5 research outputs found
Preparation and catalytic properties of palladium(0) and rhodium(I) complexes containing new chiral P,N-ligands derived from carbohydrates
No full textStability and reactivity of the cis-{PtIIR(alkyne)} fragment (R= alkyl): an unprecedented rearrangement to form the {PtII(allyl)} moiety
No full textFirst coordinatively saturated carbene complexes of Pt(II): synthesis, structure and reactivity
No full textCoordination modes of cis-P,P'-diphenyl-1,4-diphospha-cyclohexane to metal ions of Groups 9 and 10
No full textHydrophilic ligands derived from glucose: synthesis, characterization and invitro cytotoxic activity on cancer cells of Pt(II) complexes
No full textAiming to contribute to the design of new antitumoral drugs, we synthesized new hydrophilic Pt(II) complexes
of general formula [PtCl2(N,N0)] containing nitrogen bidentate amine–imine and di-imine ligands
derived from glucose. Some chemical properties were discussed. The X-ray molecular structure of
[PtCl2(a-D-glucopyranoside-methyl-6-deoxy-6(2-(methylimino)methyl)pyridine) (D) was reported. [Pt
Cl2(b-D-glucopyranosylimine-N-(2-pyridinylmethyl))] (A), which is well-soluble both in organic solvents
and in water, was tested for cytotoxicity
