3 research outputs found
Resonant x-ray diffraction study of the magnetoresistant perovskite Pr0.6Ca0.4MnO3
We report a x-ray resonant diffraction study of the perovskite
Pr0.6Ca0.4MnO3. At the Mn K-edge, this technique is sensitive to details of the
electronic structure of the Mn atoms. We discuss the resonant x-ray spectra
measured above and below the charge and orbital ordering phase transition
temperature (TCOO = 232 K), and present a detailed analysis of the energy and
polarization dependence of the resonant scattering. The analysis confirms that
the structural transition is a transition to an orbitally ordered phase in
which inequivalent Mn atoms are ordered in a CE-type pattern. The Mn atoms
differ mostly by their 3d orbital occupation. We find that the charge
disproportionation is incomplete, 3d^{3.5-\delta} and 3d^{3.5+\delta} with
\delta\ll0.5 . A revised CE-type model is considered in which there are two Mn
sublattices, each with partial e_{g} occupancy. One sublattice consists of Mn
atoms with the 3x^{2}-r^{2} or 3y^{2}-r^{2} orbitals partially occupied, the
other sublattice with the x^{2}-y^{2} orbital partially occupied.Comment: 15 pages, 15 figure
MAGNETISM OF A TWO-DIMENSIONAL XY SYSTEM : NEUTRON STUDIES OF CoCl2 INTERCALATED GRAPHITE
We present the results of magnetic neutron diffraction studies on a single crystal of a first stage CoCl2 intercalated graphite by elastic and inelastic techniques versus temperature. We deduce the magnetic couplings and the presence of defects such as vortices, related to the 2D XY nature of the compound