Direct Covalent Chemical Functionalization of Unmodified Two-Dimensional Molybdenum Disulfide

Two-dimensional semiconducting transition metal dichalcogenides (TMDCs) like molybdenum disulfide (MoS2) are generating significant excitement due to their unique electronic, chemical, and optical properties. Covalent chemical functionalization represents a critical tool for tuning the properties of TMDCs for use in many applications. However, the chemical inertness of semiconducting TMDCs has thus far hindered the robust chemical functionalization of these materials. Previous reports have required harsh chemical treatments or converting TMDCs into metallic phases prior to covalent attachment. Here, we demonstrate the direct covalent functionalization of the basal planes of unmodified semiconducting MoS2 using aryl diazonium salts without any pretreatments. Our approach preserves the semiconducting properties of MoS2, results in covalent C-S bonds, is applicable to MoS2 derived from a range of different synthesis methods, and enables a range of different functional groups to be tethered directly to the MoS2 surface. Using density functional theory calculations including van der Waals interactions and atomic-scale scanning probe microscopy studies, we demonstrate a novel reaction mechanism in which cooperative interactions enable the functionalization to propagate along the MoS2 basal plane. The flexibility of this covalent chemistry employing the diverse aryl diazonium salt family is further exploited to tether active proteins to MoS2, suggesting future biological applications and demonstrating its use as a versatile and powerful chemical platform for enhancing the utility of semiconducting TMDCsComment: To appear in Chemistry Materials (In press

Rotational superstructure in van der Waals heterostructure of self-assembled C60 monolayer on the WSe2 surface

Hybrid van der Waals (vdW) heterostructures composed of two-dimensional (2D) layered materials and self-assembled organic molecules are promising systems for electronic and optoelectronic applications with enhanced properties and performance.</p

Wrapped Magnetized Branes: Two Alternative Descriptions?

We discuss two inequivalent ways for describing magnetized D-branes wrapped N times on a torus T^2. The first one is based on a non-abelian gauge bundle U(N), while the second one is obtained by means of a Narain T-duality transformation acting on a theory with non-magnetized branes. We construct in both descriptions the boundary state and the open string vertices and show that they give rise to different string amplitudes. In particular, the description based on the gauge bundle has open string vertex operators with momentum dependent Chan-Paton factors.Comment: 60 pages, LaTe

Evolution of hydrogen and helium co-implanted single-crystal silicon during annealing

H+H+ was implanted into single-crystal silicon with a dose of 1×1016/cm21×1016/cm2 and an energy of 30 KeV, and then He+He+ was implanted into the same sample with the same dose and an energy of 33 KeV. Both of the implantations were performed at room temperature. Subsequently, the samples were annealed in a temperature range from 200 to 450 °C450 °C for 1 h. Cross-sectional transmission electron microscopy, Rutherford backscattering spectrometry/channeling, elastic recoil detection, and high resolution x-ray diffraction were employed to characterize the strain, defects, and the distribution of H and He in the samples. The results showed that co-implantation of H and He decreases the total implantation dose, with which the surface could exfoliate during annealing. During annealing, the distribution of hydrogen did not change, but helium moved deeper and its distribution became sharper. At the same time, the maximum of the strain in the samples decreased a lot and also moved deeper. Furthermore, the defects introduced by ion implantation and annealing were characterized by slow positron annihilation spectroscopy, and two positron trap peaks were found. After annealing, the maximum of these two peaks decreased at the same time and their positions moved towards the surface. No bubbles or voids but cracks and platelets were observed by cross-sectional transmission electron microscopy. Finally, the relationship between the total implantation dose and the fraction of hydrogen in total implantation dose was calculated. © 2001 American Institute of Physics.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/70387/2/JAPIAU-90-8-3780-1.pd

Exfoliation of Quasi-Two-Dimensional Nanosheets of Metal Diborides

Metal diborides are a class of ceramic materials with crystal structures consisting of hexagonal sheets of boron atoms alternating with planes of metal atoms held together with mixed character ionic/covalent bonds. Many of the metal diborides are ultrahigh-temperature ceramics such as HfB2, TaB2, and ZrB2, which have melting points above 3000 °C, high mechanical hardness and strength at high temperatures, and high chemical resistance, while MgB2 is a superconductor with a transition temperature of 39 K. Here, we demonstrate that this diverse family of non-van der Waals (vdW) materials can be processed into stable dispersions of quasi-two-dimensional (2D) nanosheets using ultrasonication-assisted exfoliation. We generate quasi-2D nanosheets of the metal diborides AlB2, CrB2, HfB2, MgB2, NbB2, TaB2, TiB2, and ZrB2 and use electron and scanning probe microscopy techniques to characterize their structures, morphologies, and compositions. The exfoliated layers have a distribution of lateral dimensions from tens of nanometers up to several micrometers and a distribution of thicknesses from as low as 2-3 nm up to tens of nanometers, all while retaining their hexagonal atomic structure and chemical composition. We exploit the convenient solution-phase dispersions of exfoliated CrB2 nanosheets to incorporate them directly into polymer composites. In contrast to the hard and brittle bulk CrB2, we find that CrB2 nanocomposites remain very flexible and simultaneously provide increases in the elastic modulus and the ultimate tensile strength of the polymer. The successful liquid-phase production of quasi-2D metal diborides enables their processing using scalable low-temperature solution-phase methods, extending their use to previously unexplored applications, and reveals a new family of non-vdW materials that can be efficiently exfoliated into quasi-2D forms

Comparison between the different implantation orders in H + and He + coimplantation

H + and He + were implanted into single crystals in different orders (H + first or He + first). Subsequently, the samples were annealed at different temperatures from 200 °C to 450 °C for 1 h. Cross sectional transmission electron microscopy, Rutherford backscattering spectrometry and channelling, elastic recoil detection were employed to characterize the defects and the distribution of H and He in the samples. Furthermore, the positron traps introduced by ion implantation and annealing were characterized by slow positron annihilation spectroscopy. Both orders in the coimplantation of H and He have the ability to decreases the total implantation dose after annealing. No bubbles or voids but cracks and platelets, were observed by cross sectional transmission electron microscopy. The different implantation orders affect the density of interstitial atoms and positron traps.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/48910/2/d10406.pd

Spatial Distribution of Snow Cover in Tibet and Topographic Dependence

Many major river systems in Asia, such as the Yangtze, Yarlung Zangbo, Indus, Ganges and Salween originate in the Tibetan mountains and snow cover in Tibet provides substantial water resources for these rivers, in addition to its weather-related and climatic significance. The high mountain terrain of Tibet is the main condition that snow cover exists and persists at mid–low altitudes. However, the relationships between snow cover and topographic factors of the plateau have not been fully addressed. In this study, the overall spatial distribution of snow cover and the impacts of topography (elevation, aspect and slope) on snow cover distribution in Tibet were analyzed based on the MODIS snow cover product and digital elevation model (DEM) using GIS spatial analysis techniques. The results showed that (1) snow cover in Tibet is spatially very uneven and is characterized by rich snow and high SCF (snow cover frequency) on Nyainqentanglha mountain and the surrounding high mountains, with less snow and a low SCF in the southern Tibetan valley and central part of northern Tibet. (2) Snow cover in Tibet has a strong elevation dependence and a higher SCF corresponds well with high mountain ranges. The mean SCF below 2000 m above sea level (m a.s.l) was less than 4%, while above 6000 m a.s.l, it reached 75%. (3) Intra-annual snow cover distribution below 4000 m a.s.l was characterized by unimodal patterns, while above 4000 m a.s.l, it was characterized by bimodal patterns. The lowest SCF below 6000 m a.s.l occurred in summer, while above 6000 m it occurred in winter. (4) The mountain slope and aspect affect snow cover distribution through changing radiation and energy balances in the mountain regions. The mean SCF generally increased with mountain slopes, with the highest on the north-facing aspect and the lowest on the south-facing aspect

Snow Cover on the Tibetan Plateau and Topographic Controls

Snow cover plays a critical role in global energy and water cycles. Snow cover on the Tibetan Plateau (TP) provides vital water sources in western China and Himalayan regions, in addition to its weather and climate significance. The massive high mountain topography of the TP is the main condition for the presence and persistence of snow cover on the plateau at the mid-low latitudes of the Northern Hemisphere (NH). However, how the mountain topography controls snow-cover distribution on the TP remains largely unclear, and the relationship is not well quantified. Here, the spatial distribution and the topographic controls of snow cover on the TP are examined based on snow cover frequency (SCF) derived from MODIS snow cover product (MOD10A2 v005) and digital elevation model (DEM) data. The results show that snow cover on the TP is spatially unevenly distributed, and that it is characterized by rich snow and high SCF on the interior and the surrounding high mountain ranges, with less snow and low SCF in inland basins and river valleys. Snow cover on the TP presents elevation dependence: the higher the altitude, the higher the SCF, the longer the snow cover duration, and the more stable the intra-annual variation. The annual mean SCF below 3000 m above sea level (m a.s.l) is less than 4%, and it reaches 77% above 6000 m a.s.l. The intra-annual snow cover variation below 4000 m a.s.l features a unimodal distribution, while above 4000 m a.s.l it presents a bimodal distribution. The mean minimum SCF below 6000 m a.s.l occurs in summer, while above 6000 m a.s.l it occurs in winter. Due to differences in solar radiation and moisture condition caused by the mountain slope and aspect, the mean SCF generally increases with mountain slopes, and it is the highest on the north-facing aspect and the lowest on the south-facing aspect