughness.Comment: 10 pages, 10 eps-figure

The end-to-end testbed of the Optical Metrology System on-board LISA Pathfinder

LISA Pathfinder is a technology demonstration mission for the Laser Interferometer Space Antenna (LISA). The main experiment on-board LISA Pathfinder is the so-called LISA Technology Package (LTP) which has the aim to measure the differential acceleration between two free-falling test masses with an accuracy of 3x10^(-14) ms^(-2)/sqrt[Hz] between 1 mHz and 30 mHz. This measurement is performed interferometrically by the Optical Metrology System (OMS) on-board LISA Pathfinder. In this paper we present the development of an experimental end-to-end testbed of the entire OMS. It includes the interferometer and its sub-units, the interferometer back-end which is a phasemeter and the processing of the phasemeter output data. Furthermore, 3-axes piezo actuated mirrors are used instead of the free-falling test masses for the characterisation of the dynamic behaviour of the system and some parts of the Drag-free and Attitude Control System (DFACS) which controls the test masses and the satellite. The end-to-end testbed includes all parts of the LTP that can reasonably be tested on earth without free-falling test masses. At its present status it consists mainly of breadboard components. Some of those have already been replaced by Engineering Models of the LTP experiment. In the next steps, further Engineering Models and Flight Models will also be inserted in this testbed and tested against well characterised breadboard components. The presented testbed is an important reference for the unit tests and can also be used for validation of the on-board experiment during the mission

Controls on the temporal and spatial variability of soil moisture in a mountainous landscape: the signature of snow and complex terrain

The controls on the spatial distribution of soil moisture include static and dynamic variables. The superposition of static and dynamic controls can lead to different soil moisture patterns for a given catchment during wetting, draining, and drying periods. These relationships can be further complicated in snow-dominated mountain regions where soil water input by precipitation is largely dictated by the spatial variability of snow accumulation and melt. In this study, we assess controls on spatial and temporal soil moisture variability in a small (0.02 km<sup>2</sup>), snow-dominated, semi-arid catchment by evaluating spatial correlations between soil moisture and site characteristics through different hydrologic seasons. We assess the relative importance of snow with respect to other catchment properties on the spatial variability of soil moisture and track the temporal persistence of those controls. Spatial distribution of snow, distance from divide, soil texture, and soil depth exerted significant control on the spatial variability of moisture content throughout most of the hydrologic year. These relationships were strongest during the wettest period and degraded during the dry period. As the catchment cycled through wet and dry periods, the relative spatial variability of soil moisture tended to remain unchanged. We suggest that the static properties in complex terrain (slope, aspect, soils) impose first order controls on the spatial variability of snow and resulting soil moisture patterns, and that the interaction of dynamic (timing of water input) and static influences propagate that relative constant spatial variability through most of the hydrologic year. The results demonstrate that snow exerts significant influence on how water is retained within mid-elevation semi-arid catchments and suggest that reductions in annual snowpacks associated with changing climate regimes may strongly influence spatial and temporal soil moisture patterns and catchment physical and biological processes

Labour efficiency on-farm

End of project reportImprovements in milking efficiency have a greater influence than any other aspect of the dairy farmers work on overall farm labour inputs (Whipp, 1992). In order to facilitate the examination of milking process labour inputs, the milking process may be divided into the following three components: herding pre and post milking (transfer of cows to and from the milking parlour); milking (milking tasks / work routines within the parlour); and washing (washing of milking machine and yard). Meanwhile, within milking specifically, the number of cows milked per operator per hour is the best measure of both the performance of the operator and the milking installation (Clough, 1978). This is affected by the following three factors: the milking times of the cows, the number and arrangement of the milking units, and the operator’s work routine (Whipp, 1992). The addition of extra milking units will only increase milking performance if the operator has idle time during milking (Hansen, 1999)

Responding to Sea Level Rise: Does Short-Term Risk Reduction Inhibit Successful Long-Term Adaptation?

Most existing coastal climate-adaptation planning processes, and the research supporting them, tightly focus on how to use land use planning, policy tools, and infrastructure spending to reduce risks from rising seas and changing storm conditions. While central to community response to sea level rise, we argue that the exclusive nature of this focus biases against and delays decisions to take more discontinuous, yet proactive, actions to adapt—for example, relocation and aggressive individual protection investments. Public policies should anticipate real estate market responses to risk reduction to avoid large costs—social and financial—when and if sea level rise and other climate-related factors elevate the risks to such high levels that discontinuous responses become the least bad alternative

Metaplectic Ice

Spherical Whittaker functions on the metaplectic n-fold cover of GL(r+1) over a nonarchimedean local field containing n distinct n-th roots of unity may be expressed as the partition functions of statistical mechanical systems that are variants of the six-vertex model. If n=1 then in view of the Casselman-Shalika formula this fact is related to Tokuyama's deformation of the Weyl character formula. It is shown that various properties of these Whittaker functions may be expressed in terms of the commutativity of row transfer matrices for the system. Potentially these properties (which are already proved by other methods, but very nontrivial) are amenable to proof by the Yang-Baxter equation

Coefficient of restitution for elastic disks

We calculate the coefficient of restitution, $\epsilon$, starting from a microscopic model of elastic disks. The theory is shown to agree with the approach of Hertz in the quasistatic limit, but predicts inelastic collisions for finite relative velocities of two approaching disks. The velocity dependence of $\epsilon$ is calculated numerically for a wide range of velocities. The coefficient of restitution furthermore depends on the elastic constants of the material via Poisson's number. The elastic vibrations absorb kinetic energy more effectively for materials with low values of the shear modulus.Comment: 25 pages, 12 Postscript figures, LaTex2