293 research outputs found
Chemical Differences between K and Na in Alkali Cobaltates
KCoO shares many similarities with NaCoO, as well as some
important differences (no hydration-induced superconductivity has been
reported). At =20 K, KCoO becomes an insulator with a tiny
optical gap as happens in NaCoO at 52 K. This similarity, with a
known common structure, enables direct comparisons to be made. Using the
K-zigzag structure recently reported and the local density approximation, we
compare and contrast these cobaltates at x=0.5. Although the electronic
structures are quite similar as expected, substantial differences are observed
near the Fermi level. These differences are found to be attributable mostly to
the chemical, rather than structural difference: although Na is normally
considered to be fully ion, K has somewhat more highly ionic character than
does Na in these cobaltates.Comment: 5 paper
A novel route to phase formation of cobalt oxyhydrates using KMnO4 as an oxidizing agent
We have first succeefully synthesized the sodium cobalt oxyhydrate
superconductors using KMnO4 as a de-intercalating and oxidizing agent. It is a
novel route to form the superconductive phase of NaxCoO2.yH2O without resorting
to the commonly used Br2/CH3CN solution. The role of the KMnO4 is to
de-intercalate the Na+ from the parent compound Na0.7CoO2 and oxidize the Co
ion as a result. The higher molar ratio of KMnO4 relative to the sodium content
tends to remove more Na+ from the parent compound and results in a slight
expansion of the c-axis in the unit cell. The superconducting transition
temperature is 4.6-3.8 K for samples treated by the aqueous KMnO4 solution with
the molar ratio of KMnO4 relative to the sodium content in the range of 0.3 and
2.29.Comment: 10 pages, 3 figure
Bulk antiferromagnetism in single crystals
Susceptibility, specific heat, and muon spin rotation measurements on
high-quality single crystals of have revealed bulk
antiferromagnetism with N\'{e}el temperature K and an
ordered moment perpendicular to the layers. The magnetic order
encompasses nearly 100% of the crystal volume. The susceptibility exhibits a
broad peak around 30 K, characteristic of two-dimensional antiferromagnetic
fluctuations. The in-plane resistivity is metallic at high temperatures and
exhibits a minimum at .Comment: published versio
Magnetic and Metal-Insulator Transitions in beta-Na0.5CoO2 and gamma-K0.5CoO2 -NMR and Neutron Diffraction Studies-
Co-oxides beta-Na0.5CoO2 and gamma-K0.5CoO2 have been prepared by the Na
de-intercalation from alpha-NaCoO2 and by the floating-zone method,
respectively. It has been found that successive phase transitions take place at
temperatures Tc1 and Tc2 in both systems. The appearance of the internal
magnetic field at Tc1 with decreasing temperature T indicates that the
antiferromagnetic order exists at T < Tc1, as in gamma-Na0.5CoO2. For
beta-Na0.5CoO2, the transition temperatures and the NMR parameters determined
from the data taken for magnetically ordered state are similar to those of
gamma-Na0.5CoO2, indicating that the difference of the stacking ways of the
CoO2 layers between these systems do not significantly affect their physical
properties. For gamma-K0.5CoO2, the quantitative difference of the physical
quantities are found from those of beta- and gamma-Na0.5CoO2. The difference
between the values of Tci (i = 1 and 2) of these systems might be explained by
considering the distance between CoO2 layers.Comment: 8 pages, 14 figures, 1 Tabl
Simultaneous initiation of radical and cationic polymerization reactions using the "G1" copper complex as photoredox catalyst: Applications of free radical/cationic hybrid photopolymerization in the composites and
WOS:000469902800007This investigation presents the use of a photoredox catalyst "G1" as a photoinitiating system for free radical/cationic hybrid polymerization under mild irradiation conditions. The G1 system (G1/iodonium salt/N-vinylcarbazole), can simultaneously initiate the free radical and cationic polymerization reactions upon exposure to a visible (405 nm) light from a Light Emitting Diode (LED) source. The multicomponent G1 system is able to simultaneously generate radical and cationic species through a catalytic photoredox process. The curing of thin samples (25 mu m), thick samples (1.4 mm) as well as the manufacture of hybrid system/glass fibers composites ( 2 to 4 mm thickness) was realized and the influence of the ratio of cationic/radical monomer blends on the polymerization kinetics was studied. The use of G1 in visible light photoinitiating system for the access to composites and 3D printing experiments was particularly outlined. G1 was also shown to have low levels of migration from the cured materials. When compared to reference materials ("F1", a similar copper complex and an anthracene derivative, dibutoxy anthracene), G1 showed better polymerization efficiency. The initiation efficiency was investigated through the real-time Fourier transform infrared (RT-FTIR) spectroscopy and optical pyrometry. Dynamical Mechanical Analysis has been used to determine the glass temperature transition of the cured hybrid system as a complementary technique
Mass-Enhanced Fermi Liquid Ground State in NaCoO
Magnetic, transport, and specific heat measurements have been performed on
layered metallic oxide NaCoO as a function of temperature .
Below a characteristic temperature =3040 K, electrical resistivity
shows a metallic conductivity with a behavior and magnetic susceptibility
deviates from the Curie-Weiss behavior showing a broad peak at 14 K. The
electronic specific heat coefficient is 60 mJ/molK at 2 K.
No evidence for magnetic ordering is found. These behaviors suggest the
formation of mass-enhanced Fermi liquid ground state analogous to that in
-electron heavy fermion compound LiVO.Comment: 4 pages, 4 figures, to be published in Phys. Rev. B 69 (2004
Precise Control of Band Filling in NaxCoO2
Electronic properties of the sodium cobaltate NaxCoO2 are systematically
studied through a precise control of band filling. Resistivity, magnetic
susceptibility and specific heat measurements are carried out on a series of
high-quality polycrystalline samples prepared at 200 C with Na content in a
wide range of 0.35 =< x =< 0.70. It is found that dramatic changes in
electronic properties take place at a critical Na concentration x* that lies
between 0.58 and 0.59, which separates a Pauli paramagnetic and a Curie-Weiss
metals. It is suggested that at x* the Fermi level touches the bottom of the
a1g band at the gamma point, leading to a crucial change in the density of
states across x* and the emergence of a small electron pocket around the gamma
point for x > x*.Comment: 4 pages, 5 figures, submitted to J. Phys. Soc. Jp
Impurity-induced transition and impurity-enhanced thermopower in the thermoelectric oxide NaCo_{2-x}Cu_x$O_4
Various physical quantities are measured and analysed for the Cu-substituted
thermoelectric oxide NaCo_{2-x}Cu_xO_4. As was previously known, the
substituted Cu enhances the thermoelectric power, while it does not increase
the resistivity significantly. The susceptibility and the electron
specific-heat are substantially decreased with increasing x, which implies that
the substituted Cu decreases the effective-mass enhancement. Through a
quantitative comparison with the heavy fermion compounds and the valence
fluctuation systems, we have found that the Cu substitution effectively
increases the coupling between the conduction electron and the magnetic
fluctuation. The Cu substitution induces a phase transition at 22 K that is
very similar to a spin-density-wave transition.Comment: 8 pages, 7 figures, submitted to Phys. Rev.
Photochemistry and Radical Chemistry under Low Intensity Visible Light Sources: Application to Photopolymerization Reactions:
The search for radical initiators able to work under soft conditions is a great challenge, driven by the fact that the use of safe and cheap light sources is very attractive. In the present paper, a review of some recently reported photoinitiating systems for polymerization under soft conditions is provided. Different approaches based on multi-component systems (e.g., photoredox catalysis) or light harvesting photoinitiators are described and discussed. The chemical mechanisms associated with the production of free radicals usable as initiating species or mediators of cations are reported
Effect of Na content and hydration on the excitation spectrum of the cobaltite Na_xCoO_2 yH_2O
We report on a Raman scattering study on the superconducting cobaltite
as function of Na content and hydration (x1/3,
3/4 and y0, 2/3, 4/3). The observed phonon scattering and scattering
continua are analyzed in terms of lattice strain due to the structural misfit
and disorder. Hydration, due to the intercalation of one or two layers,
releases a part of this strain. Our Raman data suggest a connection between
disorder on the partly occupied Na sites, the split off of the level
from the other states of and superconductivity.Comment: 10 pages, 4 figures, for further information see
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