Time-Temperature Superposition of Structural Relaxation in a Viscous Metallic Liquid

Bulk metallic glass-forming Pd40Ni10Cu30P20 has been investigated in its equilibrium liquid by quasielastic neutron scattering. The quasielastic signal exhibits a structural relaxation as known from nonmetallic viscous liquids. Even well above the melting point, the structural relaxation is nonexponential and obeys a universal time-temperature superposition. From the mean relaxation times average diffusivities have been determined, resulting in values on a 10^-10 m^2 s^-1 scale, 3 orders of magnitude slower than in simple metallic liquids

The effect of silicon on the glass forming ability of the Cu47Ti34Zr11Ni8 bulk metallic glass forming alloy during processing of composites

Composites of the Cu47Ti34Zr11Ni8 bulk metallic glass, reinforced with up to 30 vol % SiC particles are synthesized and characterized. Results based on x-ray diffraction, optical microscopy, scanning Auger microscopy, and differential scanning calorimetry (DSC) are presented. During processing of the composites, a TiC layer forms around the SiC particles and Si diffuses into the Cu47Ti34Zr11Ni8 matrix stabilizing the supercooled liquid against crystallization. The small Si addition between 0.5 and 1 at. % increases the attainable maximum thickness of glassy ingots from 4 mm for Cu–Ti–Zr–Ni alloys to 7 mm for Cu–Ti–Zr–Ni–Si alloys. DSC analyses show that neither the thermodynamics nor the kinetics of the alloy are affected significantly by the Si addition. This suggests that Si enhances the glass forming ability by chemically passivating impurities such as oxygen and carbon that cause heterogeneous nucleation in the melt

Quantum Mechanics as a Framework for Dealing with Uncertainty

Quantum uncertainty is described here in two guises: indeterminacy with its concomitant indeterminism of measurement outcomes, and fuzziness, or unsharpness. Both features were long seen as obstructions of experimental possibilities that were available in the realm of classical physics. The birth of quantum information science was due to the realization that such obstructions can be turned into powerful resources. Here we review how the utilization of quantum fuzziness makes room for a notion of approximate joint measurement of noncommuting observables. We also show how from a classical perspective quantum uncertainty is due to a limitation of measurability reflected in a fuzzy event structure -- all quantum events are fundamentally unsharp.Comment: Plenary Lecture, Central European Workshop on Quantum Optics, Turku 2009

Price Indexes for Acute Phase Treatment of Depression

Although broad trends in medical spending in the U.S. over the last decade have received widespread attention from policymakers, very little attention has focused on the components of those changes. For many other industries, economists typically divide nominal expenditures by an official government price index to decompose these expenditures into price and quantity components. In this paper we construct a new price index for the treatment of one illness depression. Making use of results from the published clinical literature and from official treatment guideline standards, we identify therapeutically similar treatment bundles. These bundles can then be linked and weighted to construct price indexes for specific forms of major depression. In doing so, we construct CPI and PPI-like medical price indexes that deal with prices of treatment episodes rather than prices of discrete inputs, that are based on transaction rather than list prices, that take quality changes and expected outcomes into account employ current, time-varying expenditure weights in the aggregation computations. We find that regardless of which index number procedure is employed time period the treatment price index for the acute phase of major depression has hardly changed remaining at 1.00 or falling slightly to around 0.97. This index grows considerably less rapidly than the various official PPIs -- thus the price index for the treatment of the acute phase of major depression has fallen over the 1991-95 time period. A hedonic approach to price index measurement yields broadly similar results. These results imply that given a budget for treatment of depression accomplished in 1995 than in 1991. Our results suggest that at least in the case of acute phase major depression, aggregate spending increases are due to a larger number of effective treatments being provided.

Uncertainty reconciles complementarity with joint measurability

The fundamental principles of complementarity and uncertainty are shown to be related to the possibility of joint unsharp measurements of pairs of noncommuting quantum observables. A new joint measurement scheme for complementary observables is proposed. The measured observables are represented as positive operator valued measures (POVMs), whose intrinsic fuzziness parameters are found to satisfy an intriguing pay-off relation reflecting the complementarity. At the same time, this relation represents an instance of a Heisenberg uncertainty relation for measurement imprecisions. A model-independent consideration show that this uncertainty relation is logically connected with the joint measurability of the POVMs in question.Comment: 4 pages, RevTeX. Title of previous version: "Complementarity and uncertainty - entangled in joint path-interference measurements". This new version focuses on the "measurement uncertainty relation" and its role, disentangling this issue from the special context of path interference duality. See also http://www.vjquantuminfo.org (October 2003

Approximate joint measurement of qubit observables through an Arthur-Kelly type model

We consider joint measurement of two and three unsharp qubit observables through an Arthur-Kelly type joint measurement model for qubits. We investigate the effect of initial state of the detectors on the unsharpness of the measurement as well as the post-measurement state of the system. Particular emphasis is given on a physical understanding of the POVM to PVM transition in the model and entanglement between system and detectors.Two approaches for characterizing the unsharpness of the measurement and the resulting measurement uncertainty relations are considered.The corresponding measures of unsharpness are connected for the case where both the measurements are equally unsharp. The connection between the POVM elements and symmetries of the underlying Hamiltonian of the measurement interaction is made explicit and used to perform joint measurement in arbitrary directions. Finally in the case of three observables we derive a necessary condition for the approximate joint measurement and use it show the relative freedom available when the observables are non-orthogonal.Comment: 22 pages; Late

Uncertainty Relations for Positive Operator Valued Measures

How much unavoidable randomness is generated by a Positive Operator Valued Measure (POVM)? We address this question using two complementary approaches. First we study the variance of a real variable associated to the POVM outcomes. In this context we introduce an uncertainty operator which measures how much additional noise is introduced by carrying out a POVM rather than a von Neumann measurement. We illustrate this first approach by studying the variances of joint estimates of \sigma_x and \sigma_z for spin 1/2 particles. We show that for unbiased measurements the sum of these variances is lower bounded by 1. In our second approach we study the entropy of the POVM outcomes. In particular we try to establish lower bounds on the entropy of the POVM outcomes. We illustrate this second approach by examples.Comment: 5 pages, minor modifications and clarification

Heisenberg's uncertainty principle for simultaneous measurement of positive-operator-valued measures

A limitation on simultaneous measurement of two arbitrary positive operator valued measures is discussed. In general, simultaneous measurement of two noncommutative observables is only approximately possible. Following Werner's formulation, we introduce a distance between observables to quantify an accuracy of measurement. We derive an inequality that relates the achievable accuracy with noncommutativity between two observables. As a byproduct a necessary condition for two positive operator valued measures to be simultaneously measurable is obtained.Comment: 7 pages, 1 figure. To appear in Phys. Rev.