1,114 research outputs found
Stability constants for some divalent metal ion/crown ether complexes in methanol determined by polarography and conductometry
Stability constants in methanol at 25.0°C were evaluated for the complexes of the divalent cations Ca2+, Ni2+, Zn2+, Pb2+, Mg2+, Co2+ and Cu2+ with the macrocyclic polyethers 15-crown-5 (15C5), 18-crown-6 (18C6), dicyclohexyl-18-crown-6 (DC18C6) and dibenzo-24-crown-8 (DB24C8). The log K values of the 1:1 complexes were generally in the range 2.1–4.2, which is low in comparison to the values of the corresponding crown ether/alkali metal ion complexes. M2L complexes were observed for the systems Pb2+/18C6, Pb2+/DC18C6, Ca2+/DC18C6 and Cu2+/D18C6, whereas ML2 complexes were found for Ca2+/18C6 and Cu2+/18C6. Within the series of complexes studied, there was no clear relationship between cation diameter and hole size
Instantaneous Bethe-Salpeter Equation and Its Exact Solution
We present an approach to solve a Bethe-Salpeter (BS) equation exactly
without any approximation if the kernel of the BS equation exactly is
instantaneous, and take positronium as an example to illustrate the general
features of the solutions. As a middle stage, a set of coupled and
self-consistent integration equations for a few scalar functions can be
equivalently derived from the BS equation always, which are solvable
accurately. For positronium, precise corrections to those of the Schr\"odinger
equation in order (relative velocity) in eigenfunctions, in order in
eigenvalues, and the possible mixing, such as that between () and
() components in () states as well, are
determined quantitatively. Moreover, we also point out that there is a
problematic step in the classical derivation which was proposed first by E.E.
Salpeter. Finally, we emphasize that for the effective theories (such as NRQED
and NRQCD etc) we should pay great attention on the corrections indicated by
the exact solutions.Comment: 4 pages, replace for shortening the manuscrip
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The durability of stabilized flue gas desulfurization sludge
The effects of freeze-thaw cycling on the strength and durability of samples of compacted, stabilized, wet flue gas desulfurization (FGD) by-products are reported. The results of laboratory tests show a clear relationship between higher water contents and increasing vulnerability to freeze-thaw effects. In the samples tested, water contents at or above 40% were characteristic of all the freeze-thaw specimens exhibiting low strengths. Lime content and curing time were also shown to have a marked influence on the durability of the FGD material. It was shown that samples can maintain good strength under freeze-thaw conditions provided 5% lime was added before compaction and the time from compaction to first freeze was at least 60 days
Recommended from our members
The durability of stabilized flue gas desulfurization sludge
The effects of freeze-thaw cycling on the strength and durability of samples of compacted, stabilized, wet flue gas desulfurization (FGD) by-products are reported. The results of laboratory tests show a clear relationship between higher water contents and increasing vulnerability to freeze-thaw effects. In the samples tested, water contents at or above 40% were characteristic of all the freeze-thaw specimens exhibiting low strengths. Lime content and curing time were also shown to have a marked influence on the durability of the FGD material. It was shown that samples can maintain good strength under freeze-thaw conditions provided 5% lime was added before compaction and the time from compaction to first freeze was at least 60 days
The pseudogap state in superconductors: Extended Hartree approach to time-dependent Ginzburg-Landau Theory
It is well known that conventional pairing fluctuation theory at the Hartree
level leads to a normal state pseudogap in the fermionic spectrum. Our goal is
to extend this Hartree approximated scheme to arrive at a generalized mean
field theory of pseudogapped superconductors for all temperatures . While an
equivalent approach to the pseudogap has been derived elsewhere using a more
formal Green's function decoupling scheme, in this paper we re-interpret this
mean field theory and BCS theory as well, and demonstrate how they naturally
relate to ideal Bose gas condensation. Here we recast the Hartree approximated
Ginzburg-Landau self consistent equations in a T-matrix form. This recasting
makes it possible to consider arbitrarily strong attractive coupling, where
bosonic degrees of freedom appear at considerably above . The
implications for transport both above and below are discussed. Below
we find two types of contributions. Those associated with fermionic
excitations have the usual BCS functional form. That they depend on the
magnitude of the excitation gap, nevertheless, leads to rather atypical
transport properties in the strong coupling limit, where this gap (as distinct
from the order parameter) is virtually -independent. In addition, there are
bosonic terms arising from non-condensed pairs whose transport properties are
shown here to be reasonably well described by an effective time-dependent
Ginzburg-Landau theory.Comment: 14 pages, 5 figures, REVTeX4, submitted to PRB; clarification of the
diagrammatic technique added, one figure update
Measurement of hybrid content of heavy quarkonia using lattice NRQCD
Using lowest-order lattice NRQCD to create heavy meson propagators and
applying the spin-dependent interaction, , at varying intermediate time slices, we
compute the off-diagonal matrix element of the Hamiltonian for the
quarkonium-hybrid two-state system. Thus far, we have results for one set of
quenched lattices with an interpolation in quark mass to match the bottomonium
spectrum. After diagonalization of the two-state Hamiltonian, we find the
ground state of the to show a (with ) probability admixture of hybrid, .Comment: 11 pages, 4 figures, to appear in Phys Rev
Polaronic Signatures in Mid-Infrared Spectra: Prediction for LaMnO3 and CaMnO3
Hole-doped LaMnO3 and electron-doped CaMnO3 form self-trapped electronic
states. The spectra of these states have been calculated using a two orbital
(Mn eg Jahn-Teller) model, from which the non-adiabatic optical conductivity
spectra are obtained. In both cases the optical spectrum contains weight in the
gap region, whose observation will indicate the self-trapped nature of the
carrier states. The predicted spectra are proportional to the concentration of
the doped carriers in the dilute regime, with coefficients calculated with no
further model parameters.Comment: 6 pages with 3 figures imbedde
Magnetic and pair correlations of the Hubbard model with next-nearest-neighbor hopping
A combination of analytical approaches and quantum Monte Carlo simulations is
used to study both magnetic and pairing correlations for a version of the
Hubbard model that includes second-neighbor hopping as a
model for high-temperature superconductors. Magnetic properties are analyzed
using the Two-Particle Self-Consistent approach. The maximum in magnetic
susceptibility as a function of doping appears both at finite
and at but for two totally different physical reasons. When
, it is induced by antiferromagnetic correlations while at
it is a band structure effect amplified by interactions.
Finally, pairing fluctuations are compared with -matrix results to
disentangle the effects of van Hove singularity and of nesting on
superconducting correlations. The addition of antiferromagnetic fluctuations
increases slightly the -wave superconducting correlations despite the
presence of a van Hove singularity which tends to decrease them in the
repulsive model. Some aspects of the phase diagram and some subtleties of
finite-size scaling in Monte Carlo simulations, such as inverted finite-size
dependence, are also discussed.Comment: Revtex, 8 pages + 15 uuencoded postcript figure
Reduction of three-band model for copper oxides to single-band generalized t~-~J model
A three-band model for copper oxides in the region of parameters where the
second hole on the copper has energy close to the first hole on the oxygen is
considered. The exact solution for one hole on a ferromagnetic background of
the ordered copper spins is obtained. A general procedure for transformation of
the primary Hamiltonian to the Hamiltonian of singlet and triplet excitations
is proposed. Reduction of the singlet-triplet Hamiltonian to the single-band
Hamiltonian of the generalized t~-~J model is performed. A comparison of the
solution for the generalized t~-~J model on a ferromagnetic background with the
exact solution shows a very good agreement.Comment: 20 pages (LATEX
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