On the positivity of MSbar parton distributions

We revisit our argument that shows that parton distribution Functions (PDFs) in the MSbar{ scheme are non-negative in the perturbative region, with the main goals of elucidating its domain of validity and clarifying its theoretical underpinnings. We specifically discuss recent results proving that PDFs can turn negative at sufficiently low scale, we clarify quantitatively various aspects of our derivation of positivity in the perturbative region, and we provide an estimate for the scale above which PDF positivity holds

Crown-Ether Functionalized Graphene Oxide Membrane for Lithium Recovery from Water

The massive worldwide transition of the transport sector to electric vehicles has dramatically increased the demand for lithium. Lithium recovery by means of ion sieves or supramolecular chemistry has been extensively studied in recent years as a viable alternative approach to the most common extraction processes. Graphene oxide (GO) has also already been proven to be an excellent candidate for water treatment and other membrane related applications. Herein, a nanocomposite 12-crown-4-ether functionalized GO membrane for lithium recovery by means of pressure filtration is proposed. GO flakes were via carbodiimide esterification, then a polymeric binder was added to improve the mechanical properties. The membrane was then obtained and tested on a polymeric support in a dead-end pressure setup under nitrogen gas to speed up the lithium recovery. Morphological and physico-chemical characterizations were carried out using pristine GO and functionalized GO membranes for comparison with the nanocomposite. The lithium selectivity was proven by both the conductance and ICP mass measurements on different sets of feed and stripping solutions filtrated (LiCl/HCl and other chloride salts/HCl). The membrane proposed showed promising properties in low concentrated solutions (7 mg(Li)/L) with an average lithium uptake of 5 mg(Li)/g in under half an hour of filtration time

PDMS/Polyimide Composite as an Elastomeric Substrate for Multifunctional Laser-Induced Graphene Electrodes

Laser-induced graphene (LIG) emerged as one of the most promising materials for flexible functional devices. However, the attempts to obtain LIG onto elastomeric substrates never succeed, hindering its full exploitation for stretchable electronics. Herein, a novel polymeric composite is reported as a starting material for the fabrication of graphene-based electrodes by direct laser writing. A polyimide (PI) powder is dispersed into the poly(dimethylsiloxane) (PDMS) matrix to achieve an easily processable and functional elastomeric substrate, allowing the conversion of the polymeric surface into laser-induced graphene (LIG). The mechanical and electrical properties of the proposed material can be easily tuned by acting on the polyimide powder concentration. The reported procedure takes advantage from the simple casting process, typical of silicone elastomer, allowing to produce electrodes conformable to any kind of shape and surface as well as complex three-dimensional structures. Electrochemical capacitors and strain gauges are selected as flexible prototypes to demonstrate the multifunctional properties of the obtained LIG on the PDMS/PI composite substrate

Production of Graphene Stably Dispersible in Ethanol by Microwave Reaction

Graphene is a 2D carbon material with peculiar features such as high electrical conductivity, high thermal conductivity, mechanical stability, and a high ratio between surface and thickness. Applications are continuously growing, and the possibility of dispersing graphene in low-boiling green solvents could reduce its global environmental impact. Pristine graphene can be dispersed in high concentration only in polar aprotic solvents that usually have high boiling points and high toxicity. For this reason, the oxidized form of graphene is always used, as it is easier to disperse and to subsequently reduce to reduced graphene oxide. However, compared to pristine graphene, reduced graphene oxide has more defects and has inferior properties respect to graphene. In this work, the polymerization of (diethyl maleate derivate) on graphene obtained by sonication was performed in a microwave reactor. The obtained material has good stability in ethanol even after a long period of time, therefore, it can be used to deposit graphene by mass production of inks or by casting and easy removal of the solvent. The thermal annealing by heating at 300–400 ◦C in inert atmosphere allows the removal of the polymer to obtain pristine graphene with a low number of defects

Parton Distributions and New Physics Searches: the Drell-Yan Forward-Backward Asymmetry as a Case Study

We discuss the sensitivity of theoretical predictions of observables used in searches for new physics to parton distributions (PDFs) at large momentum fraction $x$. Specifically, we consider the neutral-current Drell-Yan production of gauge bosons with invariant masses in the TeV range, for which the forward-backward asymmetry of charged leptons from the decay of the gauge boson in its rest frame is a traditional probe of new physics. We show that the qualitative behaviour of the asymmetry depends strongly on the assumptions made in determining the underlying PDFs. We discuss and compare the large-$x$ behaviour of various different PDF sets, and find that they differ significantly. Consequently, the shape of the asymmetry observed at lower dilepton invariant masses, where all PDF sets are in reasonable agreement because of the presence of experimental constraints, is not necessarily reproduced at large masses where the PDFs are mostly unconstrained by data. It follows that the shape of the asymmetry at high masses may depend on assumptions made in the PDF parametrization, and thus deviations from the traditionally expected behaviour cannot be taken as a reliable indication of new physics. We demonstrate that forward-backward asymmetry measurements could help in constraining PDFs at large $x$ and discuss the accuracy that would be required to disentangle the effects of new physics from uncertainties in the PDFs in this region.Comment: 27 pages, 20 figure

High rejection stacked single-layer graphene membranes for water treatment

Nowadays, the production of pure water from saltwater and wastewater is one of the most challenging issues. Polymeric materials represent, at the moment, the best solution for membranes technology but new materials with improved functionalities are desirable to overcome the typical limitations of polymers. In this work, graphene membranes with superior filtration properties are fabricated by stacking up to three graphene layers on a porous support and exploiting the intrinsic nanopores of graphene to filter diclofenac (drug), and methylene blue (dye). The rejection improves increasing the number of the stacked graphene layers, with the best results obtained with three graphene layers. Mass diffusion properties depend on the size of the probe molecule, consistently with the existence of intrinsic nanometer-sized pores within graphene. From the results of an in depth transmission electron microscopy analysis and molecular dynamics simulations it is inferred that graphene stacking results in a decrease of effective membrane pore sizes to about 13 Å diameter which corresponds to 97% rejection for diclofenac and methylene blue after one hour filtration

Flexible and Floating Photovoltaics

We present our results on dye sensitized solar cells (DSSCs) for flexible or floating photovoltaic devices. In these works, we used polymer electrolyte membranes and metal grids as electrodes substrates in order to preserve the flexibility of the entire structure. These cells aim to be competitive in the near future solar market due to the extremely low cost and easiness of processing. Moreover, they evidently improve their conversion efficiency under low illumination conditions. This feature makes flexible DSSCs extremely interesting to be exploited in particular applications. In addition, we also introduce a smart integration of a DSSC with an electrical double layer capacitor (EDLC) which employs graphene nanoplatelets as active material in a completely flexible architecture. To the best of our knowledge this harvesting-storage (HS) device has the best overall photon-to-electrical conversion and storage efficiency ever attained to date for a flexible DSSC-based non-wired integrated HS device. Noteworthy, this value increases lowering the radiation intensity, thus showing optimal performances in real operation or indoor conditions

New Transparent Laser-Drilled Fluorine-doped Tin Oxide covered Quartz Electrodes for Photo-Electrochemical Water Splitting

A new-designed transparent, conductive and porous electrode was developed for application in a compact laboratory-scale proton exchange membrane (PEM) photo-electrolyzer. The electrode is made of a thin transparent quartz sheet covered with fluorine-doped tin oxide (FTO), in which an array of holes is laser-drilled to allow water and gas permeation. The electrical, morphological, optical and electrochemical characterization of the drilled electrodes is presented in comparison with a non-drilled one. The drilled electrode exhibits, in the visible region, a good transmittance (average value of 62%), a noticeable reflectance due to the light scattering effect of the hole-drilled internal region, and a higher effective surface area than the non-drilled electrode. The proof-of-concept of the applicability of the drilled electrode was achieved by using it as a support for a traditional photocatalyst (i.e. commercial TiO2 nanoparticles). The latter, coupled with a polymeric electrolyte membrane (i.e.Nafion 117) and a Pt counter electrode, forms a transparent membrane electrode assembly (MEA), with a good conductivity, wettability and porosity. Electrochemical impedance spectroscopy (EIS) was used as a very powerful tool to gain information on the real active surface of the new drilled electrode and the main electrochemical parameters driving the charge transfer reactions on it. This new electrode architecture is demonstrated to be an ideal support for testing new anodic and cathodic photoactive materials working in tandem configuration for solar fuels production by water photo-electrolysis