Rapid Determination of Cr³⁺ and Mn²⁺ in Water Using Laser-Induced Breakdown Spectroscopy Combined with Filter Paper Modified with Gold Nanoclusters

Excessive emissions of heavy metals not only cause environmental pollution but also pose a direct threat to human health. Therefore, rapid and accurate detection of heavy metals in the environment is of great significance. Herein, we propose a method based on laser-induced breakdown spectroscopy (LIBS) combined with filter paper modified with bovine serum albumin-protected gold nanoclusters (LIBS-FP-AuNCs) for the rapid and sensitive detection of Cr3+ and Mn2+. The filter paper modified with AuNCs was used to selectively enrich Cr3+ and Mn2+. Combined with the multi-element detection capability of LIBS, this method achieved the simultaneous rapid detection of Cr3+ and Mn2+. Both elements showed linear ranges for concentrations of 10–1000 μg L−1, with limits of detection of 7.5 and 9.0 μg L−1 for Cr3+ and Mn2+, respectively. This method was successfully applied to the determination of Cr3+ and Mn2+ in real water samples, with satisfactory recoveries ranging from 94.6% to 105.1%. This method has potential application in the analysis of heavy metal pollution

Development of a High Spectral Resolution Lidar for day-time measurements of aerosol extinction

Lidar technique is the most performing way to obtain the atmospheric vertical profile of aerosol optical properties with high space-time resolution. With elastic scattering lidars, the retrieval of aerosol optical properties (as the extinction profile) is realizable only with assumptions on aerosol extinction-to-backscatter ratio or with Raman measurement achievable in night-time. In order to overcome these problems, the High Spectral Resolution Lidar (HSRL) technique has been examined. In this paper we present an innovative prototype of High Spectral Resolution Lidar realized at Physics Department of University “Federico II” of Naples for the LISA (LIdar for Space study of the Atmosphere) project in the framework of the China-Italy international cooperation between CNISM and BRIT. The prototype which represents a first step of a spaceborne HSRL, is based on a laser source at 1064nm and 532nm with high spectral resolution ability at 532nm. The separation between the molecular and the aerosol components was obtained through the use of a confocal Fabry-Perot interferometer (CFPI) cavity

Calibration of Multi-wavelength Raman Polarization Lidar

The current high energy cosmic ray detection technology, including Cherenkov telescopes and fluorescence detector, is mainly limited by uncertainties in the determination of atmospheric parameters. LIDARs are currently the best suited technology to get atmospheric parameters for the atmosphere correction of high energy cosmic ray observatory data with one single instrument. A new Multi-wavelength Raman Polarization Lidar (AMPLE) has been developed and introduced in this paper. In order to provide precise and accurate results, lidar system should be calibrated before using for atmosphere correction in cosmic rays observatory. The calibration methods and results of AMPLE have been presented, including overlap function calibration, multi-wavelength channel calibration, depolarization calibration. In order to verify the accuracy of parameter measured by AMPLE lidar system, the comparison with radio sounder and sun-photometer has been done. The results show AMPLE lidar system has the ability to precisely measure the vertical profile of the atmosphere properties without any assumption and is a good choice for cosmic rays observatory to get atmosphere correction information

Development of a High Spectral Resolution Lidar for day-time measurements of aerosol extinction

Lidar technique is the most performing way to obtain the atmospheric vertical profile of aerosol optical properties with high space-time resolution. With elastic scattering lidars, the retrieval of aerosol optical properties (as the extinction profile) is realizable only with assumptions on aerosol extinction-to-backscatter ratio or with Raman measurement achievable in night-time. In order to overcome these problems, the High Spectral Resolution Lidar (HSRL) technique has been examined. In this paper we present an innovative prototype of High Spectral Resolution Lidar realized at Physics Department of University “Federico II” of Naples for the LISA (LIdar for Space study of the Atmosphere) project in the framework of the China-Italy international cooperation between CNISM and BRIT. The prototype which represents a first step of a spaceborne HSRL, is based on a laser source at 1064nm and 532nm with high spectral resolution ability at 532nm. The separation between the molecular and the aerosol components was obtained through the use of a confocal Fabry-Perot interferometer (CFPI) cavity