Are UK E-waste recycling facilities a source of environmental contamination and occupational exposure to brominated flame retardants?

Investigations into the impacts of regulated electrical and electronic waste (e-waste) recycling activities on urban environments in Europe remain rather scarce. In this study, dust samples taken both inside and outside of five UK e-waste recycling facilities were analysed for concentrations of polybrominated diphenyl ethers (PBDEs), novel brominated flame retardants (NBFRs), and hexabromocyclododecane (HBCDD). Average concentrations of ∑BFRs in dust inside and outside UK e-waste recycling facilities were 12,000 ng/g and 180 ng/g, with median concentrations of 7500 ng/g and 85 ng/g, respectively. BDE-209 and decabromodiphenyl ethane (DBDPE) were the most abundant BFRs in both indoor and kerb dust, making a combined contribution to ∑BFRs of ~90 % on average. While four out of the five studied e-waste facilities showed a lack of significant impact on BFR contamination in surrounding environment, one of the studied e-waste recycling facilities was identified as a likely source of BFR contamination to UK urban environments, with industrial activities as another potential source of NBFRs. Occupational exposure of UK e-waste recycling workers to BFRs via dust ingestion was generally lower than that estimated for e-waste recyclers from other countries, but was comparable to BFR exposure via dust ingestion of UK office workers. Our estimates suggested that health burdens posed by dust ingestion of BFRs were minimal for UK e-waste recycling workers.</p

Impact of Legislation on Brominated Flame Retardant Concentrations in UK Indoor and Outdoor Environments:Evidence for Declining Indoor Emissions of Some Legacy BFRs

Concentrations of polybrominated diphenyl ethers, hexabromocyclododecane (HBCDD), and novel brominated flame retardants (NBFRs) were measured in indoor dust, indoor air, and outdoor air in Birmingham, UK. Concentrations of ΣBFRs ranged from 490 to 89,000 ng/g, 46–14,000 pg/m3, and 22–11,000 pg/m3, respectively, in UK indoor dust, indoor air, and outdoor air. BDE-209 and decabromodiphenyl ethane (DBDPE) were the main contributors. The maximum concentration of DBDPE (10,000 pg/m3) in outdoor air is the highest reported anywhere to date. In contrast with previous studies of outdoor air in Birmingham, we observed significant correlations between concentrations of tri- to hepta-BDEs and HBCDD and temperature. This may suggest that primary emissions from ongoing use of these BFRs have diminished and that secondary emissions (e.g., evaporation from soil) are now a potentially major source of these BFRs in outdoor air. Conversely, the lack of significant correlations between temperature and concentrations of BDE-209 and DBDPE may indicate that ongoing primary emissions from indoor sources remain important for these BFRs. Further research to clarify the relative importance of primary and secondary sources of BFRs to outdoor air is required. Comparison with earlier studies in Birmingham reveals significant (p &lt; 0.05) declines in concentrations of legacy BFRs, but significant increases for NBFRs over the past decade. While there appear minimal health burdens from BFR exposure for UK adults, dust ingestion of BDE-209 may pose a significant risk for UK toddlers