20 research outputs found

    Bis(N,N-diethyl­dithio­carbamato)(1,10-phenanthroline)cobalt(III) tetra­fluorido­borate

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    The cationic complex in the structure of the title compound, [Co(Et2NCS2)2(C12H8N2)]BF4, has a CoIII atom with a distorted octa­hedral coordination formed by four S atoms of two diethyl­dithio­carbamate and two N atoms of 1,10-phenanthroline ligands. The crystal structure features head-to-tail stacking of the phenanthroline ligands. The tetra­fluorido­borate anions are positioned in the channels between the cation stacks running along the a axis, and form weak C—H⋯F interactions

    Stable Imido Amido Complexes of Tungsten(VI).

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    5-Bromination of an η 2

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