934 research outputs found
Dyson-Schwinger Equations with a Parameterized Metric
We construct and solve the Dyson-Schwinger equation (DSE) of quark propagator
with a parameterized metric, which connects the Euclidean metric with the
Minkowskian one. We show, in some models, the Minkowskian vacuum is different
from the Euclidean vacuum. The usual analytic continuation of Green function
does not make sense in these cases. While with the algorithm we proposed and
the quark-gluon vertex ansatz which preserves the Ward-Takahashi identity, the
vacuum keeps being unchanged in the evolution of the metric. In this case,
analytic continuation becomes meaningful and can be fully carried out.Comment: 10 pages, 7 figures. To appear in Physical Review
Cold quarks in medium: an equation of state
We derive a compact, semi-algebraic expression for the cold quark matter
equation of state (EoS) in a covariant model that exhibits coincident
deconfinement and chiral symmetry restoring transitions in-medium. Along the
way we obtain algebraic expressions for: the number- and scalar-density
distributions in both the confining Nambu and deconfined Wigner phases; and the
vacuum-pressure difference between these phases, which defines a bag constant.
The confining interaction materially alters the distribution functions from
those of a Fermi gas and consequently has a significant impact on the model's
thermodynamic properties, which is apparent in the EoS.Comment: 5 pages, 5 figure
Phase diagram and critical endpoint for strongly-interacting quarks
We introduce a method based on the chiral susceptibility, which enables one
to draw a phase diagram in the chemical-potential/temperature plane for
strongly-interacting quarks whose interactions are described by any reasonable
gap equation, even if the diagrammatic content of the quark-gluon vertex is
unknown. We locate a critical endpoint (CEP) at (\mu^E,T^E) ~ (1.0,0.9)T_c,
where T_c is the critical temperature for chiral symmetry restoration at \mu=0;
and find that a domain of phase coexistence opens at the CEP whose area
increases as a confinement length-scale grows.Comment: 4 pages, 3 figure
Antagonistic actions of boron against inhibitory effects of aluminum toxicity on growth, CO2 assimilation, ribulose-1,5-bisphosphate carboxylase/oxygenase, and photosynthetic electron transport probed by the JIP-test, of Citrus grandis seedlings
<p>Abstract</p> <p>Background</p> <p>Little information is available on the amelioration of boron (B) on aluminum (Al)-induced photosynthesis inhibition. Sour pummelo (<it>Citrus grandis</it>) seedlings were irrigated for 18 weeks with nutrient solution containing 4 B levels (2.5, 10, 25 and 50 μM H<sub>3</sub>BO<sub>3</sub>) × 2 Al levels (0 and 1.2 mM AlCl<sub>3</sub>·6H<sub>2</sub>O). The objectives of this study were to determine how B alleviates Al-induced growth inhibition and to test the hypothesis that Al-induced photosynthesis inhibition can be alleviated by B <it>via </it>preventing Al from getting into shoots.</p> <p>Results</p> <p>B had little effect on plant growth, root, stem and leaf Al, leaf chlorophyll (Chl), CO<sub>2 </sub>assimilation, ribulose-1,5-bisphosphate carboxylase/oxygenase (Rubisco), Chl a fluorescence (OJIP) transient and related parameters without Al stress except that root, stem and leaf B increased with increasing B supply and that 50 μM B decreased slightly root dry weight. Al-treated roots, stems and leaves displayed a higher or similar B. B did not affect root Al under Al stress, but decreased stem and leaf Al level. Shoot growth is more sensitive to Al stress than root growth, CO<sub>2 </sub>assimilation, Chl, Rubisco, OJIP transient and most related parameters. Al-treated leaves showed decreased CO<sub>2 </sub>assimilation, but increased or similar intercellular CO<sub>2 </sub>concentration. Both initial and total Rubisco activity in Al-treated leaves decreased to a lesser extent than CO<sub>2 </sub>assimilation. Al decreased maximum quantum yield of primary photochemistry and total performance index, but increased minimum fluorescence, K-band, relative variable fluorescence at J- and I-steps. B could alleviate Al-induced increase or decrease for all these parameters. Generally speaking, the order of B effectiveness was 25 μM > 10 μM ≥ 50 μM (excess B) > 2.5 μM.</p> <p>Conclusion</p> <p>We propose that Al-induced photosynthesis inhibition was mainly caused by impaired photosynthetic electron transport chain, which may be associated with growth inhibition. B-induced amelioration of root inhibition was probably caused by B-induced changes in Al speciation and/or sub-cellular compartmentation. However, B-induced amelioration of shoot and photosynthesis inhibition and photoinhibitory damage occurring at both donor and acceptor sides of photosystem II could be due to less Al accumulation in shoots.</p
Effect of solvation shell structure on thermopower of liquid redox pairs
Recent advancements in thermogalvanic batteries offer a promising route to
efficient harvesting of low-grade heat with temperatures below 100 {\deg}C. The
thermogalvanic temperature coefficient {\alpha}, usually referred to as
effective thermopower, is the key parameter determining the power density and
efficiency of thermogalvanic batteries. However, the current understanding of
improving {\alpha} of redox pairs remains at the phenomenological level without
microscopic insights, and the development of electrolytes with high {\alpha}
largely relies on experimental trial and error. This work applies the free
energy perturbation method based on molecular dynamics simulations to predict
the {\alpha} of the {Fe^{3+}/Fe^{2+}} redox pair in aqueous and acetone
solutions. We showed that {\alpha} of the {Fe^{3+}/Fe^{2+}} redox pair can be
increased from 1.5{\pm}0.3 mV/K to 4.1{\pm}0.4 mV/K with the increased acetone
to water fraction. The predicted {\alpha} of {Fe^{3+}/Fe^{2+}} both in pure
water and acetone show excellent agreement with experimental values. By
monitoring the fluctuation of dipole orientations in the first solvation shell,
we discovered a significant change in the variance of solvent dipole
orientation between Fe^{3+} and Fe^{2+}, which can be a microscopic indicator
for large magnitudes of {\alpha}. The effect of acetone weight fraction in the
mixed acetone-water solvent on the {\alpha} of {Fe^{3+}/Fe^{2+}} is also
studied. Acetone molecules are found to intercalate into the first solvation
shell of the {Fe^{2+}} ion at high acetone fractions, while this phenomenon is
not observed in the solvation shell of the Fe^{3+} ion. Such solvation shell
structure change of {Fe^{2+}} ions contributes to the enhanced {\alpha} at high
acetone fractions. Our discovery provides atomistic insights into how solvation
shell order can be leveraged to develop electrolytes with high thermopower
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