Observation of superconductivity and enhanced upper critical field of η{\eta}-carbide-type oxide Zr4{_\mathrm{4}}Pd2_{\mathrm{2}}O

We report the first observation of bulk superconductivity of a ${\eta}$-carbide-type oxide Zr$_{4}$Pd$_{2}$O. The crystal structure and the superconducting properties were studied through synchrotron X-ray diffraction, magnetization, electrical resistivity, and specific heat measurement. The superconducting transition was observed at $T_{\mathrm{c}}$ = 2.73 K. Our measurement revealed that the ${\eta}$-carbide-type oxide superconductor Zr$_{4}$Pd$_{2}$O shows an enhanced upper critical field ${\mu_{\mathrm{0}}H_{\mathrm{c2}}\mathrm{(0)}}$ = 6.72 T, which violates the Pauli-Clogston limit ${\mu_{\mathrm{0}}H_{\mathrm{P}}}$ = 5.29 T. On the other hand, we found that the enhanced upper critical field is absent in a Rh analogue Zr$_{4}$Rh$_{2}$O. The large ${\mu_{\mathrm{0}}H_{\mathrm{c2}}\mathrm{(0)}}$ of Zr$_{4}$Pd$_{2}$O would be raised from strong spin-orbit coupling with Pd-4$d$ electrons. The discovery of new superconducting properties for Zr$_{4}$Pd$_{2}$O would shed light on the further development of ${\eta}$-carbide-type oxide superconductors.Comment: 12 pages, 4 figures, 3 table