Chemo-mechanical couplings in compacted argillite submitted to high-pH environment

AbstractIn the French concept of deep nuclear wastes repository, the galleries should be backfilled with excavated argillite after the site exploitation period. After several thousands of years, the degradation of the concrete lining of the galleries will generate alkaline fluid (pH > 12) that will diffuse through the backfill. The objective of the paper is to describe the influence of such solute diffusion on the microstructure and the mechanical behavior of compacted argillite. Saturated-portlandite water was circulated through compacted samples for 3, 6 and 12months at 20 °C or 60 °C, respectively. The microstructures before and after fluid circulation were determined with mercury intrusion porosimetry. Since it was planned to introduce additives (bentonite or lime) in the remoulded argillite to backfill the deep galleries, such mixtures were also studied. The results show that the influence of the alkaline fluid on the properties of the argillite is a function of the nature of the additive. The pure argillite undergoes slight modifications that can be related to a limited dissolution of its clayey particles. Conversely, intense alteration of the bentonite-argillite mixture was observed. Lime addition improves the mechanical characteristics of the argillite through the precipitation of cementitious compounds

An effective constitutive model for lime treated soils

This is the author accepted manuscript. The final version is available from Elsevier via the DOI in this record.The effect of lime on the yield stress, and more generally the presence of structure in the soil, is usually not accounted for in the design of geotechnical structures. As a result the potential of lime treatment or of a structured soil has not been fully exploited. This paper presents a new formulation to account for the effect of structure on the mechanical behaviour for structured soils. A constitutive model is proposed in the framework of the Modified Cam Clay model to describe the behaviour of lime treated soils. The new formulation introduces a limited number of additional parameters, all of which have a physical meaning and can be obtained from an isotropic compression test. Due to similarity in behaviour of lime treated soils and naturally structured soils, the formulation can be applied to both types of soil. It is shown that the proposed model can successfully reproduce the main features of both structured soils such as maximum rate of dilation at softening and degradation at yield. The model can be applied for any structured material regardless of the origin of cementation

Mechanical Properties of Calcareous Fly Ash Stabilised Soil

Construction of any type of structure on clayey ground could be problematic due to the high swelling potential and/or low strength characteristics of the soil. This can lead to low stability or differential settlement of the ground. Many soil stabilization techniques have been proposed to prevent the uneven settlement and failure of the soil. Stabilization of soil with class C fly ash offers many advantages such as improving engineering caracteristics, being cost-effective and being environmentally friendly. Class C fly ash chemically reacts with clay which results in a more durable and stronger soil. It has been shown by various researchers that fly ash-stabilized soil is typically stiff and strong even though there is no available standard or guidelines for the use of fly ash in construction industry. This paper presents the results from a program of experimental research on stabilization of a fine-grained soil with fly ash. Laboratory experiments, including Atterberg limits, compaction, uniaxial, and consolidation tests, were conducted on samples of a clay soil with different percentages of fly ash. The results show that adding fly ash decreased the plasticity index, increased compressive strength, and decreased the swelling and compressibility index. The maximum dry density increased and optimum moisture content decreased with addition of over 5 % fly ash by dry weight of the soil.Turkish governmentEuropean Union Horizon 202

Thermo-mechanical behaviour of a compacted swelling clay

Compacted unsaturated swelling clay is often considered as a possible buffer material for deep nuclear waste disposal. An isotropic cell permitting simultaneous control of suction, temperature and pressure was used to study the thermo-mechanical behaviour of this clay. Tests were performed at total suctions ranging from 9 to 110 MPa, temperature from 25 to 80 degrees C, isotropic pressure from 0.1 to 60 MPa. It was observed that heating at constant suction and pressure induces either swelling or contraction. The results from compression tests at constant suction and temperature evidenced that at lower suction, the yield pressure was lower, the elastic compressibility parameter and the plastic compressibility parameter were higher. On the other hand, at a similar suction, the yield pressure was slightly influenced by the temperature; and the compressibility parameters were insensitive to temperature changes. The thermal hardening phenomenon was equally evidenced by following a thermo-mechanical path of loading-heating-cooling-reloading

Impact of soil treatment on internal erosion resistance and hydro-mechanical characteristics of a silty soil

The aim of this paper is to examine the impact of soil treatment on the internal erosion and the hydro-mechanical characteristics of a silty soil. The study is focused on the treatment by kaolinite, bentonite, lime and cement, with different amounts and curing periods. A new enhanced Hole Erosion Test was developed especially to study the internal erosion of treated soils using high hydraulic shear stresses. The use of clayey products decreases both the hydraulic conductivity and the coefficient of soil erosion without changing the mechanical behavior. Lime and cement treatment induce a significant improvement of both internal erosion resistance and strength, and also keep the same level of hydraulic conductivity, and may even decrease it in some cases. The magnitude of these modifications is related to the nature and amount of the treatment product, and the curing period. The cross relationships between the hydraulic conductivity, the unconfined compression strength and the internal erosion were also assessed

Suction induced effects on the fabric of a structured soil

International audienceThis paper presents the mathematical modelling of the modification of the pore space geometry of a structured soil subjected to suction increase. Structured soil concepts are first introduced considering different fabric units, such as aggregates and fissures. The numerical modelling of the structural evolution is based on experimental test results in which the evolution of the structure of the samples subjected to different suctions is determined using the mercury intrusion porosimetry technique. From this information, the macro and micropore volume evolutions are determined. The results show that drying produces a reduction in the soil total porosity which mainly corresponds to a reduction of the macropore volume. Associated with this phenomenon, an increase in micropore volume is also observed. The proposed model divides pore size distribution into three pore classes (micropores, macropores and non-affected areas). Using the concept of a suction-influenced domain, the proposed model is able to reproduce the main observed fabric evolution between the saturated and dry states

In Search of Possible Associations between Planetary Nebulae and Open Clusters

We consider the possibility of cluster membership for 13 planetary nebulae that are located in close proximity to open clusters lying in their lines of sight. The short lifetimes and low sample size of intermediate-mass planetary nebulae with respect to nearby open clusters conspire to reduce the probability of observing a true association. Not surprisingly, line of sight coincidences almost certainly exist for 7 of the 13 cases considered. Additional studies are advocated, however, for 6 planetary nebula/open cluster coincidences in which a physical association is not excluded by the available evidence, namely M 1-80/Berkeley 57, NGC 2438/NGC 2437, NGC 2452/NGC 2453, VBRC 2 & NGC 2899/IC 2488, and HeFa 1/NGC 6067. A number of additional potential associations between planetary nebulae and open clusters is tabulated for reference purposes. It is noteworthy that the strongest cases involve planetary nebulae lying in cluster coronae, a feature also found for short-period cluster Cepheids, which are themselves potential progenitors of planetary nebulae.Comment: Accepted for publication in PASP (December 2007

TEM analysis of apatite surface layers observed on zinc based glass polyalkenoate cements

peer-reviewedGlass polyalkenoate cements (GPCs) are acid base cements formed by the reaction of an aqueous solution of polyalkenoic acid, usually polyacrylic acid (PAA) with an acid degradable aluminosilicate glass. The result of the reaction is cement consisting of reacted and unreacted glass particles embedded in a polysalt matrix. In addition to these conventional GPCs, aluminium free glass polyalkenoate cements based on zinc silicate glasses (Zn-GPCs) exhibit significant potential as bone cements for several reasons. Primarily, they are formulated without the inclusion of aluminium (Al) [1] in the glass phase and thus eliminate clinical complications arising from the release of the Al3+ ion from the cement in vivo. Such complications have, in the past, included aluminium induced encephalopathy [2-5] and defective mineralisation of cancellous bone [6]. Secondly, Zn-GPCs set without a significant evolution of heat, when compared with commercial bone cements such as Spineplex ® (Stryker, Limerick, Ireland). Finally, these materials can be tailored to release clinically beneficial ions into surrounding tissues [7]. In addition to Zn, these cements have been synthesized to contain strontium (Sr) [8, 9]. Both Sr and Zn inhibit osteoclastic turnover and promote osteoblastic turnover, resulting in increased bone strength and decreased fracture risk [10-14].Acceptedpeer-reviewe

Bright Planetary Nebulae and their Progenitors in Galaxies Without Star Formation

We present chemical abundances for planetary nebulae in M32, NGC 185, and NGC 205 based upon spectroscopy obtained at the Canada-France-Hawaii Telescope using the Multi-Object Spectrograph. From these and similar data compiled from the literature for other Local Group galaxies, we consider the origin and evolution of the stellar progenitors of bright planetary nebulae in galaxies where star formation ceased long ago. The ratio of neon to oxygen abundances in bright planetary nebulae is either identical to that measured in the interstellar medium of star-forming dwarf galaxies or at most changed by a few percent, indicating that neither abundance is significantly altered as a result of the evolution of their stellar progenitors. Several planetary nebulae appear to have dredged up oxygen, but these are the exception, not the rule. The progenitors of bright planetary nebulae typically enhance their original helium abundances by less than 50%. In contrast, nitrogen enhancements can reach factors of 100. However, nitrogen often shows little or no enhancement, suggesting that nitrogen enrichment is a random process. The helium, oxygen, and neon abundances argue that the typical bright planetary nebulae in all of the galaxies considered here are the progeny of stars with initial masses of approximately 1.5 Msun or less, based upon the nucleosynthesis predictions of current theoretical models. These models, however, are unable to explain the nitrogen enrichment or its scatter. Similar conclusions hold for the bright planetary nebulae in galaxies with ongoing star formation. Thus, though composition varies significantly, there is unity in the sense that the progenitors of typical bright planetary nebulae appear to have undergone similar physical processes. (Abridged)Comment: accepted for publication in the Astrophysical Journa