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A metapopulation model with Markovian landscape dynamics
We study a variant of Hanski's incidence function model that allows habitat
patch characteristics to vary over time following a Markov process. The widely
studied case where patches are classified as either suitable or unsuitable is
included as a special case. For large metapopulations, we determine a recursion
for the probability that a given habitat patch is occupied. This recursion
enables us to clarify the role of landscape dynamics in the survival of a
metapopulation. In particular, we show that landscape dynamics affects the
persistence and equilibrium level of the metapopulation primarily through its
effect on the distribution of a local population's life span.Comment: This manuscript version is made available under the CC-BY-NC-ND 4.0
license http://creativecommons.org/licenses/by-nc-nd/4.0
Kinetics and mechanism of formic acid decomposition on Ru(001)
The steady-state rate of decomposition of formic acid on
Ru(001) has been measured as a function of surface temperature, parametric in the pressure of formic acid. The
products of the decomposition reaction are C0_2, H_2, CO,
and H_2)0, i.e., both dehydrogenation and dehydration occur
on Ru (001). A similar product distribution has been observed on Ni(110), Ni(100), Ru(100), Fe(100), and
Ni(111) surfaces; whereas only dehydrogenation to C0_2
and H_2 occurs on the Cu(100), Cu(110), and Pt(111)
surfaces. Only reversible adsorption and desorption of formic acid is observed on the less reactive Ag(110) surface at low temperatures, whereas the more reactive Mo(100) surface is oxidized by formic acid at low temperatures with the products of this reaction being H_2, CO, and H_(2)O (Ref. 10). We report here the confirmation of earlier observations of the occurrence of both dehydrogenation and dehydration of formic acid on Ru(001), and more importantly, we provide a detailed mechanistic description of the steady-state decomposition reaction on this surface in terms of elementary steps
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