PHYSICAL AND CHEMICAL INTERACTION OF CARBONIC FULLERENES WITH MACROMOLECULES OF POLYMERS OF VARIOUS STRUCTURE

In this work authors make the comparative survey of structural transitions into the synthetic rubbers using the following methods: scanning calorimetry, infrared spectroscopy. The discriminant analysis of the binary comparison of spectrums in the canonical variant was used for interpretation of results of the frequency analysis. The analysis of features of behavior of various synthetic rubbers at presence of the mix of fullerenes was made. The influence of fullerenes in macromolecules of studied synthetic rubbers was shown. The efficiency of the discriminant analysis in the canonical variant is shown. The mechanism of interaction of injected fullerenes with the polymeric basis is considered. Groups of synthetic rubbers able to interact with the injected modifier are determined