Superconductivity in pure and electron doped MgB2: Transport properties and pressure effects

The normal state and superconducting properties of MgB2 and Mg1-xAlxB2 are discussed based on structural, transport, and high pressure experiments. The positive Seebeck coefficient and its linear temperature dependence for Tc<T<160 K provide evidence that the low-temperature transport in MgB2 is due to hole-like metallic carriers. Structural and transport data show the important role of defects as indicated by the correlation of Tc, the residual resistance ratio, and the microstrain extracted from x-ray spectra. The decrease of Tc with hydrostatic pressure is well explained by the strong-coupling BCS theory. The large scatter of the pressure coefficients of Tc for different MgB2 samples, however, cannot be explained within this theory. We speculate that pressure may increase the defect density, particularly in samples with large initial defect concentration.Comment: Presented at NATO Advanced Research Workshop "New Trends in Superconductivity", Yalta (Ukraine) 16-20 September, 200

Water Content and Superconductivity in Na0.3CoO2*yH2O

We report here the correlation between the water content and superconductivity in Na0.3CoO2*yH2O under the influences of elevated temperature and cold compression. The x-ray diffraction of the sample annealed at elevated temperatures indicates that intergrowths exist in the compound at equilibrium when 0.6 < y < 1.4. Its low-temperature diamagnetization varies linearly with y, but is insensitive to the intergrowth, indicative of quasi-2D superconductivity. The Tc-onset, especially, shifts only slightly with y. Our data from cold compressed samples, on the other hand, show that the water-loss non-proportionally suppresses the diamagnetization, which is suggestive of weak links.Comment: 10 pages, 10 figures; submitted to Physica C (August 13, 2003

Magnetoelectricity and Magnetostriction due to the Rare Earth Moment in TmAl3_3(BO3_3)4_4

The magnetic properties, the magnetostriction, and the magnetoelectric effect in the d-electron free rare-earth aluminum borate TmAl$_3$(BO$_3$)$_4$ are investigated between room temperature and 2 K. The magnetic susceptibility reveals a strong anisotropy with the hexagonal c-axis as the hard magnetic axis. Magnetostriction measurements show a large effect of an in-plane field reducing both, the a- and c-axis lattice parameters. The magnetoelectric polarization change in a- and c-directions reaches up to 300 $\mu$C/m$^2$ at 70 kOe with the field applied along the a-axis. The magnetoelectric polarization is proportional to the lattice contraction in magnetic field. The results of this investigation prove the existence of a significant coupling between the rare earth magnetic moment and the lattice in $R$Al$_3$(BO$_3$)$_4$ compounds ($R$ = rare earth). They further show that the rare earth moment itself will generate a large magnetoelectric effect which makes it easier to study and to understand the origin of the magnetoelectric interaction in this class of materials.Comment: 4 pages, 5 figure