Model fluid in a porous medium: results for a Bethe lattice

We consider a lattice gas with quenched impurities or `quenched-annealed binary mixture' on the Bethe lattice. The quenched part represents a porous matrix in which the (annealed) lattice gas resides. This model features the 3 main factors of fluids in random porous media: wetting, randomness and confinement. The recursive character of the Bethe lattice enables an exact treatment, whose key ingredient is an integral equation yielding the one-particle effective field distribution. Our analysis shows that this distribution consists of two essentially different parts. The first one is a continuous spectrum and corresponds to the macroscopic volume accessible to the fluid, the second is discrete and comes from finite closed cavities in the porous medium. Those closed cavities are in equilibrium with the bulk fluid within the grand canonical ensemble we use, but are inaccessible in real experimental situations. Fortunately, we are able to isolate their contributions. Separation of the discrete spectrum facilitates also the numerical solution of the main equation. The numerical calculations show that the continuous spectrum becomes more and more rough as the temperature decreases, and this limits the accuracy of the solution at low temperatures.Comment: 13 pages, 12 figure

Bulk and Boundary Critical Behavior at Lifshitz Points

Lifshitz points are multicritical points at which a disordered phase, a homogeneous ordered phase, and a modulated ordered phase meet. Their bulk universality classes are described by natural generalizations of the standard $\phi^4$ model. Analyzing these models systematically via modern field-theoretic renormalization group methods has been a long-standing challenge ever since their introduction in the middle of the 1970s. We survey the recent progress made in this direction, discussing results obtained via dimensionality expansions, how they compare with Monte Carlo results, and open problems. These advances opened the way towards systematic studies of boundary critical behavior at $m$-axial Lifshitz points. The possible boundary critical behavior depends on whether the surface plane is perpendicular to one of the $m$ modulation axes or parallel to all of them. We show that the semi-infinite field theories representing the corresponding surface universality classes in these two cases of perpendicular and parallel surface orientation differ crucially in their Hamiltonian's boundary terms and the implied boundary conditions, and explain recent results along with our current understanding of this matter.Comment: Invited contribution to STATPHYS 22, to be published in the Proceedings of the 22nd International Conference on Statistical Physics (STATPHYS 22) of the International Union of Pure and Applied Physics (IUPAP), 4--9 July 2004, Bangalore, Indi

Critical behavior at m-axial Lifshitz points: field-theory analysis and ϵ\epsilon-expansion results

The critical behavior of d-dimensional systems with an n-component order parameter is reconsidered at (m,d,n)-Lifshitz points, where a wave-vector instability occurs in an m-dimensional subspace of ${\mathbb R}^d$. Our aim is to sort out which ones of the previously published partly contradictory $\epsilon$-expansion results to second order in $\epsilon=4+\frac{m}{2}-d$ are correct. To this end, a field-theory calculation is performed directly in the position space of $d=4+\frac{m}{2}-\epsilon$ dimensions, using dimensional regularization and minimal subtraction of ultraviolet poles. The residua of the dimensionally regularized integrals that are required to determine the series expansions of the correlation exponents $\eta_{l2}$ and $\eta_{l4}$ and of the wave-vector exponent $\beta_q$ to order $\epsilon^2$ are reduced to single integrals, which for general m=1,...,d-1 can be computed numerically, and for special values of m, analytically. Our results are at variance with the original predictions for general m. For m=2 and m=6, we confirm the results of Sak and Grest [Phys. Rev. B {\bf 17}, 3602 (1978)] and Mergulh{\~a}o and Carneiro's recent field-theory analysis [Phys. Rev. B {\bf 59},13954 (1999)].Comment: Latex file with one figure (eps-file). Latex file uses texdraw to generate figures that are included in the tex

Landau theory of phase transitions in TTF-TCNQ

Several parameters of the Landau Free Energy Function of TTF-TCNQ are calculated from the crystal structure taking into account the atomic positions and realistic charge distributions. In particular, the parameters that determine the coupling between charge density waves and rotations (librons) on neighbouring chains are evaluated. The Free Energy Function is solved, and good agreement with the experimental observation of the 2 a period between 53 K and 48 K and its variation below this temperature, is obtained. The CDW-libron interaction seems to be responsible for this transverse period. The behaviour of C p in the vicinity of the two close phase transitions is studied. The Free Energy should possess several (up to four) Lifshitz points, for appropriate values of the parameters.On calcule plusieurs paramètres de l'énergie libre de Landau pour TTF-TCNQ à partir de la structure cristalline en tenant compte de la position des atomes et des distributions de charge réalistes. En particulier, on évalue les paramètres qui déterminent le couplage entre les ondes de densité de charge et les rotations (librons) sur des chaînes voisines. On résoud la fonction d'énergie libre et on obtient un bon accord avec l'observation expérimentale de la période 2 a entre 53 K et 48 K et sa variation en dessous de cette température. L'interaction « onde de densité de charge »-libron semble être responsable pour cette période transversale. On étudie le comportement de Cp aux environs des deux transitions de phases voisines. L'énergie libre devrait avoir plusieurs (jusqu'a quatre) points de Lifshitz, pour des valeurs convenables des paramètres