28 research outputs found

    Quaternion Gravi-Electromagnetism

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    Defining the generalized charge, potential, current and generalized fields as complex quantities where real and imaginary parts represent gravitation and electromagnetism respectively, corresponding field equation, equation of motion and other quantum equations are derived in manifestly covariant manner. It has been shown that the field equations are invariant under Lorentz as well as duality transformations. It has been shown that the quaternionic formulation presented here remains invariant under quaternion transformations.Comment: Key Words: Quaternion, dyons, gravito-dyons, gravi-electromagnetism. PACS No.: 04.90. +e ; 14.80. H

    Galactans of Gracilaria pudumadamensis

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    Photosynthesis in Algae II. Green algae with special reference to Dunaliella spp. and Tetraselmis spp.

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    The photosynthetic fixation of 14CO2 was studied in 10 species of chlorophycean algae and in 9 isolates of prasinophycean algae of the genus Tetraselmis.Green seaweeds had photosynthetic rates of 2.2 to 4.4\u2002mg CO2\u2002 7\u2002h 121\u2002 7\u2002g 121, accumulated starch, glucose, fructose, and sucrose, and excreted very little recent photosynthate.Dunaliella spp. were distinguished by a high level of organic excretion (to 29.2% of the 14C fixed in 2 hours), the production of glycerol and hydrogen sulfide, and the absence of dimethyl-\u3b2-propiothetin.Tetraselmis spp. excreted relatively small amounts of photosynthate in 2 hours, and produced mannitol and dimethyl-\u3b2-propiothetin but not hydrogen sulfide.Peer reviewed: YesNRC publication: Ye

    Lipids isolated from the cultivated red alga Chondrus crispus inhibit nitric oxide production

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    A MeOH extract of cultivated Chondrus crispus showed dose-dependent nitric oxide (NO) inhibition of lipopolysaccharide-induced NO production in macrophage RAW264.7 cells. NO inhibition-guided fractionation of the extract led to identification of eicosapentaenoic acid (EPA, 1), arachidonic acid (AA, 2), lutein (3), and eight galactolipids as active components. Based on spectral analysis, the isolated galactolipids were identified as (2S)-1,2-bis-O-eicosapentaenoyl-3-O-\u3b2-d-galactopyranosylglycerol (4), (2S)-1-O-eicosapentaenoyl-2-O-arachidonoyl-3-O-\u3b2-d-galactopyranosylglycerol (5), (2S)-1-O-(6Z,9Z,12Z,15Z-octadecatetranoyl)-2-O-palmitoyl-3-O-\u3b2-d-galactopyranosylglycerol (6), (2S)-1-O-eicosapentaenoyl-2-O-palmitoyl-3-O-\u3b2-d-galactopyranosylglycerol (7), (2S)-1,2-bis-O-arachidonoyl-3-O-\u3b2-d-galactopyranosylglycerol (8), (2S)-1-O-arachidonoyl-2-O-palmitoyl-3-O-\u3b2-d-galactopyranosylglycerol (9), (2S)-1-O-eicosapentaenoyl-2-O-palmitoyl-3-O-(\u3b2-d-galactopyranosyl-6-1\u3b1-d-galactopyranosyl)-glycerol (10), and (2S)-1-O-arachidonoyl-2-O-palmitoyl-3-O-(\u3b2-d-galactopyranosyl-6-1\u3b1-d-galactopyranosyl)-glycerol (11). All the isolated compounds showed significant NO inhibitory activity. This is the first report of the isolation and identification of individual galactolipids from C. crispus. Moreover, (2S)-1,2-bis-O-arachidonoyl -3-O-\u3b2-d-galactopyranosylglycerol (8) is a novel compound.Peer reviewed: YesNRC publication: Ye

    Polar lipids from the marine macroalga Palmaria palmata inhibit lipopolysaccharide-induced nitric oxide production in RAW264.7 macrophage cells

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    The EtOAc soluble fraction of a MeOH/CHCl3 extract of Palmaria palmata showed strong nitric oxide (NO) inhibitory activity against lipopolysaccharide (LPS)-induced NO production in murine RAW264.7 cells. NO inhibition-guided isolation led to identification of three new polar lipids including a sulfoquinovosyl diacylglycerol (SQDG) (2S)-1-O-eicosapentaenoyl-2-O- myristoyl-3-O-(6-sulfo-\u3b1-d-quinovopyranosyl)-glycerol (1) and two phosphatidylglycerols, 1-O-eicosapentaenoyl-2-O-trans-3-hexadecenoyl-3-phospho- (1\u2032-glycerol)-glycerol (3) and 1-O-eicosapentaenoyl-2-O-palmitoyl-3- phospho-(1\u2032-glycerol)-glycerol (4) from the EtOAc fraction. Seven known lipids were also isolated including a SQDG (2), a phospholipid (5) and five galactolipids (6-10). Structures of the isolated lipids were elucidated by spectral analyses. The isolated SQDGs, phosphatidylglycerols and phospholipid possessed strong and dose-dependent NO inhibitory activity compared to N G-methyl-l-arginine acetate salt (l-NMMA), a well-known NO inhibitor used as a positive control. Further study suggested that these polar lipids suppressed NO production through down-regulation of inducible nitric oxide synthase (iNOS).Peer reviewed: YesNRC publication: Ye
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