Vanadium catalyzed oxidation with hydrogen peroxide

Vanadium peroxides are known as very effective oxidants af different organic and inorganic substrates. In this short account reactivity, structural and mechanistic studies concerning the behaviour of peroxovanadates toward a number of different substrates are collected. Homogeneous and two-phases systems are presented, in addition, interesting synthetic results obtained with the use of ionic liquids as reaction media are also presented

Another integrable case in the Lorenz model

A scaling invariance in the Lorenz model allows one to consider the usually discarded case sigma=0. We integrate it with the third Painlev\'e function.Comment: 3 pages, no figure, to appear in J. Phys.

Vanadium and molybdenum peroxides: synthesis and catalytic activity in oxidation reactions

Catalysis by transition metal ions in oxidation reactions with hydrogen peroxide and alkyl hydroperoxides is a leading topic in the pursuit of more sustainable and selective processes, to obtain compounds with high added value. The most recent achievements concerning the synthesis and characterization, as well as the key aspects of reactivity, of V(v) and Mo(vi) peroxo complexes have been collected here

Towards a public analysis database for LHC new physics searches using MadAnalysis 5

We present the implementation, in the MadAnalysis 5 framework, of several ATLAS and CMS searches for supersymmetry in data recorded during the first run of the LHC. We provide extensive details on the validation of our implementations and propose to create a public analysis database within this framework.Comment: 20 pages, 15 figures, 5 recast codes; version accepted by EPJC (Dec 22, 2014) including a new section with guidelines for the experimental collaborations as well as for potential contributors to the PAD; complementary information can be found at http://madanalysis.irmp.ucl.ac.be/wiki/PhysicsAnalysisDatabas

Temporal discrimination: Mechanisms and relevance to adult-onset dystonia

Temporal discrimination is the ability to determine that two sequential sensory stimuli are separated in time. For any individual, the temporal discrimination threshold (TDT) is the minimum interval at which paired sequential stimuli are perceived as being asynchronous; this can be assessed, with high test-retest and inter-rater reliability, using a simple psychophysical test. Temporal discrimination is disordered in a number of basal ganglia diseases including adult-onset dystonia, of which the two most common phenotypes are cervical dystonia and blepharospasm. The causes of adult-onset focal dystonia are unknown; genetic, epigenetic, and environmental factors are relevant. Abnormal TDTs in adult-onset dystonia are associated with structural and neurophysiological changes considered to reflect defective inhibitory interneuronal processing within a network which includes the superior colliculus, basal ganglia, and primary somatosensory cortex. It is hypothesized that abnormal temporal discrimination is a mediational endophenotype and, when present in unaffected relatives of patients with adult-onset dystonia, indicates non-manifesting gene carriage. Using the mediational endophenotype concept, etiological factors in adult-onset dystonia may be examined including (i) the role of environmental exposures in disease penetrance and expression; (ii) sexual dimorphism in sex ratios at age of onset; (iii) the pathogenesis of non-motor symptoms of adult-onset dystonia; and (iv) subcortical mechanisms in disease pathogenesis

Disordered Regimes of the one-dimensional complex Ginzburg-Landau equation

I review recent work on the ``phase diagram'' of the one-dimensional complex Ginzburg-Landau equation for system sizes at which chaos is extensive. Particular attention is paid to a detailed description of the spatiotemporally disordered regimes encountered. The nature of the transition lines separating these phases is discussed, and preliminary results are presented which aim at evaluating the phase diagram in the infinite-size, infinite-time, thermodynamic limit.Comment: 14 pages, LaTeX, 9 figures available by anonymous ftp to amoco.saclay.cea.fr in directory pub/chate, or by requesting them to [email protected]

A sustainable two-phase procedure for V-catalyzed toluene oxidative bromination with H2O2–KBr

A sustainable V(V) and Mo(VI) catalysed two-phase procedure for bromination of toluene under quite mild conditions is proposed; H2O2 is the primary oxidant and KBr is the bromine source; metal precursors are commercially available salts. The reaction is efficient without any additional solvent. By using PhCH3 as a solvent/substrate good yields, together with interesting selectivity toward the formation of PhCH2Br, are obtained with both metal ions. Recycling of the catalytic phase is also possible. Useful information on the V-peroxido chemistry was obtained

Epidemiology and Impact of Abdominal Oblique Injuries in Major and Minor League Baseball.

BACKGROUND: Oblique injuries are known to be a common cause of time out of play for professional baseball players, and prior work has suggested that injury rates may be on the rise in Major League Baseball (MLB). PURPOSE: To better understand the current incidence of oblique injuries, determine their impact based on time out of play, and to identify common injury patterns that may guide future injury prevention programs. STUDY DESIGN: Descriptive epidemiological study. METHODS: Using the MLB Health and Injury Tracking System, all oblique injuries that resulted in time out of play in MLB and Minor League Baseball (MiLB) during the 2011 to 2015 seasons were identified. Player demographics such as age, position/role, and handedness were included. Injury-specific factors analyzed included the following: date of injury, timing during season, days missed, mechanism, side, treatment, and reinjury status. RESULTS: A total of 996 oblique injuries occurred in 259 (26%) MLB and 737 (74%) MiLB players. Although the injury rate was steady in MiLB, the MLB injury rate declined (P = .037). A total of 22,064 days were missed at a mean rate of 4413 days per season and 22.2 days per injury. The majority of these occurred during batting (n = 455, 46%) or pitching (n = 348, 35%), with pitchers losing 5 days more per injury than batters (P \u3c .001). The leading side was injured in 77% of cases and took 5 days longer to recover from than trailing side injuries (P = .009). Seventy-nine (7.9%) players received either a corticosteroid or platelet-rich plasma injection, and the mean recovery time was 11 days longer compared with those who did not receive an injection (P \u3c .001). CONCLUSION: Although the rate of abdominal oblique injuries is on the decline in MLB, this is not the case for MiLB, and these injuries continue to represent a significant source of time out of play in professional baseball. The vast majority of injuries occur on the lead side, and these injuries result in the greatest amount time out of play. The benefit of injections for the treatment of oblique injuries remains unknown

Symmetry reductions of a particular set of equations of associativity in twodimensional topological field theory

The WDVV equations of associativity arising in twodimensional topological field theory can be represented, in the simplest nontrivial case, by a single third order equation of the Monge-Ampe`re type. By investigating its Lie point symmetries, we reduce it to various nonlinear ordinary differential equations, and we obtain several new explicit solutions.Comment: 10 pages, Latex, to appear in J. Phys. A: Math. Gen. 200

Tailored functionalization of natural phenols to improve biological activity

Phenols are widespread in nature, being the major components of several plants and essential oils. Natural phenols' anti-microbial, anti-bacterial, anti-oxidant, pharmacological and nutritional properties are, nowadays, well established. Hence, given their peculiar biological role, numerous studies are currently ongoing to overcome their limitations, as well as to enhance their activity. In this review, the functionalization of selected natural phenols is critically examined, mainly highlighting their improved bioactivity after the proper chemical transformations. In particular, functionalization of the most abundant naturally occurring monophenols, diphenols, lipidic phenols, phenolic acids, polyphenols and curcumin derivatives is explored