Hydrochemistry and source apportionment of boron, sulfate, and nitrate in the Fen River, a typical loess covered area in the eastern Chinese Loess Plateau

Fen River Basin (FRB) is water-deficient and strongly influenced by human activities in the eastern Chinese Loess Plateau. The spatio-temporal variation and controlling factors of hyrochemistry and quality, sources of high boron, sulfate, and nitrate of surface waters in FRB were unclear. Major ions, delta 11B, delta 15N, and delta 18O in surface waters in dry season and wet season of FRB were analyzed and correlation analysis (CA), principal component analysis (PCA), self-organizing map (SOM), forward model, and Bayesian isotope mixing model (MixSIAR) were used to solve above problems. Results showed that average riverine delta 11B, delta 15N, and delta 18O of FRB was 7.8%o, 11.2%o, and 1.3%o (1SD), respectively. Dissolved solutes ranked midstream > downstream > upstream with water type of Na +-Cl-, Ca2+-Mg2+-Cl-, and Ca2+-HCO3-, respectively. Low dissolved solutes were in forest areas while high values were in cropland and city areas. SOM analysis indicated that hydrochemistry was both influenced by natural (upstream) and pollutional input (midstream and downstream) and variation between dry season and wet season was minor. The abnormally high boron concentrations were mainly from silicate weathering (43%) and evaporites dissolution of loess (32%), urban and industrial input contributed 15% of riverine boron. High SO42- (207 +/- 267 mg/L, 1SD) was mainly from sulfates. delta 15N and delta 18O analysis indicated that nitrification was the primary N cycling process. Further, MixSIAR showed that NO3- was mainly from municipal sewage (-67%) and the total contribution of chemical fertilizer and soil nitrogen was -30% with slightly higher values in upstream and wet season. Influenced by land-use types, evaporite dissolution, and anthropogenic input, water quality below midstream was worse and strict sewage reduction policies must be developed. This study highlights the significant influence of evaporite dissolution of loess and anthropogenic input (urban and industrial input for B and sewage for NO3- ) on hydrochemistry and water quality

Groundwater hydrochemistry, source identification and pollution assessment in intensive industrial areas, eastern Chinese loess plateau

Groundwater is essential for regional ecological-economic system and is an important resource of drinking water, especially in the Chinese Loess Plateau (CLP), where is a typical water-limited ecosystem. Groundwater quality deterioration will affect water security and exacerbate the water shortages. Groundwater hydrochemistry, pollution source apportionment, quality and health risks were evaluated based on analysis of major ions and selected trace elements in seasonal samples of the Fen River Basin (FRB) in the eastern CLP. Groundwaters in the FRB were mainly HCO3--Ca-2(+)-Na+ water type with low dissolved solutes in upstream samples, high values in midstream samples and medium values in downstream samples. Solutes in upstream samples were mainly derived from carbonate weathering, while those in midstream and downstream samples came from silicate weathering, evaporites dissolution and anthropogenic sources. Self-organizing map (SOM) showed the hydrochemistry remained unchanged from dry to wet season for most sampling points. The seasonal variations of Ag, Cd, Ni, Pb, and Tl were significant due to anthropogenic input. High NO3- in upstream and downstream samples resulted primarily from sewage discharge, and high SO42- in midstream and downstream samples was from gypsum- and coal-related industries. In addition, anthropogenic input related to coal industries significantly aggravates pollution of As, Ni, Ag, Fe, and Mn. Influenced by evaporites and anthropogenic input, midstream samples had high salinity, total hardness and water quality indices (WQIs) and were unsuitable for irrigation or drinking purposes. Seasonal variation of WQI in the FRB was unsignificant except Jiaokou River sub-basin, where groundwater quality was worse in the wet season than the dry season due to coal mining. Great attention should be paid to the high non-carcinogenic risks of exposure to F, V, Mn, and Cr via dermal absorption, particularly for children. Overall, groundwater quality in the FRB was best in upstream, medium in midstream and worst in midstream based on different index. Groundwater quality is deteriorated by anthropogenic input and the sewage discharge in the FRB should be strictly controlled. Our report provides a reference for groundwater pollution evaluation and source identification in similar areas. (c) 2021 Elsevier Ltd. All rights reserved

Spatiotemporal variations, sources, water quality and health risk assessment of trace elements in the Fen River

As the largest river in Shanxi Province, the Fen River is the main water source for regional economic and ecological development. Water deficiency and industrialization have led to serious water pollution in the Fen River. The major and trace elements of seasonal river waters were measured to determine the spatiotemporal variations and assess the water quality as well as its controlling factors in the Fen River. Trace elements are divided into high abundance elements (B, Ba, Li, and Mn) and low abundance elements (As, Cu, Fe, Ni, Rb, Se, U, and V). The spatial variation of trace elements is obvious, with low values upstream, intermediate values downstream, and very high values midstream. The average values of the trace elements showed different seasonal variations, with high values of As, B, Ba, Mn, and Rb in the wet season, high Cu, V, and Li values in the dry season, and minor seasonal variations of Fe, Ni, Se, and U concentrations. Principal component analysis (PCA) and correlation analysis (CA) showed natural origins of Eta, Mn, Ni, and U, a nthropogenic input of As, B, Cu, Li, Rb, Se, and V. According to the results of absolute principal component sore-multivariate linear regression (APCS-MLR), the major pollution sources in the Fen River basin were related to human activities. The land use type significantly influenced the concentrations of trace elements, with high values in the cropland and low values in the forest. The water quality index (WQI) values were higher in the midstream and wet season. In comparison with other rivers in the world, the pollution of the Fen River is at a moderate level. Health risk assessment showed that As, Ba, Mn, Ni, V, and Se were the potential pollutants damaging in the Fen River, especially for children. This study highlights the importance of seasonal sample analysis and can provide vital data for water quality conservation in the Fen River basin. (C) 2020 Elsevier B.V. All rights reserved