Phonons in potassium doped graphene: the effects of electron-phonon interactions, dimensionality and ad-atom ordering

Graphene phonons are measured as a function of electron doping via the addition of potassium adatoms. In the low doping regime, the in-plane carbon G-peak hardens and narrows with increasing doping, analogous to the trend seen in graphene doped via the field-effect. At high dopings, beyond those accessible by the field-effect, the G-peak strongly softens and broadens. This is interpreted as a dynamic, non-adiabatic renormalization of the phonon self-energy. At dopings between the light and heavily doped regimes, we find a robust inhomogeneous phase where the potassium coverage is segregated into regions of high and low density. The phonon energies, linewidths and tunability are remarkably similar for 1-4 layer graphene, but significantly different to doped bulk graphite.Comment: Accepted in Phys. Rev. B as a Rapid Communication. 5 pages, 3 figures, revised text with additional dat

Analog of the Clauser-Horne-Shimony-Holt inequality for steering

The Clauser-Horne-Shimony-Holt (CHSH) inequality (and its permutations), are necessary and sufficient criteria for Bell nonlocality in the simplest Bell-nonlocality scenario: 2 parties, 2 measurements per party and 2 outcomes per measurement. Here we derive an inequality for EPR-steering that is an analogue of the CHSH, in that it is necessary and sufficient in this same scenario. However, since in the case of steering the device at Bob's site must be specified (as opposed to the Bell case in which it is a black box), the scenario we consider is that where Alice performs two (black-box) dichotomic measurements, and Bob performs two mutually unbiased qubit measurements. We show that this inequality is strictly weaker than the CHSH, as expected, and use it to decide whether a recent experiment [Phys. Rev. Lett. 110, 130401 (2013).] involving a single-photon split between two parties has demonstrated EPR-steering.Comment: Expanded v2, new results, new figure. 9 pages, 2 figure

The economic performance of cities: a Markov-switching approach

This paper examines the determinants of employment growth in metro areas. To obtain growth rates, we use a Markov-switching model that separates a city’s growth path into two distinct phases (high and low), each with its own growth rate. The simple average growth rate over some period is, therefore, the weighted average of the high-phase and low-phase growth rates, with the weight being the frequency of the two phases. We estimate the effects of a variety of factors separately for the high-phase and low-phase growth rates, along with the frequency of the low phase. We find that growth in the high phase is related to human capital, industry mix, and average firm size. In contrast, we find that growth in the low phase is mostly related to industry mix, specifically, the relative importance of manufacturing. Finally, the frequency of the low phase appears to be related to the level of non-education human capital, but to none of the other variables. Overall, our results strongly reject the notion that city-level characteristics influence employment growth equally across the phases of the business cycle.Business cycles ; Cities and towns

Practice patterns and outcomes of equivocal bone scans for patients with castration-resistant prostate cancer: Results from SEARCH.

ObjectiveTo review follow-up imaging after equivocal bone scans in men with castration resistant prostate cancer (CRPC) and examine the characteristics of equivocal bone scans that are associated with positive follow-up imaging.MethodsWe identified 639 men from five Veterans Affairs Hospitals with a technetium-99m bone scan after CRPC diagnosis, of whom 99 (15%) had equivocal scans. Men with equivocal scans were segregated into "high-risk" and "low-risk" subcategories based upon wording in the bone scan report. All follow-up imaging (bone scans, computed tomography [CT], magnetic resonance imaging [MRI], and X-rays) in the 3 months after the equivocal scan were reviewed. Variables were compared between patients with a positive vs. negative follow-up imaging after an equivocal bone scan.ResultsOf 99 men with an equivocal bone scan, 43 (43%) received at least one follow-up imaging test, including 32/82 (39%) with low-risk scans and 11/17 (65%) with high-risk scans (p = 0.052). Of follow-up tests, 67% were negative, 14% were equivocal, and 19% were positive. Among those who underwent follow-up imaging, 3/32 (9%) low-risk men had metastases vs. 5/11 (45%) high-risk men (p = 0.015).ConclusionWhile 19% of all men who received follow-up imaging had positive follow-up imaging, only 9% of those with a low-risk equivocal bone scan had metastases versus 45% of those with high-risk. These preliminary findings, if confirmed in larger studies, suggest follow-up imaging tests for low-risk equivocal scans can be delayed while high-risk equivocal scans should receive follow-up imaging

Comparison of dye wastewater treatment methods: A review.

Wastewater is produced by numerous dyes producing and dye consuming industries in their process activities especially the textile industry. These effluents become toxic and harmful to the living things and the environment if not properly treated before being discharged to the environment. In recent decades dye wastewater has been becomes a growing water pollution problem because it is one of the most difficult to treat. To put an end to this problem, viable, efficient, and sustainable method of treatment of dye wastewater and color removal needs to be established. Several research papers have been done over the years on various treatment method of dye wastewater with evolving options; this paper is to bring together both the conventional and new methods. Some of the conventional and new methods researched over the years include activated sludge, coagulation, adsorption, membrane separation processes and electrochemical process etc. Although there is currently no uniform standard or method of treatment universally adopted, many countries have put in place allowable limits of composition of dischargeable wastewater. This paper seeks to explore which methods are highly efficient, produces manageable and recyclable waste and a combination/hybrid treatment option of these methods to achieve maximum color removal

Scalable Dashboard for Identifying Split Failures and Heuristic for Reallocating Split Times

The three fundamental parameters of a traffic signal system are split, cycle, and offset. This paper describes the use of high-resolution data (a) to identify time periods during which split parameters may be insufficient and (b) to help practitioners identify opportunities for reallocating split time. A case study of seven corridors with 47 intersections is presented. A drill-down approach was developed to identify movements that could be improved by a reallocation of split times. A heuristic that can reallocate up to 5 seconds of underutilized green time on a competing phase was applied to those corridors. For the selected phase identified in this study, the adjustment reduced split failures by an average of 40% while also decreasing yellow occupancy an average of 40% and red light violations an average of 66%. The paper concludes by recommending that central systems implement drill-down dashboards. Such tools would enable easy identification and systemwide monitoring of split failures and would provide opportunities to reallocate slack time

Independent evaluation of a simple clinical prediction rule to identify right ventricular dysfunction in patients with shortness of breath

BACKGROUND: Many patients have unexplained persistent dyspnea after negative computed tomographic pulmonary angiography (CTPA). We hypothesized that many of these patients have isolated right ventricular (RV) dysfunction from treatable causes. We previously derived a clinical decision rule (CDR) for predicting RV dysfunction consisting of persistent dyspnea and normal CTPA, finding that 53% of CDR-positive patients had isolated RV dysfunction. Our goal is to validate this previously derived CDR by measuring the prevalence of RV dysfunction and outcomes in dyspneic emergency department patients. METHODS: A secondary analysis of a prospective observational multicenter study that enrolled patients presenting with suspected PE was performed. We included patients with persistent dyspnea, a nonsignificant CTPA, and formal echo performed. Right ventricular dysfunction was defined as RV hypokinesis and/or dilation with or without moderate to severe tricuspid regurgitation. RESULTS: A total of 7940 patients were enrolled. Two thousand six hundred sixteen patients were analyzed after excluding patients without persistent dyspnea and those with a significant finding on CTPA. One hundred ninety eight patients had echocardiography performed as standard care. Of those, 19% (95% confidence interval [CI], 14%-25%) and 33% (95% CI, 25%-42%) exhibited RV dysfunction and isolated RV dysfunction, respectively. Patients with isolated RV dysfunction or overload were more likely than those without RV dysfunction to have a return visit to the emergency department within 45 days for the same complaint (39% vs 18%; 95% CI of the difference, 4%-38%). CONCLUSION: This simple clinical prediction rule predicted a 33% prevalence of isolated RV dysfunction or overload. Patients with isolated RV dysfunction had higher recidivism rates and a trend toward worse outcomes

Constructing a Man-Made Oyster Reef in the Little Hellgate Salt Marsh, Randall\u27s Island, New York: A Project Overview

Atlantic oyster beds provide instrumental estuarine infrastructure, shaping waterways and mediating the impacts of storm surge. In addition, the reefs provide habitat for numerous species. The oysters themselves are expert filter feeders, remediating poor water quality at little cost to the organism. As the free-swimming oyster larvae (spat) only settle on the shells of their forbears, the reefs are essential in perpetuation of the species, as well as for the continuation of such invaluable ecosystem services. Oyster reefs of the New York City waterway system have long been subject to environmental degradation, from water pollution and sedimentation to dredging. Randall’s Island Park Alliance’s Natural Areas crew received a donation of six hundred oysters from the New York Harbor School to conduct a test for the viability of a manmade oyster garden in 2014. Three hundred oysters were placed in each cage, which were then established in different parts of Randall’s Island Park’s Harlem River shoreline. One was hung by the 103rd Street footbridge seawall and the other was placed on the seawall by the Little Hellgate Salt Marsh inlet. The cages were monitored monthly for oyster growth and mortality rate, and water quality was tested as well. After a year of monitoring, it was determined that the Little Hellgate Salt Marsh was the ideal site for a man-made oyster reef—oysters had shown significantly more growth and a lower mortality rate than those in the cage at the 103rd St. Bridge, most likely due to the protective shape of the salt marsh inlet. The cages that will serve as the reef framework were constructed in the spring of this year and await the placement of oyster shells, which are being treated and sterilized (completion is projected to be late fall 2015). Future monitoring of oyster colonization and growth are expected, with the aim that water quality will measurably improve