A model study of a homogeneous light-water thorium reactor

This work presents a computational study of a 232 Th -based homogeneous light-water reactor. Thorium reactors have been proposed as an alternative to the uranium fuel cycle since they exploit both the availability of thorium and its ability to afford fissile uranium isotopes by a sequence of neutron captures. Besides 233 U , as a result of the neutron captures, a significant amount of 234 U (36.3%) and 6.46% of 235 U are formed in the reactor under study. More importantly, the proposed simulation points out the possibility of a continuous withdrawal of the uranium isotopes without compromising the criticality and the power output of the reactor. This withdrawal affords the fissile material for the startup of reactors other than the first one, which requires a one-time only limited amount of fissile material. The significant molar fraction of the 234 U (0.17) in the extracted fuel does not pose a limitation on weapon proliferation, as a consequence of its high fission cross section for high-energy neutrons

On the Physical and Evolutionary Limits to the Rates of Enzyme-Catalyzed Reactions

An existing model for the rate coefficients of enzyme-catalyzed processes involves the regularized gamma function of Euler replacing the exponential dependence of the rate coefficient from the reaction barrier. The application of this model to experimental data, on one hand, validates the model by correctly describing the negative curvature of Eyring plots. On the other hand, this analysis evidences that enzymes never reach the maximum theoretical efficiency, a counterintuitive fact that requires an explanation. This work interprets this evolutionary limit in terms of the necessity of living systems to achieve and maintain homeostasis. Further validation of the expression for the rate coefficients comes from the analysis of the discrepancy between the theoretically predicted energy difference between reactants and products in a chemical equilibrium and the corresponding value obtained by regression to the classical expression for the equilibrium constant. The discrepancy is resolved by making use of the proposed model

A Model Study on the Dynamics of the Amino Acid Content in Micrometeoroids during Atmospheric Entry

A model for the survival of the amino acid content in micrometeorites and its possible transformations upon atmospheric entry is described. Since any organic species released in the atmosphere at high altitudes would exhibit a limited lifetime with respect to the typical timescale for atmospheric mixing (due to the substantial radiation field of the early Sun), only the organic content inside the meteorites could have contributed to prebiotic chemistry. It is thus important to determine both the amino acid loss from meteorites, due to both degassing and chemical degradation, and the extent of the chemical transformation of amino acids subjected to the increased temperature due to friction with the atmosphere. According to the interplay between the potential energy barrier and the pre-exponential factor in rate coefficients, either diffusion or chemical processing might be the dominant process following the rising temperature upon atmospheric entry. The possibility of the elimination of water from glycine to form aminoketene, or CO2 to form methylamine, ultimately driven by gravitational energy, was examined along with the more conventional formation of a peptide bond between two glycine units to afford Gly–Gly. While retention, degassing, and decarboxylation are the fastest processes, each dominating in different ranges of the initial velocity and radius, the formation of either Gly–Gly from bimolecular water elimination or aminoketene from unimolecular water elimination appears to be negligible