6 research outputs found
Relaxation kinetics in two-dimensional structures
We have studied the approach to equilibrium of islands and pores in two
dimensions. The two-regime scenario observed when islands evolve according to a
set of particular rules, namely relaxation by steps at low temperature and
smooth at high temperature, is generalized to a wide class of kinetic models
and the two kinds of structures. Scaling laws for equilibration times are
analytically derived and confirmed by kinetic Monte Carlo simulations.Comment: 6 pages, 7 figures, 1 tabl
Early stage morphology of quench condensed Ag, Pb and Pb/Ag hybrid films
Scanning Tunneling Microscopy (STM) has been used to study the morphology of
Ag, Pb and Pb/Ag bilayer films fabricated by quench condensation of the
elements onto cold (T=77K), inert and atomically flat Highly Oriented Pyrolytic
Graphite (HOPG) substrates. All films are thinner than 10 nm and show a
granular structure that is consistent with earlier studies of QC films. The
average lateral diameter, , of the Ag grains, however, depends on
whether the Ag is deposited directly on HOPG ( = 13 nm) or on a Pb
film consisting of a single layer of Pb grains ( = 26.8 nm). In
addition, the critical thickness for electrical conduction () of Pb/Ag
films on inert glass substrates is substantially larger than for pure Ag films.
These results are evidence that the structure of the underlying substrate
exerts an influence on the size of the grains in QC films. We propose a
qualitative explanation for this previously unencountered phenomenon.Comment: 11 pages, 3 figures and one tabl
Electromigration-Induced Flow of Islands and Voids on the Cu(001) Surface
Electromigration-induced flow of islands and voids on the Cu(001) surface is
studied at the atomic scale. The basic drift mechanisms are identified using a
complete set of energy barriers for adatom hopping on the Cu(001) surface,
combined with kinetic Monte Carlo simulations. The energy barriers are
calculated by the embedded atom method, and parameterized using a simple model.
The dependence of the flow on the temperature, the size of the clusters, and
the strength of the applied field is obtained. For both islands and voids it is
found that edge diffusion is the dominant mass-transport mechanism. The rate
limiting steps are identified. For both islands and voids they involve
detachment of atoms from corners into the adjacent edge. The energy barriers
for these moves are found to be in good agreement with the activation energy
for island/void drift obtained from Arrhenius analysis of the simulation
results. The relevance of the results to other FCC(001) metal surfaces and
their experimental implications are discussed.Comment: 9 pages, 13 ps figure