Effect of Design Features and Operating Conditions on the Performance of a Bipolar Membrane-Based Acid/Base Flow Battery

In the context of renewable energy sources, storage systems have been proposed as a solution to the issues related to fluctuations in the production and consumption of electric power. The EU funded BAoBaB project is aimed at developing the Acid/Base Flow battery (AB-FB), an environment-friendly, cost-competitive, grid-scale battery storage system based on the cyclic coupling of Bipolar Membrane ElectroDialysis (BMED) and its reverse, the Bipolar Membrane Reverse ElectroDialysis (BMRED) (Pärnamäe et al., 2020). Bipolar membranes promote catalytically water dissociation, thus allowing the storage of electric power in the form of acidic and alkaline solutions (pH gradient), obtained from their corresponding salt (charging mode - BMED), which are then recombined to provide electrical power (discharging mode - BMRED). The membranes are key elements for the process performance; however, the energy conversion efficiency is also affected by the operating parameters of the process and the design features of the stack. In this work, we performed a sensitivity analysis by a mathematical multi-scale model previously developed (Culcasi et al., 2020a). The performance of AB-FB systems was predicted, focusing on the Round Trip Efficiency. Results showed that proper design features made the effect of parasitic currents negligible. Moreover, proper operating conditions maximized the RTE up to 66%

Performance and Perspectives of an Acid/Base Flow Battery

Recently, the utilisation of renewable energy sources is a matter of increasing importance in Europe for Energy Transition and to achieve energy independence. To this aim, tailored Electric Energy Storage (EES) devices must be employed to tackle the issue of fluctuating production from renewables. The Acid/Base Flow Battery (AB-FB) is a cutting-edge technology that allows energy to be stored in the form of acidic and alkaline solutions (van Egmond et al., 2018). This method employs two membrane processes, one for the charge phase and one for the discharge phase, namely Electrodialysis with Bipolar Membrane (EDBM) and Reverse Electrodialysis with Bipolar Membrane (REDBM), respectively. The polymeric membranes and the two electrodes are the main components of this battery. The AB-FB is a novel technology, and a lot of effort is needed to properly assess its current and future potential and identify the geometrical and operating conditions maximising its performance. This study presents a techno-economic analysis (TEA) carried out by using technically optimal results from a previous bi-objective optimisation (Culcasi, et al., 2022b). By assessing the sensitivity on the input parameters, the Levelized Cost of Storage (LCOS) of a battery operating in closed-loop and using current commercial membranes spanned from 0.17 € kWh−1 to 0.45 € kWh−1, indicating that the AB-FB has significant potential in the commercial market

A comprehensive multi-scale model for bipolar membrane electrodialysis (BMED)

Bipolar membrane electrodialysis (BMED) is a technology combining solute and solvent dissociation to produce chemicals. In the recent decades, it has been typically studied for the production of valuable acid and base solutions from salt streams. Although many works have been devoted to the experimental investigation of BMED, only a few efforts have focused on its mathematical modelling. In the present work, a comprehensive process model based on a multi-scale approach with distributed parameters is presented for the first time. Five models related to four different dimensional scales were fully integrated to form a comprehensive tool. The integrated model was developed by using the process simulator gPROMS Model builder and was based on a semi-empirical approach combining high prediction accuracy and low computational demand. Once validated through a wide range of experimental data, the model capability was shown by carrying out a broad sensitivity analysis assessing the performance of the BMED technology for industrial-scale applications. Results showed how the performance of a BMED unit changes with both varying process conditions and the installed membrane area. Particularly, the non-ideal phenomena that reduce the produced NaOH concentration and increase the energy consumption were thoroughly investigated. Finally, this study demonstrated that a Levelized Cost Of Caustic Soda of about 280 € ton-1NaOH can be obtained, thus making this technology a possible candidate for the industrial production of caustic soda from brines in the future

A brine evaporative cooler/concentrator for autonomous thermal desalination units

In recent years growing attention has been paid to the problem of brine disposal due to the raising awareness of significant environmental issues related to the use of desalination processes for fresh water production. This is particularly relevant when desalination units are located in remote sites, characterised by major complexity in the construction and management of intake and outfall structures. In the present work a novel device, named brine evaporative cooler/concentrator (BECC, patent pending), has been developed for coupling with small-scale thermal desalination plants in order to reduce the problem of brine disposal. Such device fulfils two different functions: i) cooling of the recirculating brine (which is often mixed with cold seawater to feed the unit, acting first as a cooling medium for the condensation of the vapour) and ii) concentration of the brine to de disposed. The BECC device is based on the principle of evaporative cooling, i.e. a primary liquid stream is cooled by means of a secondary liquid stream (by-pass stream), which in turn evaporates in contact with atmospheric air, thus being cooled naturally. The two streams are separated by a heat-conductive surface, through which heat is transferred from the primary stream to the cooling-evaporating by-pass stream. A lab scale BECC pilot unit has been designed, constructed and tested. Geometrical and operating features have been studied in order to allow the operation with concentrated brines, to minimise problems of corrosion, scaling and fouling. The first results have demonstrated the feasibility of the technology and a larger scale prototype unit has been designed for the installation within a 5 m3/d solar membrane distillation unit to be constructed in Pantelleria Island, Italy

Electrodialysis with Bipolar Membranes for the Sustainable Production of Chemicals from Seawater Brines at Pilot Plant Scale

Environmental concerns regarding the disposal of seawater reverse osmosis brines require the development of new valorization strategies. Electrodialysis with bipolar membrane (EDBM) technology enables the production of acid and base from a salty waste stream. In this study, an EDBM pilot plant with a membrane area of 19.2 m2 was tested. This total membrane area results much larger (i.e., more than 16 times larger) than those reported in the literature so far for the production of HCl and NaOH aqueous solutions, starting from NaCl brines. The pilot unit was tested both in continuous and discontinuous operation modes, at different current densities (200-500 A m-2). Particularly, three different process configurations were evaluated, namely, closed loop, feed and bleed, and fed-batch. At lower applied current density (200 A m-2), the closed-loop had a lower specific energy consumption (SEC) (1.4 kWh kg-1) and a higher current efficiency (CE) (80%). When the current density was increased (300-500 A m-2), the feed and bleed mode was more appropriate due to its low values of SEC (1.9-2.6 kWh kg-1) as well as high values of specific production (SP) (0.82-1.3 ton year-1 m-2) and current efficiency (63-67%). These results showed the effect of various process configurations on the performance of the EDBM, thereby guiding the selection of the most suitable process configuration when varying the operating conditions and representing a first important step toward the implementation of this technology at industrial scale

CFD analysis of the fluid flow behavior in a reverse electrodialysis stack

Salinity Gradient Power by Reverse Electrodialysis (SGP-RE) technology allows the production of electricity from the different chemical potentials of two differently concentrated salty solutions flowing in alternate channels suitably separated by selective ion exchange membranes. In SGP-RE, as well as in conventional ElectroDialysis (ED) technology, the process performance dramatically depends on the stack geometry and the internal fluid dynamics conditions: optimizing the system geometry in order to guarantee lower pressure drops (DP) and uniform flow rates distribution within the channels is a topic of primary importance. Although literature studies on Computational Fluid Dynamics (CFD) analysis and optimization of spacer-filled channels have been recently increasing in number and range of applications, only a few efforts have been focused on the analysis of the overall performance of the process. In particular, the proper attention should be devoted to verify whether the spacer geometry optimization really represents the main factor affecting the overall process performance. In the present work, realized within the EU-FP7 funded REAPower project, CFD simulations were carried out in order to assess the effects of different parameters on the global process efficiency, such as the choice of spacer material and morphology, and the optimization of feed and blowdown distribution systems. Spacer material and morphology can affect the fluid dynamics inside each channel. In particular, the appropriate choice of net spacer material can influence the slip/no-slip condition of the flow on the spacer wires, thus significantly affecting the channel fluid dynamics in terms of pressure drops. A Unit Cell approach was adopted to investigate the effect of the different choices on the fluid flow along the channel. Also, the possibility of choosing a porous medium to substitute the net spacer was theoretically addressed. Such investigation focused on the porosity and the fiber radius required to respect the process constrains of pressure drops and mechanical stability. On the other hand, the overall pressure drops of a SGP-RE or ED stack can be considered as resulting from different contributions: the pressure drop relevant to the feed distributor, the pressure drop inside the channel, and the pressure drop in the discharging collector. The choice of the optimal stack geometry is, therefore, strongly related to the need of both minimizing each of the above terms and obtaining the most uniform feed streams distribution among the stack channels. In order to investigate such aspects, simulations were performed on a simplified ideal planar stack with either 50 spacer-less or 50 spacer-filled channels. The effect of the distribution/collector channel thickness and geometry on single-channel flow rates and overall pressure drops in the system was analyzed and a significant influence of distributor layout and size on the overall process performance was found

Experimental Analysis via Thermochromic Liquid Crystals of the Temperature Local Distribution in Membrane Distillation Modules

A reliable and optimized design of channels for Membrane Distillation (MD) requires knowledge of local temperature distributions within the module. This information is essential to measure the temperature polarization, choice the module configuration (net spacer features, channel size, etc) providing the best process performance. Notwithstanding such crucial aspects, only few studies have been devoted to the experimental characterization of MD channels and none of them includes data on the local temperature distribution. In the present work, an experimental technique based on the use of Thermochromic Liquid Crystals (TLCs) and digital image processing, previously proposed by the authors (Pitò et al., 2011), was further developed and employed in order to measure the temperature and local heat transfer coefficient distribution on the membrane surface in a MD spacer-filled channel. The performance of different types of commercial net spacers were tested. The channel provided with the symmetric net spacer was found to be the configuration leading to the best heat transfer and to the lowest temperature polarization

Towards 1 kW power production in a reverse electrodialysis pilot plant with saline waters and concentrated brines

Reverse electrodialysis (RED) is a promising technology to extract energy from salinity gradients, especially in the areas where concentrated brine and saline waters are available as feed streams. A first pilot-scale plant was recently built in Trapani (Italy), and tested with real brackish water and brine from saltworks. The present work focuses on the scale-up of the pilot plant, reaching more than 400 m2 of total membrane area installed and representing the largest operating RED plant so far reported in the literature. With a nominal power capacity of 1 kW, the pilot plant reached almost 700 W of power capacity using artificial brine and brackish water, while a 50% decrease in power output was observed when using real solutions. This reduction was likely due to the presence of non-NaCl ions in relatively large concentration, which negatively affected both the electromotive force and stack resistance. These results provide relevant and unique information for the RED process scale-up, representing the first step for the feasibility assessment of RED technology on large scale