Influence of the Dzyaloshinskii-Moriya exchange interaction on quantum phase interference of spins

Magnetization measurements of a Mn12mda wheel single-molecule magnet with a spin ground state of S = 7 show resonant tunneling and quantum phase interference, which are established by studying the tunnel rates as a function of a transverse field applied along the hard magnetization axis. Dzyaloshinskii-Moriya (DM) exchange interaction allows the tunneling between different spin multiplets. It is shown that the quantum phase interference of these transitions is strongly dependent on the direction of the DM vector.Comment: 5 pages, 5 figure

Fabrication of Nano-Gapped Single-Electron Transistors for Transport Studies of Individual Single-Molecule Magnets

Three terminal single-electron transistor devices utilizing Al/Al2O3 gate electrodes were developed for the study of electron transport through individual single-molecule magnets. The devices were patterned via multiple layers of optical and electron beam lithography. Electromigration induced breaking of the nanowires reliably produces 1-3 nm gaps between which the SMM can be situated. Conductance through a single Mn12(3-thiophenecarboxylate) displays the coulomb blockade effect with several excitations within +/- 40 meV.Comment: 10 pages, 5 figure

Shaping the global communications milieu : the EU's influence on internet and telecommunications governance

This article evaluates the European Union's (EU) influence in shaping the global governance for telecommunications and the Internet. Through analysing EU behaviour within an actorness framework, we demonstrate how the external opportunity structure and the EU's internal environment has impacted on its ability to exert and maximize its presence in order to meet its goals and aims in these two very different sub-sectors of global communications in terms of evolution and development. Such a comparison of EU actorness, we argue, is revealing in terms of uncovering the underlying factors and conditions that allow the EU to influence two important and dynamic communications sub-sectors

Quantum tunneling in a three dimensional network of exchange coupled single-molecule magnets

A Mn4 single-molecule magnet (SMM) is used to show that quantum tunneling of magnetization (QTM) is not suppressed by moderate three dimensional exchange coupling between molecules. Instead, it leads to an exchange bias of the quantum resonances which allows precise measurements of the effective exchange coupling that is mainly due to weak intermolecular hydrogen bounds. The magnetization versus applied field was recorded on single crystals of [Mn4]2 using an array of micro-SQUIDs. The step fine structure was studied via minor hysteresis loops.Comment: 4 pages, 4 figure

Keck Adaptive Optics Imaging of Nearby Young Stars: Detection of Close Multiple Systems

Using adaptive optics on the Keck II 10-meter telescope on Mauna Kea, we have surveyed 24 of the nearest young stars known in search of close companions. Our sample includes members of the MBM 12 and TW Hydrae young associations and the classical T Tauri binary UY Aurigae in the Taurus star-forming region. We present relative photometry and accurate astrometry for 10 close multiple systems. The multiplicity frequency in the TW Hydrae and MBM 12 groups are high in comparison to other young regions, though the significance of this result is low because of the small number statistics. We resolve S 18 into a triple system including a tight 63 mas (projected separation of 17 AU at a distance of 275 pc) binary for the first time, with a hierarchical configuration reminiscent of VW Chamaeleontis and T Tauri. Another tight binary in our sample -- TWA 5Aab (54 mas or 3 AU at 55 pc) -- offers the prospect of dynamical mass measurement using astrometric observations within a few years, and thus could be important for testing pre-main sequence evolutionary models. Our observations confirm with 9-sigma confidence that the brown dwarf TWA 5B is bound to TWA 5A. We find that the flux ratio of UY Aur has changed dramatically, by more than a magnitude in the H-band, possibly as a result of variable extinction. With a smaller flux ratio, the system may once again become detectable as an optical binary, as it was at the time of its discovery in 1944. Taken together, our results demonstrate that adaptive optics on large telescopes is a powerful tool for detecting tight companions, and thus exploring the frequency and configurations of close multiple systems.Comment: accepted for publication in The Astronomical Journa

Quantum phase interference and spin parity in Mn12 single-molecule magnets

Magnetization measurements of Mn12 molecular nanomagnets with spin ground states of S = 10 and S = 19/2 showresonance tunneling at avoided energy level crossings. The observed oscillations of the tunnel probability as a function of the magnetic field applied along the hard anisotropy axis are due to topological quantum phase interference of two tunnel paths of opposite windings. Spin-parity dependent tunneling is established by comparing the quantum phase interference of integer and half-integer spin systems.Comment: 5 pages, 5 figure

Quantum Phase Interference and Neel-Vector Tunneling in Antiferromagnetic Molecular Wheels

The antiferromagnetic molecular wheel Fe18 of eighteen exchange-coupled Fe(III) ions has been studied by measurements of the magnetic torque, the magnetization, and the inelastic neutron scattering spectra. The combined data show that the low-temperature magnetism of Fe18 is very accurately described by the Neel-vector tunneling (NVT) scenario, as unfolded by semiclassical theory. In addition, the magnetic torque as a function of applied field exhibits oscillations that reflect the oscillations in the NVT tunnel splitting with field due to quantum phase interference.Comment: 5 pages, 4 figures, REVTEX4, to appear in PR

Huge Transverse Magnetization in the Field-Induced Phase of the Antiferromagnetic Molecular Wheel CsFe8

The 1H-NMR spectrum and nuclear relaxation rate 1/T_1 in the antiferromagnetic wheel CsFe8 were measured to characterize the previously observed magnetic field-induced low-temperature phase around the level crossing at 8 T. The data show that the phase is characterized by a huge staggered transverse polarization of the electronic Fe spins, and the opening of a gap, providing microscopic evidence for the interpretation of the phase as a field-induced magneto-elastic instability.Comment: 5 pages, 4 figures, REVTEX4, to appear in PR

Realization of random-field dipolar Ising ferromagnetism in a molecular magnet

The longitudinal magnetic susceptibility of single crystals of the molecular magnet Mn$_{12}$-acetate obeys a Curie-Weiss law, indicating a transition to a ferromagnetic phase due to dipolar interactions. With increasing magnetic field applied transverse to the easy axis, the transition temperature decreases considerably more rapidly than predicted by mean field theory to a T=0 quantum critical point. Our results are consistent with an effective Hamiltonian for a random-field Ising ferromagnet in a transverse field, where the randomness is induced by an external field applied to Mn$_{12}$-acetate crystals that are known to have an intrinsic distribution of locally tilted magnetic easy axes.Comment: 4 pages, 4 figure

Tuning Magnetic Avalanches in Mn12-ac

Using micron-sized Hall sensor arrays to obtain time-resolved measurements of the local magnetization, we report a systematic study in the molecular magnet Mn$_{12}$-acetate of magnetic avalanches controllably triggered in different fixed external magnetic fields and for different values of the initial magnetization. The speeds of propagation of the spin-reversal fronts are in good overall agreement with the theory of magnetic deflagration of Garanin and Chudnovsky \cite{Garanin}.Comment: 8 pages, 7 figures; discussion expanded and revise