2 research outputs found
Voltammetry at porous electrodes: A theoretical study
Theory is presented to simulate both chronoamperometry and cyclic voltammetry
at porous electrodes fabricated by means of electro-deposition around spherical
templates. A theoretical method to extract heterogeneous rate constants for
quasireversible and irreversible systems is proposed by the approximation of
decoupling of the diffusion within the porous electrode and of bulk diffusion
to the electrode surface