62 research outputs found

    Synthesis of polypeptide based rod-coil block copolymers

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    A bifunctional initiator was synthesized and used for a sequence of a nickel initiated polymerization of -benzyl-L-glutamate-N-carboxy anhydride and atom transfer radical polymerization of methyl methacrylate yielding a rod–coil block copolymer

    Synthesis of rod-coil block copolymers using two controlled polymerization techniques

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    A double-headed initiator was synthesized yielding two functional groups for the initiation of the nickel mediated ring-opening polymerization of -benzyl-L-glutamate-N-carboxyanhydride and controlled radical polymerization of vinyl monomers via ATRP or NMP. Well-defined block copolymers combining polypeptides and synthetic polymers were obtained
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