Biotreatment of Winery Wastewater Using a Hybrid System Combining Biological Trickling Filters and Constructed Wetlands

The objective of this work was to determine the ability of a pilot-scale hybrid system to treat real (non-synthetic) winery wastewater. The experimental treatment system consisted of two stages: An attached growth pilot-scale bioreactor (biological trickling filter with plastic support material) was initially used to remove a significant amount of dissolved chemical oxygen demand (d-COD) from winery wastewater, and then a pilot-scale, horizontal subsurface flow constructed wetland (CW) was examined as a post-treatment step for further d-COD removal. Results from the biofilter revealed that the recirculation rate of 1.0 L/min lead to higher d-COD removal rates than that of 0.5 L/min for all feed d-COD concentrations tested (3500, 7500, 9000 and 18,000 mg d-COD/L). Experiments in the CW were performed using feed d-COD concentrations of about 1500 mg/L (equivalent to biofilter effluent when initial filter feed d-COD concentrations are 18,000 mg/L). The wetland polishing stage managed to further remove d-COD and produced effluent concentrations below current legislation limits for safe disposal. Furthermore, the presence of zeolite in CW (one third of the length of CW) enhanced ammonium removal. The experimental results indicate that the combination of a biological trickling filter and a constructed wetland could effectively treat effluents originating from small wineries typical of the Mediterranean region

Agro-Industrial Wastewater Treatment with Decentralized Biological Treatment Methods

Food processing consumes high volumes of water, making agro-industries the third biggest industrial user of water after oil refineries, primary metals and chemicals industries [...

Performance of a Full-Scale Biogas Plant Operation in Greece and Its Impact on the Circular Economy

Biogas plants have been started to expand recently in Greece and their positive contribution to the economy is evident. A typical case study is presented which focuses on the long-term monitoring (lasting for one year) of a 500 kW mesophilic biogas plant consisting of an one-stage digester. The main feedstock used was cow manure, supplemented occasionally with chicken manure, corn silage, wheat/ray silage, glycerine, cheese whey, molasses and olive mill wastewater. The mixture of the feedstocks was adjusted based on their availability, cost and biochemical methane potential. The organic loading rate (OLR) varied at 3.42 ± 0.23 kg COD m−3 day−1 (or 2.74 ± 0.18 kg VS m−3 day−1) and resulted in a stable performance in terms of specific biogas production rate (1.27 ± 0.12 m3 m−3 day−1), biogas yield (0.46 ± 0.05 m3 kg−1 VS, 55 ± 1.3% in methane) and electricity production rate (12687 ± 1140 kWh day−1). There were no problems of foaming, nor was there a need for trace metal addition. The digestate was used by the neighboring farmers who observed an improvement in their crop yield. The profit estimates per feedstock indicate that chicken manure is superior to the other feedstocks, while molasses, silages and glycerin result in less profit due to the long distance of the biogas plant from their production source. Finally, the greenhouse gas emissions due to the digestate storage in the open air seem to be minor (0.81% of the methane consumed)

Constructed wetlands in the treatment of agro-industrial wastewater: A review

Due to their simplicity and low operation cost, constructed wetlands are becoming more prevalent in wastewater treatment all over the world. Their range of applications is no longer limited to municipal wastewater but has expanded to the treatment of heavily polluted wastewaters such as agro-industrial effluents. This paper provides a comprehensive literature review of the application of constructed wetlands in treating a variety of agro-industrial wastewaters, and discusses pollutant surface loads and the role of constructed wetland type, prior-treatment stages and plant species in pollutant removal efficiency. Results indicate that constructed wetlands can tolerate high pollutant loads and toxic substances without losing their removal ability, thus these systems are very effective bio-reactors even in hostile environments. Additionally, the review outlines issues that could improve pollutant treatment efficiency and proposes design and operation suggestions such as suitable vegetation, porous media and constructed wetland plain view. Finally, a decision tree for designing constructed wetlands treating agro-industrial wastewaters provides an initial design tool for scientists and engineers

Monitoring Water Quality Parameters in Small Rivers Using SuperDove Imagery

Freshwater ecosystems provide an array of provisioning, regulating/maintenance, and cultural ecosystem services. Despite their crucial role, freshwater ecosystems are exceptionally vulnerable due to changes driven by both natural and human factors. Water quality is essential for assessing the condition and ecological health of freshwater ecosystems, and its evaluation involves various water quality parameters. Remote sensing has become an efficient approach for retrieving and mapping these parameters, even in optically complex waters such as small rivers. This study specifically focuses on modelling two non-optically active water quality parameters, dissolved oxygen (DO) and electrical conductivity (EC), by integrating 3 m PlanetScope satellite imagery with data from real-time in situ remote monitoring sensors across two small rivers in Thrace, Northeast Greece. We employed three different experimental setups using a support vector regression (SVR) algorithm: ‘Multi-seasonal by Individual Sensor’ (M-I-S) for individual sensor analysis across two seasons, ‘Multi-seasonal—All Sensors’ (M-A-S) integrating data across all seasons and sensors, and ‘Seasonal—All Sensors’ (S-A-S) focusing on per-season sensor data. The models incorporating multiple seasons and all in situ sensors resulted in R2 values of 0.549 and 0.657 for DO and EC, respectively. A multi-seasonal approach per in situ sensor resulted in R2 values of 0.885 for DO and 0.849 for EC. Meanwhile, the seasonal approach, using all in situ sensors, achieved R2 values of 0.805 for DO and 0.911 for EC. These results underscore the significant potential of combining PlanetScope data and machine learning to model these parameters and monitor the condition of ecosystems over small river surfaces

Simultaneous Treatment of Agro-Industrial and Industrial Wastewaters: Case Studies of Cr(VI)/Second Cheese Whey and Cr(VI)/Winery Effluents

Hexavalent chromium (Cr(VI)) was co-treated either with second cheese whey (SCW) or winery effluents (WE) using pilot-scale biological trickling filters in series under different operating conditions. Two pilot-scale filters in series using plastic support media were used in each case. The first filter (i.e., Cr-SCW-filter or Cr-WE-filter) aimed at Cr(VI) reduction and the partial removal of dissolved chemical oxygen demand (d-COD) from SCW or WE and was inoculated with indigenous microorganisms originating from industrial sludge. The second filter in series (i.e., SCW-filter or WE-filter) aimed at further d-COD removal and was inoculated with indigenous microorganisms that were isolated from SCW or WE. Various Cr(VI) (5–100 mg L−1) and SCW or WE (d-COD, 1000–25,000 mg L−1) feed concentrations were tested. Based on the experimental results, the sequencing batch reactor operating mode with recirculation of 0.5 L min−1 proved very efficient since it led to complete Cr(VI) reduction in the first filter in series and achieved high Cr(VI) reduction rates (up to 36 and 43 mg L−1 d−1, for SCW and WW, respectively). Percentage d-COD removal for SCW and WE in the first filter was rather low, ranging from 14 to 42.5% and from 4 to 29% in the Cr-SCW-filter and Cr-WE-filter, respectively. However, the addition of the second filter in series enhanced total d-COD removal to above 97% and 90.5% for SCW and WE, respectively. The above results indicate that agro-industrial wastewater could be used as a carbon source for Cr(VI) reduction, while the use of two trickling filters in series could effectively treat both industrial and agro-industrial wastewaters with very low installation and operational costs

Agroindustrial Wastewater Treatment with Simultaneous Biodiesel Production in Attached Growth Systems Using a Mixed Microbial Culture

The use of cyanobacteria in biological wastewater treatment technologies can greatly reduce operation costs by combining wastewater bioremediation and production of lipid suitable as biodiesel feedstock. In this work, an attached growth system was employed to achieve the above-mentioned dual objective using a mixed microbial culture dominated by Leptolyngbya and Limnothrix species in diverse heterotrophic consortia. Kinetic experiments on different initial pollutant concentrations were carried out to determine the ability of the established culture to remove organic load (expressed by d-COD, dissolved-Chemical Oxygen Demand), N and P from agroindustrial wastewaters (dairy, winery and raisin). Biomass and oil productivity were determined. It was found that significant removal rates of nutrients were achieved in all the wastewaters examined, especially in that originated from winery in which the highest d-COD removal rate (up to 97.4%) was observed. The attached microbial biomass produced in winery wastewater contained 23.2% lipid/biomass, wt/wt, which was satisfying. The growth in the dairy wastewater yielded the highest attached biomass productivity (5.03 g m−2 day−1) followed by the mixed effluent of winery-raisin (4.12 g m−2 day−1) and the winery wastewater (3.08 g m−2 day−1). The produced microbial lipids contained high percentages of saturated and mono-unsaturated fatty acids (over 89% in total lipids) in all substrates examined. We conclude that the proposed attached growth photobioreactor system can be considered an effective wastewater treatment system that simultaneously produces microbial lipids suitable as biodiesel feedstock

Second Cheese Whey Treatment Using Zeolite under Continuous Flow Mode and Its Application on Wheat Growth

The efficiency of natural zeolite to treat second cheese whey (SCW) and remove ammonium from artificial wastewater (AWW) was examined. Since zeolite has been reported to improve nitrogen availability in soils, its effect on wheat plant growth was also examined. Continuing a previous study using batch reactors, results are presented concerning experiments in fixed-bed columns under continuous operation. Results from the continuous flow column experiments using AWW and zeolite (2.0−2.8 mm) indicated that low flow rates (4 mL/min and 8 mL/min) did not significantly affect zeolite adsorption ability, while maximum zeolite adsorption capacity reached 15.30 mg NH4+-N/g. Finally, the effect of zeolite saturated with NH4+-N on plant growth was examined. The application of saturated zeolite affected significantly wheat plant growth and resulted in faster growth and higher biomass production

Zeolite as a Potential Medium for Ammonium Recovery and Second Cheese Whey Treatment

The efficiency of natural zeolite to remove ammonium from artificial wastewater (ammonium aqueous solutions) and to treat second cheese whey was examined, aiming to recover nitrogen nutrients that can be used for further applications, such as slow-release fertilizers. Sorption experiments were performed using artificial wastewater and zeolite of different granulometries (i.e., 0.71–1.0, 1.8–2.0, 2.0–2.8, 2.8–4.0, and 4.0–5.0 mm). The granulometry of the zeolite had no significant effect on its ability to absorb ammonium. Nevertheless, smaller particles (0.71–1.0 mm) exhibited quicker NH4+-N adsorption rates of up to 93.0% in the first 10 min. Maximum ammonium removal efficiency by the zeolite was achieved at ammonium concentrations ranging from 10 to 80 mg/L. Kinetic experiments revealed that chemisorption is the mechanism behind the adsorption process of ammonium on zeolite, while the Freundlich isotherm model fitted the experimental data well. Column sorption experiments under batch operating mode were performed using artificial wastewater and second cheese whey. Column experiments with artificial wastewater showed high NH4+-N removal rates (over 96% in the first 120 min) for all granulometries and initial NH4+-N concentrations tested (200 and 5000 mg/L). Column experiments with second cheese whey revealed that natural zeolite can remove significant organic loads (up to 40%, 14.53 mg COD/g of zeolite) and NH4+-N (about 99%). For PO43−-P, the zeolite appeared to saturate after day 1 of the experiments at a removal capacity of 0.15 mg P/g of zeolite. Desorption experiments with water resulted in low NH4+-N and PO43−-P desorption rates indicating that the zeolite could be used as a substrate for slow nitrogen release in soils