Petrogenesis of Mafic to Felsic Lavas from the Oligocene Siebengebirge Volcanic Field (Germany): Implications for the Origin of Intracontinental Volcanism in Central Europe

Magmatism in the Cenozoic Central European Volcanic Province (CEVP) has been related to two geodynamic scenarios, either extensional tectonics in the north Alpine realm or upwelling of deep mantle material. The Oligocene (∼30-19 Ma) Siebengebirge Volcanic Field (SVF) is a major part of the German portion of the CEVP and consists of erosional remnants of mafic to felsic volcanic edifices. It covers an area of ∼35 km (NW-SE) by ∼25 km (SW-NE) with eruptive centres concentrated near the eastern shore of the Rhine river in the vicinity of the city of Bonn. Mafic rocks in the SVF comprise strongly SiO2-undersaturated basanites to alkaline basalts. Occurrences of alkaline basalts are confined to an inner NW-SE-striking zone, whereas the more SiO2-undersaturated basanites dominate the western and eastern periphery of the SVF. Radiogenic isotope compositions (87Sr/86Sr 0·70335-0·70371; εNd +3·1 to +4·5; εHf +6·5 to +8·0; 206Pb/204Pb 19·46-19·69; 207Pb/204Pb 15·63-15·66; 208Pb/204Pb 39·34-39·62) indicate a common asthenospheric mantle end-member with HIMU-like characteristics for all mafic rocks, similar to the European Asthenospheric Reservoir (EAR). A lithospheric mantle source component with a residual K-bearing phase (phlogopite or amphibole) is inferred from negative K anomalies. Incompatible trace element modelling indicates that melting took place in the spinel-garnet transition zone with low degrees of melting at higher pressures generating the basanitic magmas (LaN/YbN = 20-25), whereas the alkaline basalts (LaN/YbN = 14-18) are the result of higher melting degrees at shallower average melting depths. Differentiation of basanitic primary melts generated tephritic to tephriphonolitic magmas that, for instance, erupted at the Löwenburg Volcanic Complex in the central SVF. Latites and trachytes, such as the prominent Drachenfels and Wolkenburg protrusions, are more common in the central portion of the SVF. These compositions originate from parental alkaline basaltic melts. All differentiated samples show evidence for crustal contamination, possibly with lower- to mid-crustal material comprising mafic granulites as found in Eifel basalt xenoliths and metapelites. Based on the spatial and temporal distribution of the various volcanic rock types, a model for the temporal evolution of the SVF can be proposed. During the initial phase of volcanism, low-degree basanitic melts were generated as a result of decompression following tectonic rifting and formation of the Cologne Embayment, a northward extension of the Rhine Graben. In a second stage, alkali basalts were generated at shallower depths and higher degrees of melting as a result of continued lithospheric thinning and passive upwelling of asthenospheric mantle. These conclusions strengthen previous models suggesting that intraplate volcanism in Central Europe is directly linked to regional lithospheric thinning and asthenospheric upwelling. Overall, the SVF constitutes an exceptionally well-preserved magmatic assemblage to illustrate these tectono-magmatic relationship

Mass-independent Sn isotope fractionation and radiogenic 115Sn in chondrites and terrestrial rocks

Tin has ten stable isotopes, providing the opportunity to investigate and discriminate nucleosynthetic isotope anomalies from mass-dependent and mass-independent isotope fractionation. Novel protocols for chemical separation (based on TBP-resin) and MC-ICP-MS analyses are reported here for high precision Sn isotope measurements on terrestrial rocks and chondrites. Relative to the Sn reference standard (NIST SRM 3161a), terrestrial basalts and chondrites show isotope patterns that are consistent with mass-dependent and mass-independent isotope fractionation processes as well as with 115Sn radiogenic ingrowth from 115In. Two different mass-independent isotope effects are identified, namely the nuclear volume (or nuclear field shift) and the magnetic isotope effect. The magnetic isotope effect dominates in the two measured ordinary chondrites, while repeated analyses of the carbonaceous chondrite Murchison (CM2) display a pattern consistent with a nuclear volume effect. Terrestrial basalts show patterns that are compatible with a mixture of nuclear volume and magnetic isotope effects. The ultimate origin of the isotope fractionation is unclear but a fractionation induced during sample preparation seems unlikely because different groups of chondrites show distinctly different patterns, hence pointing towards natural geo/cosmochemical processes. Only the carbonaceous chondrite Murchison (CM2) shows a Sn isotope pattern similar to what expected for nucleosynthetic variations. However, this pattern is better reproduced by nuclear volume effects. Thus, after considering mass-independent and mass-dependent effects, we find no evidence of residual nucleosynthetic anomalies, in agreement with observations for most other elements with similar half-mass condensation temperatures. Most chondrites show a deficit in 115Sn/120Sn (typically −150 to −200 ppm) relative to terrestrial samples, with the exception of one ordinary chondrite that displays an excess of about +250 ppm. The 115Sn/120Sn data correlate with In/Sn, being consistent with the β− decay of 115In over the age of the solar system. This represents the first evidence of the 115In-115Sn decay system in natural samples. The radiogenic 115Sn signature of the BSE derives from a suprachondritic In/SnBSE, which reflects preferential partitioning of Sn into the Earth's core

Aluminum-26 Enrichment in the Surface of Protostellar Disks Due to Protostellar Cosmic Rays

The radioactive decay of aluminum-26 ($^{26}$Al) is an important heating source in early planet formation. Since its discovery, there have been several mechanisms proposed to introduce $^{26}$Al into protoplanetary disks, primarily through contamination by external sources. We propose a local mechanism to enrich protostellar disks with $^{26}$Al through irradiation of the protostellar disk surface by cosmic rays accelerated in the protostellar accretion shock. We calculate the $^{26}$Al enrichment, [$^{26}$Al/$^{27}$Al], at the surface of the protostellar disk in the inner AU throughout the evolution of low-mass stars, from M-dwarfs to proto-Suns. Assuming constant mass accretion rates, $\dot{m}$, we find that irradiation by MeV cosmic rays can provide significant enrichment on the disk surface if the cosmic rays are not completely coupled to the gas in the accretion flow. Importantly, we find that low accretion rates, $\dot{m} < 10^{-7}$ M$_{\odot}$ yr$^{-1}$, are able to produce canonical amounts of $^{26}$Al, $[^{26}{\rm Al}/^{27}{\rm Al}] \approx 5\times10^{-5}$. These accretion rates are experienced at the transition from Class I- to Class II-type protostars, when it is assumed that calcium-aluminum-rich inclusions condense in the inner disk. We conclude that irradiation of the inner disk surface by cosmic ray protons accelerated in accretion shocks at the protostellar surface may be an important mechanism to produce $^{26}$Al. Our models show protostellar cosmic rays may be a viable model to explain the enrichment of $^{26}$Al found in the Solar System.Comment: Accepted to ApJ, in pres

Diachronous collision in the Seve Nappe Complex: Evidence from Lu–Hf geochronology of eclogites (Norrbotten, North Sweden)

Agentúra na Podporu Výskumu a Vývoja, Grant/Award Number: APVV-18- 0107; Deutsche Forschungsgemeinschaft, Grant/ Award Number: FR700/18-1We thank Christopher Barnes (AGH University of Science and Technology, Kraków) for providing us with some of the studied samples. Kathrin Fassmer thanks Svenja Trapp and Matthias Hauke (University of Bonn) for help during Lu–Hf laboratory work. We would also like to thank M. Smit, F. Corfu and A. Kylander-Clark for their reviews which greatly contributed to improving the manuscript. This research was funded by DFG-Grant FR700/18-1 to N. F. and the Slovak Research and Development Agency project APVV-18- 0107 to M.J, and partially supported by the National Science Centre (Poland) project 2014/14/ST10/00321 to J. Majka. M.Bukała acknowledges The Polish National Agency for Academic Exchange for the scholarship no. PPN/ IWA/2018/1/00046/U/0001. This is contribution no. 64 of the DFG-funded LA-ICP- MS Laboratory at the Institute for Geosciences, University of Bonn, Germany.The collision of Baltica and Laurentia during the Caledonian Orogeny happened at c. 400-420 Ma. However, subduction and collision processes also took place before this main collisional phase and the tectonic history of these is still not fully resolved. The Seve Nappe Complex in Sweden has recorded these earlier phases. The Seve Nappe Complex in Norrbotten (North Swedish Caledonides) comprises four superimposed nappes emplaced by eastward thrusting (from base to top according to the conventional structural interpretation): Lower Seve Nappe, Vaimok, Sarek, and Tsakkok Lenses. Eclogites occur in the Vaimok and Tsakkok Lenses. The Vaimok Lens represents rocks of the Baltican continental margin intruded by Neoproterozoic dolerite dikes which were later eclogitized and boudinaged. By contrast, eclogites of the Tsakkok Lens are former oceanic basalts associated with calcschists, possibly representing the ocean-continent transition between Baltica and Iapetus. Previous age determinations for eclogitization yielded various ages between c. 500 and 480 Ma, in contrast to younger (460-450 Ma) ages of ultra high-P metamorphism in the Seve Nappe Complex further south in Jamtland. Eclogites from the Vaimok (one sample) and Tsakkok (three samples) lenses were dated using Lu-Hf garnet geochronology. Garnet from all samples shows prograde zoning of major element and Lu contents and yielded well-defined isochrons of the following ages: 480.4 +/- 1.2 Ma (Vaimok); 487.7 +/- 4.6 Ma, 486.2 +/- 3.2, 484.6 +/- 4.6 Ma (Tsakkok). The ages from Tsakkok are interpreted to date the burial of the Iapetus-Baltica ocean-continent transition in a west-dipping subduction zone around c. 485 Ma, and the age from the structurally deeper Vaimok Nappe the following subduction of the continental margin. Previously reported ages of 500 Ma and older are not supported by this study. The age difference between eclogites in the Seve Nappe Complex in Jamtland (c. 460-450 Ma) and Norrbotten (c. 488-480 Ma) may reflect the collision of an island arc with an irregularly shaped passive continental margin of Baltica or alternatively the collision of a straight margin with a microcontinent (Sarek Lens) accreted to the upper plate.Agentura na Podporu Vyskumu a Vyvoja APVV-18-0107German Research Foundation (DFG) FR700/18-

Temporal evolution of 142Nd signatures in SW Greenland from high precision MC-ICP-MS measurements

Measurements of 142Nd isotope signatures in Archean rocks are a powerful tool to investigate the earliest silicate differentiation events on Earth. Here, we introduce a new analytical protocol that allows high precision radiogenic and mass-independent Nd isotope measurements by MC-ICP-MS. To validate our method, we have measured well-characterized ∼3.72 to ∼3.8 Ga samples from the Eoarchean Itsaq Gneiss Complex and associated supracrustal belts, as well as Mesoarchean greenstones and a Proterozoic dike in SW Greenland, including lithostratigraphic units that were previously analyzed for 142-143Nd isotope systematics, by both TIMS and MC-ICP-MS. Our μ142Nd values for ∼3.72 to ∼3.8 Ga rocks from the Isua region range from +9.2 ± 2.6 to +13.2 ± 1.1 ppm and are in good agreement with previous studies. Using coupled 142,143Nd/144Nd isotope systematics from our data for ∼3.8 Ga mafic-ultramafic successions from the Isua region, we can confirm previous age constraints on the earliest silicate differentiation events with differentiation age of 4.390−0.060+0.045 Ga. Moreover, we can resolve a statistically significant decrease of 142Nd/144Nd isotope compositions in the ambient mantle of SW Greenland that already started to commence by Eoarchean time, between ∼3.8 Ga (μ142Nd = +13.0 ± 1.1) and ∼ 3.72 Ga (μ142Nd = +9.8 ± 1.0). Even lower but homogeneous μ142Nd values of +3.8 ± 1.1 are found in ∼3.4 Ga mantle-derived rocks from the Ameralik dike swarms. Our study reveals that ε143Nd(i) and εHf(i) values of Isua rocks scatter more than it would be expected from a single stage differentiation event as implied from nearly uniform μ142Nd values, suggesting that the previously described decoupling of Hf and Nd isotopes is not a primordial magma ocean signature. Instead, we conclude that some of second stage processes like younger mantle depletion events or recycling of subducted material affected the 147Smsingle bond143Nd isotope systematics. The preservation of pristine whole-rock isochrons largely rules out a significant disturbance by younger alteration events. Based on isotope and trace element modelling, we argue that the temporal evolution of coupled 142,143Nd/144Nd isotope compositions in the ambient mantle beneath the Isua rocks is best explained by the progressive admixture of material to the Isua mantle source that must have had present-day-like μ142Nd compositions. In contrast, Mesoarchean mafic rocks from the ∼3.08 Ga Ivisaartoq greenstone belt and the 2.97 Ga inner Ameralik Fjord region as well as a 2.0 Ga Proterozoic dike within that region all have higher μ142Nd values as would be expected from our simple replenishment model. This argues for reworking of older Isua crustal material that carried elevated μ142Nd compositions

Geodynamic implications of synchronous Norite and TTG formation in the 3 Ga Maniitsoq Norite Belt, West Greenland

This study was supported by Villum Fonden through grant VKR18978 to K.S. Funding for article fees was supplied by the Ministry of Mineral Resources, Government of Greenland.We present new data for the ∼3.0 Ga Maniitsoq Norite Belt of the Akia Terrane, West Greenland, with the aim of understanding its petrogenesis. The Maniitsoq Norite Belt is hosted in regional tonalite-trondhjemite-granodiorite (TTG) and dioritic orthogneisses, intruded by later sheets of TTG and granite pegmatites, and comprises two main rock types: plagioclase-rich “norites” and pyroxene-rich “melanorites”. Both norites and melanorites have high SiO2 contents (52–60 wt% SiO2), high bulk rock Mg# (0.57–0.83), and low TiO2 contents (0.1–0.7 wt%). Their trace element patterns are defined by depleted heavy Rare-Earth elements, highly enriched light Rare-Earth elements, negative anomalies in Nb, Ta, and Ti, and variable anomalies in Zr, Hf, and Eu. New zircon U-Pb geochronology data and previously published ages establish an emplacement age of 3,013 ± 1 Ma for the majority of the Maniitsoq Norite Belt, with magmatism continuing until 3,001 ± 3 Ma. This ∼12 Myr period of norite magmatism is coeval with an ongoing period of TTG production in the Akia Terrane. Norite Belt emplacement was closely followed by high temperature, low pressure granulite-facies metamorphism at ∼800°C and 900°C/GPa) and that the norite magmas were emplaced into thin crust and lithosphere. Compositions of the norites and melanorites can be explained by derivation from a single mafic parental melt (∼13 wt% MgO), with the norites predominantly accumulating plagioclase and the melanorites predominantly accumulating pyroxene. Evidence from field relationships, the presence of xenocrystic zircon, major element compositions and combined trace element and Hf-isotope modelling suggests the norites were contaminated by assimilation of ∼20–30% continental TTG crust. Geochemical and Hf-Nd isotopic constraints indicate that the norite mantle source was depleted, and that this depletion occurred significantly before the emplacement of the norite magmas. Contemporaneous production of both TTGs and norite, their emplacement in thin crust, and the rapid transition to high temperature, low pressure granulite-facies metamorphism is best explained by their formation in an ultra-hot orogeny. Formation of norites in this setting may be restricted to >2.7 Ga, when geothermal gradients were higher on Earth.Publisher PDFPeer reviewe

Upper mantle control on the W isotope record of shallow level plume and intraplate volcanic settings

Several studies have revealed small heterogeneities in the relative abundance of 182W, the radiogenic nuclide of short-lived 182Hf (t1/2 = ∼9 Ma), in terrestrial rocks. Whereas the majority of Archean rocks display 182W excesses relative to bulk silicate Earth, many young ocean island basalts show small 182W deficits, in particular if they are sourced from deep-rooted mantle plumes. The origin of this anomaly is still ambiguous, proposed models focus on core-mantle interaction or the presence of reservoirs in the lower mantle that have been isolated since the Hadean. In order to evaluate the role of upper mantle reservoirs, we report the first 182W data for intraplate basalts where a deep plume origin is still debated (Ascension Island, Massif Central, Siebengebirge and Eifel) and intraplate volcanic rocks associated with either plume or subduction zone environments (Italian Magmatic Provinces) and compare them to new data for basalts that have a deep mantle plume origin (La Réunion and Baffin Island). The proto-Iceland plume basalts from Baffin Island have uniform and modern mantle-like W of around 0 despite extremely high (3He/4He). In contrast, basalts from both volcanic edifices from La Réunion span a range from modern upper mantle values to deficits as low as W = −8.8 ppm, indicating a heterogeneous source reservoir. The W in all other intraplate volcanic provinces overlap the composition of modern upper mantle to within 3 ppm. The absence of resolvable 182W anomalies in these intraplate basalts, which partially tap the lithospheric mantle, suggests that primordial components are neither present in the central and southern European lithosphere nor in the European asthenospheric reservoir (EAR). The general absence of 182W anomalies in European plume-related basalts can either be explained by a shallow mantle source or by the absence of isotopically anomalous and isolated domains in the deep mantle beneath the northern hemisphere, as also suggested by geophysical evidence

Ruthenium isotopes show the Chicxulub impactor was a carbonaceous-type asteroid

An impact at Chicxulub, Mexico, occurred 66 million years ago, producing a global stratigraphic layer that marks the boundary between the Cretaceous and Paleogene eras. That layer contains elevated concentrations of platinum-group elements, including ruthenium. We measured ruthenium isotopes in samples taken from three Cretaceous-Paleogene boundary sites, five other impacts that occurred between 36 million to 470 million years ago, and ancient 3.5-billion- to 3.2-billion-year-old impact spherule layers. Our data indicate that the Chicxulub impactor was a carbonaceous-type asteroid, which had formed beyond the orbit of Jupiter. The five other impact structures have isotopic signatures that are more consistent with siliceous-type asteroids, which formed closer to the Sun. The ancient spherule layer samples are consistent with impacts of carbonaceous-type asteroids during Earth’s final stages of accretion