5,189 research outputs found
Inconsistencies between lifetime and polarizability measurements in Cs
Electric-dipole matrix elements for 6p-nd, n=5, 6, 7 transitions in cesium
are calculated using a relativistic all-order method. The resulting matrix
elements are used to evaluate 5d lifetimes and 6p polarizabilities. The data
are compared with experimental lifetime and polarizability measurements made by
different groups. Domination of the 6p scalar polarizabilities by 5d-6p dipole
matrix elements facilitates an exacting consistency check of 5d lifetime and 6p
polarizability data. Values of 5d-6p matrix elements obtained from experimental
5d lifetime data are found to be inconsistent with those inferred from 6p
polarizabilities derived from experimental Stark shift data. Our ab initio
calculated 6p polarizabilities agree well with experimental determinations.Comment: 5 pages, submitted to Physical Review
Utilization of community resources in the intermediate grades.
Thesis (Ed.M.)--Boston Universit
Magic wavelengths for optical cooling and trapping of lithium
Using first-principles calculations, we identify magic wavelengths for the
2s-2p and 2s-3p transitions in lithium. The ns and np atomic levels have the
same ac Stark shifts at the corresponding magic wavelength, which facilitates
state-insensitive optical cooling and trapping. Tune-out wavelengths for which
the ground-state frequency-dependent polarizability vanishes are also
calculated. Differences of these wavelengths between 6Li and 7Li are reported.
Our approach uses high-precision, relativistic all-order methods in which all
single, double, and partial triple excitations of the Dirac-Fock wave functions
are included to all orders of perturbation theory. Recommended values are
provided for a large number of Li electric-dipole matrix elements. Static
polarizabilities for the 2s, 2p, 3s, 3p, and 3d levels are compared with other
theory and experiment where available. Uncertainties of all recommended values
are estimated. The magic wavelengths for the uv 2s-3p transition are of
particular interest for the production of a quantum gas of lithium [Duarte et
al., Phys. Rev. A 84, 061406R (2011)].Comment: 7 pages, 5 figure
Polarizabilities of Si^{2+}: a benchmark test of theory and experiment
We have calculated electric-dipole polarizabilities of the 3s^2 ^1S_0, 3s3p
^3P_0, and 3s3p ^1P_1 states of the Si^{2+} ion using recently developed
configuration interaction + all-order method. Detailed evaluation of the
uncertainties of the final results is carried out. Our value for the ground
state electric-dipole polarizability 11.670(13) a.u. is in excellent agreement
with the resonant excitation Stark ionization spectroscopy value 11.669(9) a.u.
[Komara et al., J. Phys. B 38, 87 (2005); Mitroy, Phys. Rev. A 78, 052515
(2008)]. This work represents the most precise benchmark test to date of theory
and experiment in divalent atoms. The near cancellation of the ns^2 ^1S_0
ground state and the lowest nsnp ^3P_0 polarizabilities previously observed in
B+, Al+, In+, Tl+, and Pb^{2+} is also found in Si^{2+} ion.Comment: 6 page
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