6,830 research outputs found

    π\pi-Electron Ferromagnetism in Metal Free Carbon Probed by Soft X-Ray Dichroism

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    Elemental carbon represents a fundamental building block of matter and the possibility of ferromagnetic order in carbon attracted widespread attention. However, the origin of magnetic order in such a light element is only poorly understood and has puzzled researchers. We present a spectromicroscopy study at room temperature of proton irradiated metal free carbon using the elemental and chemical specificity of x-ray magnetic circular dichroism (XMCD). We demonstrate that the magnetic order in the investigated system originates only from the carbon π\pi-electron system.Comment: 10 pages 3 color figure

    Induced Magnetic Ordering by Proton Irradiation in Graphite

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    We provide evidence that proton irradiation of energy 2.25 MeV on highly-oriented pyrolytic graphite samples triggers ferro- or ferrimagnetism. Measurements performed with a superconducting quantum interferometer device (SQUID) and magnetic force microscopy (MFM) reveal that the magnetic ordering is stable at room temperature.Comment: 3 Figure

    Mapping spectroscopic uncertainties into prospective methane retrieval errors from Sentine-5 and its precursor

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    Sentinel-5 (S5) and its precursor (S5P) are future European satellite missions aiming at global monitoring of methane (CH4) column average dry air mole fractions (XCH4). The spectrometers to be deployed on-board the satellites record spectra of sunlight backscattered from the Earth\u27s surface and atmosphere. In particular, they exploit CH4 absorption in the shortwave infrared spectral range around 1.65 µm (S5 only) and 2.35 µm (both, S5 and S5P) wavelength. Given an accuracy goal of better than 2% for XCH4 to be delivered on regional scales, assessment and reduction of potential sources of systematic error such as spectroscopic uncertainties is crucial. Here, we investigate how spectroscopic errors propagate into retrieval errors on the global scale. To this end, absorption spectra of a ground-based Fourier Transform Spectrometer (FTS) operating at very high spectral resolution serve as estimate for the quality of the spectroscopic parameters. Feeding the FTS fitting residuals as a perturbation into a global ensemble of simulated S5 and S5P-like spectra at relatively low spectral resolution, XCH4 retrieval errors exceed 1% in large parts of the world and show systematic correlations on regional scales, calling for improved spectroscopic parameters

    Thermodynamics of C incorporation on Si(100) from ab initio calculations

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    We study the thermodynamics of C incorporation on Si(100), a system where strain and chemical effects are both important. Our analysis is based on first-principles atomistic calculations to obtain the important lowest energy structures, and a classical effective Hamiltonian which is employed to represent the long-range strain effects and incorporate the thermodynamic aspects. We determine the equilibrium phase diagram in temperature and C chemical potential, which allows us to predict the mesoscopic structure of the system that should be observed under experimentally relevant conditions.Comment: 5 pages, 3 figure

    FORE II: A COMPUTATIONAL PROGRAM FOR THE ANALYSIS OF STEADY-STATE AND TRANSIENT REACTOR PERFORMANCE.

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    Pinning and switching of magnetic moments in bilayer graphene

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    We examine the magnetic properties of the localized states induced by lattice vacancies in bilayer graphene with an unrestricted Hartree-Fock calculation. We show that with realistic values of the parameters and for experimentally accessible gate voltages we can have a magnetic switching between an unpolarized and a fully polarized system.Comment: 9 pages, 4 figure
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