24 research outputs found

    Determination of the phase diagram of the electron doped superconductor Ba(Fe1−x_{1-x}Cox_x)2_2As2_2

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    Systematic measurements of the resistivity, heat capacity, susceptibility and Hall coefficient are presented for single crystal samples of the electron-doped superconductor Ba(Fe1−x_{1-x}Cox_x)2_2As2_2. These data delineate an x−Tx-T phase diagram in which the single magnetic/structural phase transition that is observed for undoped BaFe2_2As2_2 at 134 K apparently splits into two distinct phase transitions, both of which are rapidly suppressed with increasing Co concentration. Superconductivity emerges for Co concentrations above x∼0.025x \sim 0.025, and appears to coexist with the broken symmetry state for an appreciable range of doping, up to x∼0.06x \sim 0.06. The optimal superconducting transition temperature appears to coincide with the Co concentration at which the magnetic/structural phase transitions are totally suppressed, at least within the resolution provided by the finite step size between crystals prepared with different doping levels. Superconductivity is observed for a further range of Co concentrations, before being completely suppressed for x∼0.018x \sim 0.018 and above. The form of this x−Tx-T phase diagram is suggestive of an association between superconductivity and a quantum critical point arising from suppression of the magnetic and/or structural phase transitions

    Quantum oscillations in the parent pnictide BaFe2_2As2_2 : itinerant electrons in the reconstructed state

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    We report quantum oscillation measurements that enable the direct observation of the Fermi surface of the low temperature ground state of \ba122. From these measurements we characterize the low energy excitations, revealing that the Fermi surface is reconstructed in the antiferromagnetic state, but leaving itinerant electrons in its wake. The present measurements are consistent with a conventional band folding picture of the antiferromagnetic ground state, placing important limits on the topology and size of the Fermi surface.Comment: 5 pages, 3 figure

    Probing the reaction pathway in (La_(0.8)Sr_(0.2))_(0.95)MnO_(3+δ) using libraries of thin film microelectrodes

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    Libraries of (La_(0.8)Sr_(0.2))_(0.95)MnO_(3+δ) (LSM) thin film microelectrodes with systematically varied thickness or growth temperature were prepared by pulsed laser deposition, and a novel robotic instrument was used to characterize these libraries in automated fashion by impedance spectroscopy. The measured impedance spectra are found to be described well by an electrochemical model based on a generalized transmission model for a mixed conducting oxide, and all trends are consistent with a reaction pathway involving oxygen reduction over the LSM surface followed by diffusion through the film and into the electrolyte substrate. The surface activity is found to be correlated with the number of exposed grain boundary sites, which decreases with either increasing film thickness (at constant growth temperature) or increasing film growth temperature (at constant thickness). These findings suggest that exposed grain boundaries in LSM films are more active than exposed grains towards the rate-limiting surface process, and that oxygen ion diffusion through polycrystalline LSM films is faster than many prior studies have concluded

    Exceptional power density and stability at intermediate temperatures in protonic ceramic fuel cells

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    Over the past several years, important strides have been made in demonstrating protonic ceramic fuel cells (PCFCs). Such fuel cells offer the potential of environmentally sustainable and cost-effective electric power generation. However, their power outputs have lagged behind predictions based on their high electrolyte conductivities. Here we overcome PCFC performance and stability challenges by employing a high-activity cathode, PrBa_(0.5)Sr_(0.5)Co_(1.5)Fe_(0.5)O_(5+δ) (PBSCF), in combination with a chemically stable electrolyte, BaZr_(0.4)Ce_(0.4)Y_(0.1)Yb_(0.1)O_3 (BZCYYb4411). We deposit a thin dense interlayer film of the cathode material onto the electrolyte surface to mitigate contact resistance, an approach which is made possible by the proton permeability of PBSCF. The peak power densities of the resulting fuel cells exceed 500 mW cm^(−2) at 500 °C, while also offering exceptional, long-term stability under CO_2

    Exceptional power density and stability at intermediate temperatures in protonic ceramic fuel cells

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    Over the past several years, important strides have been made in demonstrating protonic ceramic fuel cells (PCFCs). Such fuel cells offer the potential of environmentally sustainable and cost-effective electric power generation. However, their power outputs have lagged behind predictions based on their high electrolyte conductivities. Here we overcome PCFC performance and stability challenges by employing a high-activity cathode, PrBa_(0.5)Sr_(0.5)Co_(1.5)Fe_(0.5)O_(5+δ) (PBSCF), in combination with a chemically stable electrolyte, BaZr_(0.4)Ce_(0.4)Y_(0.1)Yb_(0.1)O_3 (BZCYYb4411). We deposit a thin dense interlayer film of the cathode material onto the electrolyte surface to mitigate contact resistance, an approach which is made possible by the proton permeability of PBSCF. The peak power densities of the resulting fuel cells exceed 500 mW cm^(−2) at 500 °C, while also offering exceptional, long-term stability under CO_2

    Focus topics for the ECFA study on Higgs / Top / EW factories

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    In order to stimulate new engagement and trigger some concrete studies in areas where further work would be beneficial towards fully understanding the physics potential of an e+e−e^+e^- Higgs / Top / Electroweak factory, we propose to define a set of focus topics. The general reasoning and the proposed topics are described in this document.Comment: v3: fixed spelling of two author

    Reported UAV incidents in Canada: analysis and potential solutions

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    UAV incidents were analyzed using data from Transport Canada's Civil Aviation Daily Occurrence Reporting System (CADORS). Between 05 November 2005 and 31 December 2016 a total of 355 incidents were reported in Canadian airspace. The largest number involved UAV sightings (66.5%) and close encounters with piloted aircraft (22.3%). These incidents increased markedly after 2013, with the highest number in British Columbia, followed by Ontario, Quebec, Alberta, and Manitoba. The vast majority of UAV incident reports were filed by pilots of piloted aircraft. Typically, airspace at altitudes greater than 400 feet above ground level (AGL) is off limits to UAVs; however, of the 270 incidents in the CADORS database with UAV altitude reported, 80.4% were above 400 feet AGL and 62.6% were above 1000 feet AGL. Of the 268 incidents with reported horizontal distance to the nearest aerodrome, 74.6% occurred or likely occurred within 5 nautical miles (nm), and of those 92.4% and 76.6% were reported above 100 and 300 feet AGL, respectively. Collectively, the CADORS data indicate that the overwhelming majority of UAV incidents reported in Canada were airspace violations. These results can guide future risk mitigation measures, hardware/software solutions, and educational campaigns to increase airspace safety.The accepted manuscript in pdf format is listed with the files at the bottom of this page. The presentation of the authors' names and (or) special characters in the title of the manuscript may differ slightly between what is listed on this page and what is listed in the pdf file of the accepted manuscript; that in the pdf file of the accepted manuscript is what was submitted by the author
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