29,482 research outputs found
Testing a dissipative kinetic k-essence model
In this work, we present a study of a purely kinetic k-essence model,
characterized basically by a parameter in presence of a bulk
dissipative term, whose relationship between viscous pressure and energy
density of the background follows a polytropic type law , where , in principle, is a parameter without
restrictions. Analytical solutions for the energy density of the k-essence
field are found in two specific cases: and
, and then we show that these solutions posses the
same functional form than the non-viscous counterpart. Finally, both approach
are contrasted with observational data from type Ia supernova, and the most
recent Hubble parameter measurements, and therefore, the best values for the
parameters of the theory are founds.Comment: 9 pages, 5 figures, accepted in EPJ
Electron Transfer Reaction Through an Adsorbed Layer
We consider electron transfer from a redox to an electrode through and
adsorbed intermediate. The formalism is developed to cover all regimes of
coverage factor, from lone adsorbate to monolayer regime. The randomness in the
distribution of adsorbates is handled using coherent potential approximation.
We give current-overpotential profile for all coverage regimes. We explictly
analyse the low and high coverage regimes by supplementing with DOS profile for
adsorbate in both weakly coupled and strongly coupled sector. The prominence of
bonding and anti-bonding states in the strongly coupled adsorbates at low
coverage gives rise to saddle point behaviour in current-overpotential profile.
We were able to recover the marcus inverted region at low coverage and the
traditional direct electron transfer behaviour at high coverage
Vortex Softening: Origin of the second peak effect in BiSrCaCuO
Transverse ac permeability measurements in BiSrCaCuO single crystals at low fields and temperatures in a vortex configuration
free of external forces show that the decrease of the critical current as
measured by magnetization loops at the second peak effect is an artifact due to
creep. On the other hand, the increase of critical current at the second peak
is due to a genuine softening of the tilting elastic properties of vortices in
the individual pinning regime that precedes the transition to a disorder state.Comment: 4 pages, 5 figures, RevTex, two column versio
Complexation of oppositely charged polyelectrolytes: effect of ion pair formation
Complexation in symmetric solutions of oppositely charged polyelectrolytes is
studied theoretically. We include polyion crosslinking due to formation of
thermoreversible ionic pairs. The electrostatic free energy is calculated
within the Random Phase Approximation taking into account the structure of
thermoreversible polyion clusters. The degree of ion association is obtained
self-consistently from a modified law of mass action, which includes long-range
electrostatic contributions. We analyze the relative importance of the three
complexation driving forces: long-range electrostatics, ion association and van
der Waals attraction. The conditions on the parameters of the system that
ensure stability of the complex with addition of salt are determined
- …