1,554 research outputs found

    Stress relaxation after low and high-rate deformation of polyurethanes

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    Polymers possess a wide range of mechanical behaviours depending upon the temperature and loading rate. An often-overlooked aspect is relaxation, important because it acts over a wide range of time periods and begins as soon as the polymer is loaded. In the research presented here, the relaxation behaviour of two polyurethanes (PUs) following deformation was investigated at low-rate, 10-3 s-1, and dynamic, 103 s- 1, loading rates, with the former exploring temperatures from 20 °C to - 60 °C. These are compared to a predictive Prony series model calibrated using mastercurves produced by applying time-temperature superposition to data obtained using a dynamic mechanical analysis machine. For relaxation after dynamic loading, a recently proposed analysis was used to account for the movement of the bars during the relaxation. The model was able to predict the stress-time response after low-rate deformation to strains of 2 %, at all temperatures. As the strains increased, irrecoverable deformation was observed and the model became less accurate. In the dynamic experiments, the model accurately predicted the early stages of relaxation for both PUs but deviated later on. A modification to the model was suggested to account for these observations. Further characterisation of the mechanical response under large strain compressive loading is also reported

    The Grenadian Crisis and the Caribbean Left

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    SUMMARY Prior to October 1983 ‘popular forces’ had established a hitherto unmatched degree of hegemony throughout the Caribbean region. The self?destruction of the Grenadian revolution opened the way to the restoration of colonial or neo colonial principles under US hegemony. The article examines the importance of democracy in the Caribbean political tradition, and the responsibility of the New Jewel Movement's leadership, and of the Caribbean intelligentsia who supported them, for ignoring this. RESUMEN La crisis de Grenada y la izquierda caribeña Con anterioridad a octubre de 1983, las ‘fuerzas populares’ establecieron un grado de hegemonĂ­a hasta entonces inĂ©dito en la regiĂłn caribeña. La autodestrucciĂłn de la revoluciĂłn de Grenada abriĂł el camino para la restauraciĂłn de los principios coloniales o neocoloniales bajo la hegemonĂ­a estadounidense. El artĂ­culo examina la importancia de la democracia en la tradiciĂłn polĂ­tica del Caribe y la responsabilidad que le cabe a la lideranza del Movimiento New Jewel, asĂ­ como a la intelectualidad caribeña que la apoyĂł, por haberlo ignorado. SOMMAIRE La crise de la Grenade et la gauche Antillaise Avant Octobre 1983, les ‘forces populaires’ ont Ă©tabli une hĂ©gĂ©monie Ă  un degrĂ© jusqu Ă  present inĂ©galĂ© dans la rĂ©gion des Antilles. L'autodestruction de la rĂ©volution grenadine a ouvert la route Ă  la restauration des principes coloniaux et nĂ©o?coloniaux sous l'hĂ©gĂ©monie amĂ©ricaine. L'article examine l'importance de la DĂ©mocratie dans la tradition politique des CaraĂŻbes et la responsabilitĂ© de la direction du mouvement du ‘Nouveau Bijou’ et de l'Intelligentsia des CaraĂŻbes qui la supporte et veut ignorer cette premiĂšre donnĂ©e

    Influence of surface preparation and polymer backing properties on the quasi-static and impact response of ceramic faced 1d armour systems

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    Ballistic impact is a highly complex environment, the understanding of which is compounded by the advanced materials used for ceramic-polymer composite armours. In this study, the influence of surface preparation and polymer backing properties on the energy absorptive capabilities and ballistic performance of simplified model armours was approached via a methodical investigation using simplified materials and geometries. Quasi-1D (beam) specimens consisting of polyurethane-backed alumina were loaded under three-point bend quasi-statically and at impact speeds. The specimen geometries allowed for the fracture pathways to be observed. To produce the specimens, two polyurethanes with different glass transition temperatures were cured onto alumina strips, eliminating the requirement for a dedicated adhesive and thus simplifying the interfacial dynamics. Further modifications were made by applying a primer surface treatment, by using unbonded polyurethane and adhered polyurethane, and by replacing the polyurethane with glass-reinforced polycarbonate. The beam specimens were loaded quasi-statically at 0.05 mm s-1 at ambient and sub-ambient temperatures, and at 50-300 m s-1 at ambient temperatures. The quasi-static specimens were found to fail by one of two failure modes with approximately a 3x energy absorption difference; the failure was highly dependent upon the interface and polymer characteristics. Under impact, a significant proportion of the energy absorption was provided by the kinetic energy of the fragments. Although, the polymer backing and interfacial properties were found to influence fracture paths during loading. FEA simulations were used to model the behaviours using characterisation data from a previous study; these were found to predict the experimental response well
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