Nieuw peilbeheer in de veenweiden?

Bij het huidige waterbeheer in de veenweidegebieden zal het maaiveld in de komende honderd jaar op veel plaatsen met meer dan een meter dalen. De maaivelddaling gaat door tot al het veen is verdwenen en de minerale ondergrond aan de oppervlakte ligt. Met het veen verdwijnt dan ook het bijbehorende veenlandschap. De enige mogelijkheid om deze ontwikkeling af te remmen, is door het waterpeil te verhogen. Er zijn verschillende waterpeilstrategieën denkbaar om dat te realiseren, maar die hebben de nodige gevolgen voor inrichting, bodemgebruik en waterinlaat. Een strategiestudie brengt momenteel de gevolgen in kaart en biedt daarmee de waterbeheerder handvatten om mogelijke veranderingen in het peilbeheer te beoordele

Collective Fluorescence Enhancement In Nanoparticle Clusters

Many nanoscale systems are known to emit light intermittently under continuous illumination. In the fluorescence of single semiconductor nanoparticles, the distributions of bright and dark periods (\u27on\u27 and \u27off\u27 times) follow Levy statistics. Although fluorescence from single-quantum dots and from macroscopic quantum dot ensembles has been studied, there has been little study of fluorescence from small ensembles. Here we show that blinking nanorods (NRs) interact with each other in a cluster, and the interactions affect the blinking statistics. The on-times in the fluorescence of a NR cluster increase dramatically; in a cluster with N NRs, the maximum on-time increases by a factor of N or more compared with the combined signal from N well-separated NRs. Our study emphasizes the use of statistical properties in identifying the collective dynamics. The scaling of this interaction-induced increase of on-times with number of NRs reveals a novel collective effect at the nanoscale

Lagere Rijnafvoer bij veranderingen in klimaat en landgebruik

Alterra onderzocht samen met Wageningen Universiteit de gevolgen van klimaat- en landgebruikverandering op lage afvoeren in de Rijn. Hiervoor maakten ze gebruik van het grond- en oppervlaktewatermodel SIMGRO. Uit het onderzoek komt naar voren dat extreme klimaatscenario’s in 2050 zullen leiden tot aanzienlijk lagere afvoeren in de Rijn en bovendien een toename in de duur. Verder blijkt dat veranderingen in het landgebruik een veel kleiner effect hebben op lage afvoeren dan veranderingen in het klimaat. Hierdoor kunnen lagere afvoeren door klimaatverandering moeilijk opgevangen worden met alleen aanpassingen in het landgebrui

Was hoog water in Noord-Nederland te voorkomen?

In Noord-Nederland steeg door stevige regenval het waterpeil in de boezem sinds de jaarwisseling enorm. Een belemmerende factor was dat dit overtollige water nauwelijks op zee geloosd kon worden vanwege de aanhoudende harde tot stormachtige noordwestenwind en daardoor zeer hoge waterstanden in de Waddenzee. De inzet van bergingsgebieden moest de extreem hoge waterstanden verlagen. Het is de allereerste keer dat de noordelijke waterschappen met succes gebruik maakten van deze voorzieningen. Erik Querner en Cees Kwakernaak pleiten voor het bovenstrooms vasthouden van water, waarmee overlast te vermijden is

Fluorescence Blinking Statistics From CdSe Core And Core/Shell Nanorods

We report fluorescence blinking statistics measured from single CdSe nanorods (NRs) of seven different sizes with aspect ratios ranging from 3 to 11. This study also included core/shell CdSe/ZnSe NRs and core NRs with two different surface ligands producing different degrees of surface passivation. We compare the findings for NRs to our measurements of blinking statistics from spherical CdSe core and CdSe/ZnS core/shell nanocrystals (NCs). We find that, for both NRs and spherical NCs, the off-time probability distributions are well described by a power law, while the on-time probability distributions are best described by a truncated power law, P(tau(on)) similar to tau(-alpha)(on)e(on)(-tau)(/tau c). The measured crossover time, tau(c), is indistinguishable within experimental uncertainty for core and core/shell NRs, as well as for core NRs with different ligands, for the same core size, indicating that surface passivation does not affect the blinking statistics significantly. We find that, at fixed excitation intensity, 1/tau(c) increases approximately linearly with increasing NR aspect ratio; for a given sample, 1/tau(c) increases very gradually with increasing excitation intensity. Examining 1/tau(c) versus the single-particle photon absorption rate for all samples indicates that the change in NR absorption cross section with sample size can account for some but not all of the differences in crossover time. This suggests that the degree of quantum confinement may be partially responsible for the aspect ratio dependence of the crossover time

Perspectief voor een zelfvoorzienend watersysteem in de Veenkoloniën

Het klimaat verandert en dat heeft de nodige consequenties voor de zoetwatervoorziening en de verwerking van neerslagpieken. Inmiddels wordt al volop gewerkt aan plannen om Nederland klimaatbestendiger te maken, onder meer in het Deltaprogramma. In deze fase worden strategische keuzen rond lange termijn veiligheid en zoetwatervoorziening voorbereid. In dat kader past ook het verkennende onderzoek naar de watervoorziening in de Gronings-Drentse Veenkoloniën. Met een hydrologisch model is nagegaan of water vasthouden in regionale retentiegebieden een realistisch alternatief kan bieden voor het verminderen of zo mogelijk volledig stoppen van wateraanvoer vanuit het IJsselmeer

Formation of PbSe/CdSe Core/Shell Nanocrystals for Stable Near-Infrared High Photoluminescence Emission

PbSe/CdSe core/shell nanocrystals with quantum yield of 70% were obtained by the “successive ion layer adsorption and reaction” technology in solution. The thickness of the CdSe shell was exactly controlled. A series of spectral red shifts with the CdSe shell growth were observed, which was attributed to the combined effect of the surface polarization and the expansion of carriers’ wavefunctions. The stability of PbSe nanocrystals was tremendously improved with CdSe shells

Integrated time-lapse geoelectrical imaging of wetland hydrological processes

Wetlands provide crucial habitats, are critical in the global carbon cycle, and act as key biogeochemical and hydrological buffers. The effectiveness of these services is mainly controlled by hydrological processes, which can be highly variable both spatially and temporally due to structural complexity and seasonality. Spatial analysis of 2D geoelectrical monitoring data integrated into the interpretation of conventional hydrological data has been implemented to provide a detailed understanding of hydrological processes in a riparian wetland. This study shows that a combination of processes can define the resistivity signature of the shallow subsurface, highlighting the seasonality of these processes and its corresponding effect on biogeochemical processesthe wetland hydrology. Groundwater exchange between peat and the underlying river terrace deposits, spatially and temporally defined by geoelectrical imaging and verified by point sensor data, highlighted the groundwater dependent nature of the wetland. A 30 % increase in peat resistivity was shown to be caused by a nearly entire exchange of the saturating groundwater. For the first time, we showed that automated interpretation of geoelectrical data can be used to quantify shrink-swell of expandable soils, affecting hydrological parameters, such as, porosity, water storage capacity, and permeability. This study shows that an integrated interpretation of hydrological and geophysical data can significantly improve the understanding of wetland hydrological processes. Potentially, this approach can provide the basis for the evaluation of ecosystem services and may aid in the optimization of wetland management strategies

Surface Doping Quantum Dots with Chemically Active Native Ligands: Controlling Valence without Ligand Exchange

One remaining challenge in the field of colloidal semiconductor nanocrystal quantum dots is learning to control the degree of functionalization or valence per nanocrystal. Current quantum dot surface modification strategies rely heavily on ligand exchange, which consists of replacing the nanocrystal\u27s native ligands with carboxylate- or amine-terminated thiols, usually added in excess. Removing the nanocrystal\u27s native ligands can cause etching and introduce surface defects, thus affecting the nanocrystal\u27s optical properties. More importantly, ligand exchange methods fail to control the extent of surface modification or number of functional groups introduced per nanocrystal. Here, we report a fundamentally new surface ligand modification or doping approach aimed at controlling the degree of functionalization or valence per nanocrystal while retaining the nanocrystal\u27s original colloidal and photostability. We show that surface-doped quantum dots capped with chemically active native ligands can be prepared directly from a mixture of ligands with similar chain lengths. Specifically, vinyl and azide-terminated carboxylic acid ligands survive the high temperatures needed for nanocrystal synthesis. The ratio between chemically active and inactive-terminated ligands is maintained on the nanocrystal surface, allowing to control the extent of surface modification by straightforward organic reactions. Using a combination of optical and structural characterization tools, including IR and 2D NMR, we show that carboxylates bind in a bidentate chelate fashion, forming a single monolayer of ligands that are perpendicular to the nanocrystal surface. Moreover, we show that mixtures of ligands with similar chain lengths homogeneously distribute themselves on the nanocrystal surface. We expect this new surface doping approach will be widely applicable to other nanocrystal compositions and morphologies, as well as to many specific applications in biology and materials science

The scientific payload of the Ultraviolet Transient Astronomy Satellite (ULTRASAT)

The Ultraviolet Transient Astronomy Satellite (ULTRASAT) is a space-borne near UV telescope with an unprecedented large field of view (200 sq. deg.). The mission, led by the Weizmann Institute of Science and the Israel Space Agency in collaboration with DESY (Helmholtz association, Germany) and NASA (USA), is fully funded and expected to be launched to a geostationary transfer orbit in Q2/3 of 2025. With a grasp 300 times larger than GALEX, the most sensitive UV satellite to date, ULTRASAT will revolutionize our understanding of the hot transient universe, as well as of flaring galactic sources. We describe the mission payload, the optical design and the choice of materials allowing us to achieve a point spread function of ~10arcsec across the FoV, and the detector assembly. We detail the mitigation techniques implemented to suppress out-of-band flux and reduce stray light, detector properties including measured quantum efficiency of scout (prototype) detectors, and expected performance (limiting magnitude) for various objects.Comment: Presented in the SPIE Astronomical Telescopes + Instrumentation 202