497 research outputs found

    Ī·-Ricci Soliton on 3-Dimensional f-Kenmotsu Manifolds

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    The object of the present paper is to carry out Ī·-Ricci soliton on 3-dimensional regularf-Kenmotsu manifold and we turn up some geometrical results. Furthermore we bring out the curvature conditions for which Ī·-Ricci soliton on such manifolds are shrinking, steady or expanding. We wind up by considering examples of existence of shrinking and expanding Ī·-Ricci soliton on 3-dimensional regularf-Kenmotsu manifolds

    Quinolinium Dichromate Oxidation of Aliphatic Aldehydes: A Kinetic Study

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    Kinetic data on the rates of quinolinium dichromate oxidation of a series of aliphatic aldehydes have been determined and discussed with reference to aldehyde hydration equilibria. Kinetic results support a pathway proceeding via a rate-determining oxidative decomposition of a chromate ester of an aldehyde hydrate. A cyclic transition state is suggested; being a HĆ¼ckel-type system (4n + 2), this would be an allowed process. The deuterium isotope effect for the oxidation of acetaldehyde (kH / kD = 6.4) indicated a carbon-hydrogen cleavage rather than a carbon-carbon cleavage

    Kinetics of Oxidation of Heterocyclic Compounds by Quinolinium Dichromate

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    Quinolinium dichromate in sulfuric acid oxidized heterocyclic aldehydes (to the corresponding acids) and heterocyclic carboxylic acids (to the corresponding hydroxy-substituted acids) in acetic acidwater medium (vol. ratio, v(water)/v(acetic acid) = 50:50). The kinetic results supported a mechanistic pathway proceeding via a rate-determining decomposition of the chromate ester

    Kinetics of Oxidation of Heterocyclic Compounds by Quinolinium Dichromate

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    Quinolinium dichromate in sulfuric acid oxidized heterocyclic aldehydes (to the corresponding acids) and heterocyclic carboxylic acids (to the corresponding hydroxy-substituted acids) in acetic acidwater medium (vol. ratio, v(water)/v(acetic acid) = 50:50). The kinetic results supported a mechanistic pathway proceeding via a rate-determining decomposition of the chromate ester
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