232 research outputs found
X-Ray Diffuse Scattering Study on Ionic-Pair Displacement Correlations in Relaxor Lead Magnesium Niobate
Ionic-pair equal-time displacement correlations in relaxor lead magnesium
niobate, , have been investigated at room
temperature in terms of an x-ray diffuse scattering technique. Functions of the
distinct correlations have been determined quantitatively. The results show the
significantly strong rhombohedral-polar correlations regarding Pb-O, Mg/Nb-O,
and O-O' pairs. Their spatial distribution forms an ellipse or a sphere with
the radii of 30-80. This observation of local structure in the system
proves precursory presence of the polar microregions in the paraelectric state
which leads to the dielectric dispersion.Comment: 11 pages, 3 figure
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Coherent coupling in ferroelectric superlattices
The phase transition and dielectric behavior of ferroelectric multilayers have been discussed. The coherent interaction between ultra-thin layers can be significantly strong, resulting in a broad diffuse phase transition. The thicknesses of layers and their spatial distributions hold the keys of enhancing dielectric properties in a broad temperature range
Coexistence of the Critical Slowing Down and Glassy Freezing in Relaxor Ferroelectrics
We have developed a dynamical model for the dielectric response in relaxor
ferroelectrics which explicitly takes into account the coexistence of the
critical slowing down and glassy freezing. The application of the model to the
experiment in PMN allowed for the reconstruction of the nonequilibrium spin
glass state order parameter and its comparison with the results of recent NMR
experiment (Blinc et al., Phys. Rev. Lett. 83, No. 2 (1999)). It is shown that
the degree of the local freezing is rather small even at temperatures where the
field-cooled permittivity exceeds the frequency dependent permittivity by an
order of magnitude. This observation indicates the significant role of the
critical slowing down (accompanying the glass freezing) in the system dynamics.
Also the theory predicts an important interrelationship between the frequency
dependent permittivity and the zero-field-cooled permittivity, which proved to
be consistent with the experiment in PMN (A. Levstik et. al., Phys. Rev. B 57,
11204 (1998))
Diffuse Neutron Scattering Study of a Disordered Complex Perovskite Pb(Zn1/3Nb2/3)O3 Crystal
Diffuse scattering around the (110) reciprocal lattice point has been
investigated by elastic neutron scattering in the paraelectric and the relaxor
phases of the disordered complex perovskite crystal-Pb(Zn1/3Nb2/3)O3(PZN). The
appearance of a diffuse intensity peak indicates the formation of polar
nanoregions at temperature T*, approximately 40K above Tc=413K. The analysis of
this diffuse scattering indicates that these regions are in the shape of
ellipsoids, more extended in the direction than in the direction.
The quantitative analysis provides an estimate of the correlation length, \xi,
or size of the regions and shows that \xi ~1.2\xi , consistent with
the primary or dominant displacement of Pb leading to the low temperature
rhombohedral phase. Both the appearance of the polar regions at T*and the
structural transition at Tc are marked by kinks in the \xi curve but not
in the \xi one, also indicating that the primary changes take place in a
direction at both temperatures.Comment: REVTeX file. 4 pages, 3 figures embedded, New version after referee
cond-mat/010605
Role of MALDI-MSI in combination with 3D tissue models for early stage efficacy and safety testing of drugs and toxicants
Introduction: Three-dimensional (3D) cell cultures have become increasingly important materials to investigate biological processes and drug efficacy and toxicity. The ability of 3D cultures to mimic the physiology of primary tissues and organs in the human body enables further insight into cellular behavior and is hence highly desirable in early-stage drug development. Analyzing the spatial distribution of drug compounds and endogenous molecules provides an insight into the efficacy of a drug whilst simultaneously giving information on biological responses. Areas Covered: In this review we will examine the main 3D cell culture systems employed and applications, which describe their integration with mass spectrometry imaging (MSI). Expert Opinion: MSI is a powerful technique that can map a vast range of molecules simultaneously in tissues without the addition of labels that can provide insights into the efficacy and safety of a new drug. The combination of MSI and 3D cell cultures has emerged as a promising tool in early-stage drug analysis. However, the most common administration route for pharmaceutical drugs is via oral delivery. The use of MSI in combination with models of the GI tract is an area that has been little explored to date, the reasons for this are discussed
Disorder and relaxation mode in the lattice dynamics of PbMgNbO relaxor ferroelectric
The low-energy part of vibration spectrum in PbMgNbO
relaxor ferroelectric was studied by inelastic neutron scattering. We observed
the coexistence of a resolution-limited central peak with strong quasielastic
scattering. The line-width of the quasielastic component follows a
dependence. We find that is temperature-dependent.
The relaxation time follows the Arrhenius law well. The presence of a
relaxation mode associated with quasi-elastic scattering in PMN indicates that
order-disorder behaviour plays an important r\^ole in the dynamics of diffuse
phase transitions
Direct evidence of soft mode behavior near the Burns' temperature in PbMgNbO (PMN) relaxor ferroectric
Inelastic neutron scattering measurements of the relaxor ferroelectric
PbMgNbO (PMN) in the temperature range
490~KT880~K directly observe the soft mode (SM) associated with the
Curie-Weiss behavior of the dielectric constant (T). The results
are treated within the framework of the coupled SM and transverse optic (TO1)
mode and the temperature dependence of the SM frequency at q=0.075 a* is
determined. The parameters of the SM are consistent with the earlier estimates
and the frequency exhibits a minimum near the Burns temperature (
650K)Comment: 6 figure
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