Synthesis and Characterization of PANI and Block Copolymer PANI-b-PEO Catalyzed by Maghnite (AlgerianMMT): Electrical and Electronic Domain

Polyaniline (PANI) and its block copolymer (PANI-PEO2000) has been prepared under effect of Maghnite-H+ (Algerian MMT) in different weight percentage (wt %) by cationic polymerization method. The structure of PANI and PANI-PEO2000 is predicted by the FT-IR and 1HNMR spectra. The thermal stability of homopolymer and block copolymer is confirmed by difference scanning calorimetry and analysis thermogravimetry. So after this results we can suggest that our heterogeneous catalyst called maghnite (Algerian MMT) can modified the morphology and the physical chemical properties of polyaniline (PANI) and its homolog block polyaniline-b-poly ethylene oxide (PANI-b-PEO2000) in the mild conditions under microwave irradiation

Electromagnetic Shielding Performance of a Metallic Enclosure with Apertures

International audienceGenerally, most of the electronic equipment need a metallic enclosure in order to mechanically protect and electrically shield the interior printed circuit boards (PCBs) and subsystems. But in practical situations, the apertures or slots of various forms are essential parts of the shielding enclosure for thermal dissipation, CD-ROMs, connectors, I/O cabling and so on. The performance of shielding enclosures for high-speed digital systems is compromised by these inevitable discontinuities on enclosure. To minimize the electromagnetic interferences and susceptibility risks by these discontinuities, the shielding enclosures with apertures should be designed based on thorough analysis about the electromagnetic coupling mechanism through apertures. In this paper, the effect of apertures and oblique incident plane wave on shielding effectiveness of the enclosure is studied with the Circuital Approach, and the Finite-Difference Time-Domain method, the simulated SE data are verified by experimental technique. Good agreements are found between these approaches

Analytical and numerical models compared with measurements for analysis of electromagnetic radiation through apertures of a metallic enclosure

International audienceGenerally, most of the electronic equipments need a metallic enclosure in order to mechanically protect and electrically shield the interior printed circuit boards (PCBs) and subsystems. But in practical situations, the apertures or slots of various forms are essential parts of the shielding enclosure for thermal dissipation, CD-ROMs, connectors, I/O cabling and so on. The performance of shielding enclosures for high-speed digital systems is compromised by these inevitable discontinuities on enclosure. To minimize the electromagnetic interferences and susceptibility risks by these discontinuities, the shielding enclosures with apertures should be designed based on thorough analysis about the electromagnetic coupling mechanism through apertures. In this paper, the effect of apertures and oblique incident plane wave on shielding effectiveness of the enclosure is studied with the Circuital Approach, and the Finite-Difference Time-Domain (FDTD) method, the simulated SE data are verified by experimental technique. Good agreements are found between these approaches

Measurement and three-dimensional calculation of induced electromotive force in permanent magnets heater cylinders

In this work, the electromotive force (EMF) near a permanent magnet heating cylinder was determined using a practical test bench. The aim is to elaborate three-dimensional analytical calculation capable of predicting accurately the same electromagnetic quantities by calculating the induced EMF in the presence of an inductive sensor. The analytical approach is obtained from developing mathematical integrals using the Coulombian approach to permanent magnets. In this approach, rotations are considered by Euler’s transformations matrices permitting the calculation of all permanent magnets flux densities contributions at the same points in the surrounding free space. These points, part of a uniform rectangular grid of the active EMF sensor surface, are used to compute the EMF by Faraday’s law. The validation results between experimental and simulated ones confirm the robustness and the efficiency of the proposed analytical approach

Structural and Chemical Analysis of New Cement Based on Eggshells and Sand from Dunes (Southern West of Algeria) Stabilized by PET

In this chapter, we present our study of geopolymers and hybrid geopolymers synthesized with treated fly ash from eggshells (FAES) and sand from the dunes of southern Algeria using activators such as NaOH and Na2SiO3, respectively, in addition to the organic polymer polyethylene terephthalate (PET). Several parameters have been modified, such as alkali concentration and percentage of activators and PET, with the objective to improve the quality of the desired geopolymers and hybrid geopolymers. The main objective of this work is to study the use of waste PET in the matrix of this new material to replace Portland cement, which is widely used today, as well as develop ecological building materials that are durable and lightweight and prevent chemicals from attacking old structures. Through optical and electron microscopy, we studied the effect of the addition of PET on the structure of our geopolymer material and on the bond and interface areas between the aggregates and the matrix. The microstructural analysis discussed here refers to specimens containing 5% PET by weight. We observed that PET contents significantly altered the structure and morphology of the samples

Synthesis and Characterization of Copolymers and Nanocomposites from Limonene, Styrene and Organomodified-Clay Using Ultrasonic Assisted Method

In the present work, we report a simple synthesis method for preparation of copolymers and nanocomposites from limonene and styrene using clay as a catalyst. The copolymerization reaction is carried out by using a proton exchanged clay as a catalyst called Mag-H+. The effect of temperature, reaction time and amount of catalyst were studied, and the obtained copolymer structure (lim-co-sty) is characterized by Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance spectroscopy (1H-NMR) and differential scanning calorimetry (DSC). The molecular weight of the obtained copolymer is determined by gel permeation chromatography (GPC) and is about 4500 g·mol−1. The (lim-co-sty/Mag 1%, 3%, 7% and 10% by weight of clay) nanocomposites were prepared through polymer/clay mixture in solution method using ultrasonic irradiation, in the presence of Mag-CTA+ as green nano-reinforcing filler. The Mag-CTA+ is organophilic silicate clay prepared through a direct exchange process, using cetyltrimethylammonuim bromide (CTAB). The prepared lim-co-sty/Mag nanocomposites have been extensively characterized by FT-IR spectroscopy, X-ray diffraction (XRD), scanning electronic microscopy (SEM) and transmission electronic microscopy (TEM). TEM analysis confirms the results obtained by XRD and clearly show that the obtained nanocomposites are partially exfoliated for the lower amount of clay (1% and 3% wt) and intercalated for higher amounts of clay (7% and 10% wt). Moreover, thermogravimetric analysis (TGA) indicated an enhancement of thermal stability of nanocomposites compared with the pure copolymer

Green Copolymers and Nanocomposites from Myrcene and Limonene Using Algerian Nano-Clay as Nano-Reinforcing Filler

In this work, we report a new facile method for the preparation of myrcene-limonene copolymers and nanocomposites using a Lewis acid as a catalyst (AlCl3) and organo-modified clay as a nano-reinforcing filler. The copolymer (myr-co-lim) was prepared by cationic copolymerization using AlCl3 as a catalyst. The structure of the obtained copolymer is studied and confirmed by Fourier Transform Infrared spectroscopy, Nuclear Magnetic Resonance spectroscopy, and Differential Scanning Calorimetry. By improving the dispersion of the matrix polymer in sheets of the organoclay, Maghnite-CTA+ (Mag-CTA+), an Algerian natural organophilic clay, was used to preparenanocomposites of linear copolymer (myr-co-lim). In order to identify and assess their structural, morphological, and thermal properties, the effect of the organoclay, used in varyingamounts (1, 4, 7, and 10% by weight), and the preparation process were investigated. The Mag-CTA+ is an organophylic montmorillonite silicate clay prepared through a direct exchange process in which they were used as green nano-reinforcing filler. The X-ray diffraction of the resulting nanocomposites revealed a considerable alteration in the interlayer spacing of Mag-CTA+. As a result, interlayer expansion and myr-co-lim exfoliation between layers of Mag-CTA+ were observed. Thermogravimetric analysis provided information on the synthesized nanocomposites’ thermal properties. Fourier transform infrared spectroscopy and scanning electronic microscopy, respectively, were used to determine the structure and morphology of the produced nanocomposites (myr-co-lim/Mag). The intercalation of myr-co-lim in the Mag-CTA+ sheets has been supported by the results, and the optimum amount of organoclay needed to create a nanocomposite with high thermal stability is 10% by weight. Finally, a new method for the preparation of copolymer and nanocomposites from myrcene and limonene in a short reaction time was developed