The high-pressure phase of boron, {\gamma}-B28: disputes and conclusions of 5 years after discovery

{\gamma}-B28 is a recently established high-pressure phase of boron. Its structure consists of icosahedral B12 clusters and B2 dumbbells in a NaCl-type arrangement (B2){\delta}+(B12){\delta}- and displays a significant charge transfer {\delta}~0.5- 0.6. The discovery of this phase proved essential for the understanding and construction of the phase diagram of boron. {\gamma}-B28 was first experimentally obtained as a pure boron allotrope in early 2004 and its structure was discovered in 2006. This paper reviews recent results and in particular deals with the contentious issues related to the equation of state, hardness, putative isostructural phase transformation at ~40 GPa, and debates on the nature of chemical bonding in this phase. Our analysis confirms that (a) calculations based on density functional theory give an accurate description of its equation of state, (b) the reported isostructural phase transformation in {\gamma}-B28 is an artifact rather than a fact, (c) the best estimate of hardness of this phase is 50 GPa, (d) chemical bonding in this phase has a significant degree of ionicity. Apart from presenting an overview of previous results within a consistent view grounded in experiment, thermodynamics and quantum mechanics, we present new results on Bader charges in {\gamma}-B28 using different levels of quantum-mechanical theory (GGA, exact exchange, and HSE06 hybrid functional), and show that the earlier conclusion about significant degree of partial ionicity in this phase is very robust

Title: Modern Mars' geomorphological activity, driven by wind, frost, and gravity

International audienceExtensive evidence of landform-scale martian geomorphic changes has been acquired in the last decade, and the number and range of examples of surface activity have increased as more high-resolution imagery has been acquired. Within the present-day Mars climate, wind and frost/ice are the dominant drivers, resulting in large avalanches of material down icy, rocky, or sandy slopes; sediment transport leading to many scales of aeolian bedforms and erosion; pits of various forms and patterned ground; and substrate material carved out from under subliming ice slabs. Due to the ability to collect correlated observations of surface activity and new landforms with relevant environmental conditions with spacecraft on or around Mars, studies of martian geomorphologic activity are uniquely positioned to directly test surface-atmosphere interaction and landform formation/evolution models outside of Earth. In this paper, we outline currently observed and interpreted surface activity occurring within the modern Mars environment, and tie this activity to wind, seasonal surface CO2 frost/ice, sublimation of subsurface water ice, and/or gravity drivers. Open questions regarding these processes are outlined, and then measurements needed for answering these questions are identified. In the final sections, we discuss how many of these martian processes and landforms may provide useful analogs for conditions and processes active on other planetary surfaces, with an emphasis on those that stretch the bounds of terrestrial-based models or that lack terrestrial analogs. In these ways, modern Mars presents a natural and powerful comparative planetology base case for studies of Solar System surface processes, beyond or instead of Earth