Phosphorus recovery from wastewater and sludge

Wastewater and sludge are potential resource of phosphorus (P) for fertilizer production. One method of recovering phosphorus is via chemical precipitation. In the study, phosphorus was recovered from wastewater and sludge. First, hydrolysis was carried out to release the phosphorus in the sludge by the addition of 1.0M acid (sulfuric acid) or base (sodium hydroxide) solution mixed for three hours at 200 rpm. The hydrolyzed sludge was filtered, and the pH of the solution was adjusted to 9.0. Precipitation for both wastewater and hydrolyzed sludge solution was carried out using magnesium chloride hexahydrate (MgCl2•6H2O) and ammonium chloride (NH4Cl). The mixture was stirred for an hour for crystallization. Precipitates were allowed to settle for 24 hours before it was filtered and dried in an oven at 55-58oC for 24 hours. The dried sample was grinded and characterized using Fourier transform infrared spectroscopy (FTIR), x-ray fluorenscence (XRF), and scanning electron microscope with energy-dispersive x-ray spectroscopy(SEM-EDX)

Life cycle assessment of nutrient recovery strategies from domestic wastewaters to quantify environmental performance and identification of trade-offs

Abstract Increase in anthropogenic activities proliferated the consumption of resources such as phosphorus; and increase the adverse environmental impacts especially eutrophication on water resources such as lakes. Nutrient recovery from domestic wastewaters to produce a fertiliser has been explored to address these challenges in the context of a sustainable circular nutrient economy. Life cycle assessment (LCA) was performed to holistically assess the impacts of integrating a nutrient recovery system on wastewater and water resource management using Laguna de Bay, Philippines as the geographical boundary. The inventory was developed based on the results of the emerging nutrient recovery reactor operations and the application of the recovered fertiliser on the agricultural crops. The LCA results for the proposed scenario showed environmental benefits of about 83.6% freshwater eutrophication, 102.5% terrestrial ecotoxicity, 26.9% water consumption, 100.7% mineral resource scarcity, while the global warming potential is 95.4% higher than the baseline scenario. Results imply policy review for septage management, system optimisation, and evaluation of alternative methods of wastewater management, in terms of life cycle thinking and sustainability across the globe

A decision modelling approach for selection of biological nutrient removal systems for wastewater

This paper proposes a decision model built on a hierarchical network for optimal selection of biological nutrient removal systems (BNR) in wastewater treatment plants. BNR is an important component of a sustainable wastewater management wherein resource recovery from wastewater becomes an integral part of the municipal wastewater treatment plants (WTP). However, selection of the most appropriate technology or systems requires a multiple criteria analysis. This study focuses on the following criteria namely 1) Economic aspect; 2) Technical aspect; 3) Environmental Aspect; and 4) Space Requirement. The following alternatives were then evaluated: 1) 3 Stage Pho-redox (A2O); 2) 5 Stage Bardenpho (5BP); 3) University of Cape Town (UCT); 4) Virginia Initiative Plant; 5) Sequencing Batch Reactor (SBR); 6) Membrane Bioreactor (MBR). A fuzzy ANP approach with Monte Carlo simulation was used to derive the overall priorities of these alternatives. This decision modelling approach addresses the uncertainty and complexity involved in the selection of appropriate BNR in Metro Manila’s WTP

Life cycle assessment of a retrofit wastewater nutrient recovery system in Metro Manila

The increase in water pollution from nutrients like phosphorus and nitrogen has prompted the Philippine government to issue stringent regulatory standards for wastewater effluent quality. Hence, two alternatives are being proposed to be integrated in the current wastewater treatment plant in the Philippines: biological nutrient removal and nutrient recovery systems. Biological nutrient removal technologies (BNRT) utilize microorganisms to minimize the nutrient content in the effluent streams to the standard limit while leaving high nutrient concentrations to the sludge that is typically transported as waste to landfill. The nutrient recovery system aims to recover phosphorus and nitrogen in the form of struvite (NH4MgPO46H2O) fertiliser from sludge through chemical precipitation. The two proposed systems have been studied in other settings but their effectiveness has not been studied in the Metro Manila setting. There is a need to systematically assess the environmental effects brought about by the proposed systems in Metro Manila, whether beneficial or adverse, in the context of agriculture, food and energy consumption, and wastewater. A holistic evaluation of the environmental benefits and burdens was done using Life Cycle Assessment (LCA) framework considering a cradle-to-grave approach of three scenarios: 1) current wastewater treatment system scenario; 2) biological nutrient recovery technology; and 3) nutrient recovery system. The environmental impact assessment was done using IMPACT2002+ methodology with the following impact indicators: human health, ecosystem quality, climate change and resources. The life cycle assessment of the scenarios shows the potential of the proposed retrofit wastewater systems for Metro Manila that extends to a more sustainable approach in dealing with issues such as water pollution, climate change, resource depletion and even food security. Moreover, a baseline understanding of the food-water-energy-nutrient nexus in the Philippines was established which can be the basis for future life cycle sustainability assessment studies. © 2018, AIDIC Servizi S.r.l

A decision modelling approach for selection of biological nutrient removal systems for wastewater

This paper proposes a decision model built on a hierarchical network for optimal selection of biological nutrient removal systems (BNR) in wastewater treatment plants. BNR is an important component of a sustainable wastewater management wherein resource recovery from wastewater becomes an integral part of the municipal wastewater treatment plants (WTP). However, selection of the most appropriate technology or systems requires a multiple criteria analysis. This study focuses on the following criteria namely 1) Economic aspect; 2) Technical aspect; 3) Environmental Aspect; and 4) Space Requirement. The following alternatives were then evaluated: 1) 3 Stage Pho-redox (A2O); 2) 5 Stage Bardenpho (5BP); 3) University of Cape Town (UCT); 4) Virginia Initiative Plant; 5) Sequencing Batch Reactor (SBR); 6) Membrane Bioreactor (MBR). A fuzzy ANP approach with Monte Carlo simulation was used to derive the overall priorities of these alternatives. This decision modelling approach addresses the uncertainty and complexity involved in the selection of appropriate BNR in Metro Manila\u27s WTP. © The Authors, published by EDP Sciences, 2018

Integrated life cycle assessment-analytic hierarchy process (LCA-AHP) with sensitivity analysis of phosphorus recovery from wastewater in Metro Manila

© 2020 IOP Publishing Ltd. The adverse environmental impact caused by eutrophication has recently prompted the Philippine government to issue stringent regulatory standards for wastewater effluent quality. The involved stakeholders and industries are assessing the integration of biological nutrient removal (BNR) technologies in the current sewage treatment plant (STP) scenario. Moreover, efforts are being done to utilize wastewater as a resource such us recovery of nutrients as struvite fertilizer from the wastewater sludge. Since BNR and nutrient recovery systems are not yet integrated in STPs, the magnitude of the environmental impacts are yet to be evaluated in the Philippine setting. This study covers the holistic evaluation of the overall environmental performance scores of the following scenarios using a consequential Life Cycle Assessment (LCA) framework integrated with Analytic Hierarchy Process (AHP) in the context of Water-Energy-Food Nexus: 1) current STP scenario; 2) BNR technology; and 3) nutrient recovery system. The environmental impact assessment was done using IMPACT 2002+ methodology in terms of the following impact indicators: human health, ecosystem quality, climate change, resources, aquatic acidification, and aquatic eutrophication. Value judgments from relevant stakeholders were elicited to rank the relative importance of the impact indicators in the evaluation of the overall environmental performance score. The LCA-AHP results show that the integration of a nutrient recovery system is the most preferred scenario. Sensitivity analysis was also done to evaluate the effects of changes in diet and utilization of alternative energy

A Perception Study of an Integrated Water System Project in a Water Scarce Community in the Philippines

The Integrated Water System (IWS) offers alternative water and sanitation services that can potentially benefit rural communities experiencing water scarcity. The IWS described in this study comprises three systems: The Rainwater Harvesting System (RWHS), Water Treatment System (WTS), and Eco-Toilet System (ETS). RWHS and WTS make use of rainwater, which can be utilized for several domestic uses, especially during wet season. ETS has several benefits to users including promotion of environmental and public health, as well as food security. Despite the potential benefits of the IWS components, the perceived acceptance of its users threatens the success of its implementation. This study focuses on determining the significant factors that can influence the social acceptance of IWS in the Municipality of Mulanay, Quezon Province, Philippines. This study considers behavioral intention as an indicator of social acceptance of the IWS components. The framework of this study is based on the combined technology acceptance model and theory of planned behavior (C-TAM-TPB) concept. C-TAM-TPB was analyzed using Partial Least Square–Structural Equation Modeling (PLS–SEM). The result of the C-TAM-TPB evaluation reveals that the user’s attitude towards use (ATU), including its significant predictors, can promote behavioral intention towards use of the IWS components. This study can further improve the development of IWS projects

A perception study of an integrated water system project in a water scarce community in the Philippines

© 2019 by the authors. The Integrated Water System (IWS) offers alternative water and sanitation services that can potentially benefit rural communities experiencing water scarcity. The IWS described in this study comprises three systems: The Rainwater Harvesting System (RWHS), Water Treatment System (WTS), and Eco-Toilet System (ETS). RWHS and WTS make use of rainwater, which can be utilized for several domestic uses, especially during wet season. ETS has several benefits to users including promotion of environmental and public health, as well as food security. Despite the potential benefits of the IWS components, the perceived acceptance of its users threatens the success of its implementation. This study focuses on determining the significant factors that can influence the social acceptance of IWS in the Municipality of Mulanay, Quezon Province, Philippines. This study considers behavioral intention as an indicator of social acceptance of the IWS components. The framework of this study is based on the combined technology acceptance model and theory of planned behavior (C-TAM-TPB) concept. C-TAM-TPB was analyzed using Partial Least Square-Structural Equation Modeling (PLS-SEM). The result of the C-TAM-TPB evaluation reveals that the user\u27s attitude towards use (ATU), including its significant predictors, can promote behavioral intention towards use of the IWS components. This study can further improve the development of IWS projects

Phosphorus recovery from wastewater and sludge

Wastewater and sludge are potential resource of phosphorus (P) for fertilizer production. One method of recovering phosphorus is via chemical precipitation. In the study, phosphorus was recovered from wastewater and sludge. First, hydrolysis was carried out to release the phosphorus in the sludge by the addition of 1.0M acid (sulfuric acid) or base (sodium hydroxide) solution mixed for three hours at 200 rpm. The hydrolyzed sludge was filtered, and the pH of the solution was adjusted to 9.0. Precipitation for both wastewater and hydrolyzed sludge solution was carried out using magnesium chloride hexahydrate (MgCl2•6H2O) and ammonium chloride (NH4Cl). The mixture was stirred for an hour for crystallization. Precipitates were allowed to settle for 24 hours before it was filtered and dried in an oven at 55-58oC for 24 hours. The dried sample was grinded and characterized using Fourier transform infrared spectroscopy (FTIR), x-ray fluorenscence (XRF), and scanning electron microscope with energy-dispersive x-ray spectroscopy(SEM-EDX)

A stochastic fuzzy multi-criteria decision-making model for optimal selection of clean technologies

Selection of clean technology options requires systematic evaluation based on multiple criteria which are often conflicting. The optimal choice should consider not just technical performance but also the economic, environmental and social aspects of technologies. Furthermore, the interdependencies of these aspects should also be considered. The decision-maker often needs to make explicit trade-offs while ranking the alternatives. In addition, data gaps and imprecise information that are typical when dealing with emerging technologies make conventional methods ineffective. This work thus proposes a Stochastic Fuzzy Analytic Hierarchical Network Process decision model to address the complexity and uncertainty involved in the clean technology selection process. This method first decomposes the problem into a hierarchical network structure, and then derives the probability distribution of the priority weights needed for ranking. The capabilities of the methodology are demonstrated with three case studies, involving the comparison of different carbon nanotube synthesis methods, nutrient removal treatment technology options for municipal wastewater, and low-carbon electricity sources in the Philippines. © 201