Effect of Tris-(hydroxymethyl)-amino methane on microalgae biomass growth in a photobioreactor

© 2016 Elsevier Ltd. One of the buffers namely Tris (Tris-(hydroxymethyl)-amino methane) was used to increase the growth of microalgae by stabilizing the pH value in microalgae cultures. The objective of this research is to determine the growth rate and biomass productivity of Chlorella sp. with and without Tris addition. Both conditions function at various N:P ratios cultured in photobioreactors (carbon dioxide of 5% (v/v), light intensity of 3.3 Klux). Daily variations in nutrient removal (nitrogen and phosphorus), cell concentration, DO, temperature and pH were measured for data analysis. The results show that the largest yield of biomass was achieved at the N:P ratio of 15:1 with and without Tris. After cultivation lasting 92 h, the algae concentration at this ratio was 1250 mg L-1 and 3568 mg L-1 with and without Tris, respectively. This indicates that adding Tris to the photobioreactor greatly reduces algae biomass due to bacterial competition

Multicriteria assessment of advanced treatment technologies for micropollutants removal at large-scale applications

© 2016 Elsevier B.V. With the introduction and discharge of thousands of new micropollutants (MPs) every year, traditional water and wastewater treatment plants may be incapable of tackling them all. With their low concentrations and diversity in nature, MP removal encounters numerous challenges. Although some MPs are effectively eliminated via conventional treatment methods, most of them can easily escape and are retained in the discharged effluent. Therefore, advanced methods such as (i) adsorption, (ii) oxidation and advanced oxidation processes (O3 and O3-based advanced oxidation processes, UV/H2O2), (iii) membrane processes, and (iv) membrane bioreactors, become an inevitable approach. Despite the unsurprisingly vast number of papers on MP treatment available at present, most of these studies were carried out at a laboratory scale while only a few pilot- and full-scale studies have experimented. Nevertheless, an in-depth assessment of real-world MP treatment methods is extremely crucial for practitioners. To date, no paper has been dedicated to look at this issue. Therefore, this paper aims to review these large-scale treatment methods. First, the paper goes through the regulations and standards which deal with MPs in water courses. It will then assess these methods in various case-studies with reference to different criteria towards serving as a reference for further practical applications

Removal of antibiotics in sponge membrane bioreactors treating hospital wastewater: Comparison between hollow fiber and flat sheet membrane systems

© 2017 Elsevier Ltd Hollow fiber (HF) and flat sheet (FS) Sponge MBRs were operated at 10–20 LMH flux treating hospital wastewater. Simultaneous nitrification denitrification (SND) occurred considerably with TN removal rate of 0.011–0.020 mg TN mg VSS−1 d−1. Furthermore, there was a remarkable removal of antibiotics in both Sponge MBRs, namely Norfloxacin (93–99% (FS); 62–86% (HF)), Ofloxacin (73–93% (FS); 68–93% (HF)), Ciprofloxacin (76–93% (FS); 54–70% (HF)), Tetracycline (approximately 100% for both FS and HF) and Trimethoprim (60–97% (FS); 47–93% (HF). Whereas there was a quite high removal efficiency of Erythromycin in Sponge MBRs, with 67–78% (FS) and 22–48% (HF). Moreover, a slightly higher removal of antibiotics in FS than in HF achieved, with the removal rate being of 0.67–32.40 and 0.44–30.42 µg mg VSS−1 d−1, respectively. In addition, a significant reduction of membrane fouling of 2–50 times was achieved in HF-Sponge MBR for the flux range

A new approach involving a multi transducer ultrasonic system for cleaning turbine engines’ oil filters under practical conditions

© 2016 The purpose of this paper is to provide a green technology that can clean turbine engine oil filters effectively in ships using ultrasound, with ultrasonic devices having a frequency of 25 kHz and different powers of 300 W and 600 W, respectively. The effects of temperature, ultrasonic cleaning times, pressure losses through the oil filter, solvent washing, and ultrasonic power devices were investigated. In addition, the cleaning efficiency of three modes (hand washing, preliminary washing and ultrasonic washing) were compared to assess their relative effectiveness. Experimental results revealed that the necessary ultrasonic time varied significantly depending on which solvent was used for washing. For instance, the optimum ultrasonic cleaning time was 50–60 min when the oil filter was cleaned in a solvent of kerosene oil (KO) and over 80 min when in a solvent of diesel oil (DO) using the same ultrasonic generator device (25 kHz, 600 W) and experimental conditions. Furthermore, microscopic examination did not reveal any damage or breakdown on or within the structure of the filter after ultrasonic cleaning, even in the filter's surfaces at a constantly low frequency of 25 kHz and power specific capacity (100 W/gal). Overall, it may be concluded that ultrasound-assisted oil filter washing is effective, requiring a significantly shorter time than manual washing. This ultrasonic method also shows promise as a green technology for washing oil filters in turbine engines in general and Vietnamese navy ships in particular, because of its high cleaning efficiency, operational simplicity and savings

White hard clam (Meretrix lyrata) shells media to improve phosphorus removal in lab-scale horizontal sub-surface flow constructed wetlands: Performance, removal pathways, and lifespan.

This work examined the phosphorus (P) removal from the synthetic pretreated swine wastewater using lab-scale horizontal sub-surface flow constructed wetlands (HSSF-CWs). White hard clam (Meretrix lyrata) shells (WHC) and Paspalum atratum were utilized as substrate and plant, respectively. The focus was placed on treatment performance, removal mechanisms and lifespan of the HSSF-CWs. Results indicated that WHC-based HSSF-CW with P. atratum exhibited a high P removal (89.9%). The mean P efluent concentration and P removal rate were 1.34 ± 0.95 mg/L and 0.32 ± 0.03 g/m2/d, respectively. The mass balance study showed that media sorption was the dominant P removal pathway (77.5%), followed by microbial assimilation (14.5%), plant uptake (5.4%), and other processes (2.6%). It was estimated the WHC-based bed could work effectively for approximately 2.84 years. This WHC-based HSSF-CWs technology will therefore pave the way for recycling Ca-rich waste materials as media in HSSF-CWs to enhance P-rich wastewater purification

Influences of operational parameters on phosphorus removal in batch and continuous electrocoagulation process performance

© 2017, Springer-Verlag GmbH Germany. Performance of an electrocoagulation (EC) process in batch and continuous operating modes was thoroughly investigated and evaluated for enhancing wastewater phosphorus removal under various operating conditions, individually or combined with initial phosphorus concentration, wastewater conductivity, current density, and electrolysis times. The results revealed excellent phosphorus removal (72.7–100%) for both processes within 3–6 min of electrolysis, with relatively low energy requirements, i.e., less than 0.5 kWh/m3 for treated wastewater. However, the removal efficiency of phosphorus in the continuous EC operation mode was better than that in batch mode within the scope of the study. Additionally, the rate and efficiency of phosphorus removal strongly depended on operational parameters, including wastewater conductivity, initial phosphorus concentration, current density, and electrolysis time. Based on experimental data, statistical model verification of the response surface methodology (RSM) (multiple factor optimization) was also established to provide further insights and accurately describe the interactive relationship between the process variables, thus optimizing the EC process performance. The EC process using iron electrodes is promising for improving wastewater phosphorus removal efficiency, and RSM can be a sustainable tool for predicting the performance of the EC process and explaining the influence of the process variables

Integration of SWAT and QUAL2K for water quality modeling in a data scarce basin of Cau River basin in Vietnam

© 2019 European Regional Centre for Ecohydrology of the Polish Academy of Sciences Water quality modeling in a river basin often faces the problem of having a large number of parameters yet limited available data. The important inputs to the water quality model are pollution concentrations and discharge from river tributaries, lateral inflows and related pollution load from different sources along the river. In general, such an extensive data set is rarely available, especially for data scarce basins. This makes water quality modeling more challenging. However, integration of models may be able to fill this data gap. Selection of models should be made based on the data that is available for the river basin. For the case of Cau River basin, the SWAT and QUAL2K models were selected. The outputs of SWAT model for lateral inflows and discharges of ungauged tributaries, and the observed pollutant concentrations data and estimated pollution loads of sub-watersheds were used as inputs to the water quality model QUAL2K. The resulting QUAL2K model was calibrated and validated using recent water quality data for two periods in 2014. Four model performance ratings PBIAS, NSE, RSR and R2 were used to evaluate the model results. PBIAS index was chosen for water quality model evaluation because it more adequately accounted for the large uncertainty inherent in water quality data. In term of PBIAS, the calibration and validation results for Cau River water quality model were in the “very good” performance range with ǀPBIASǀ < 15%. The obtained results could be used to support water quality management and control in the Cau River basin

Performance and membrane fouling of two types of laboratory-scale submerged membrane bioreactors for hospital wastewater treatment at low flux condition

© 2016 Elsevier B.V. All rights reserved. The performance and membrane fouling of a lab-scale submerged sponge-membrane bioreactor (Sponge-MBR) and a conventional MBR were investigated and compared for hospital wastewater treatment at low fluxes of 2-6 LMH. COD removal by the Sponge-MBR was similar to that of the MBR, while the Sponge-MBR achieved 9-16% removed more total nitrogen than the MBR. This was due to 60% of total biomass being entrapped in the sponges, which enhanced simultaneous nitrification denitrification. Additionally, the fouling rates of the Sponge-MBR were 11-, 6.2- and 3.8-times less than those of the MBR at flux rates of 2, 4 and 6 LMH, respectively. It indicates the addition of sponge media into a MBR could effectively reduce the fouling caused by cake formation and absorption of soluble substances in a low flux scenario

Enhanced efficiency for better wastewater sludge hydrolysis conversion through ultrasonic hydrolytic pretreatment

© 2016 Taiwan Institute of Chemical Engineers The major requirements for accelerating the process of anaerobic digestion and energy production are breaking the structure of waste activated sludge (WAS), and transforming it into a soluble form suitable for biodegradation. This work investigated and analysed a novel bench-scale ultrasonic system for WAS disruption and hydrolysis using ultrasonic homogenization. Different commercial sonoreactors were used at low frequencies under a variety of operating conditions (intensity, density, power, sonication time, and total suspended solids) to evaluate the effects of the equipment on sludge hydrolysis and to generate new insights into the empirical models and mechanisms applicable to the real-world processing of wastewater sludge. A relationship was established between the operating parameters and the experimental data. Results indicated an increase in sonication time or ultrasonic intensity correlated with improved sludge hydrolysis rates, sludge temperature, and reduction rate of volatile solids (33.51%). It also emerged that ultrasonication could effectively accelerate WAS hydrolysis to achieve disintegration within 5–10 min, depending on the ultrasonic intensity. This study also determined multiple alternative parameters to increase the efficiency of sludge treatment and organic matter reduction, and establish the practicality of applying ultrasonics to wastewater sludge pretreatment

Bioprocessing for elimination antibiotics and hormones from swine wastewater

© 2017 Elsevier B.V. Antibiotics and hormones in swine wastewater have become a critical concern worldwide due to the severe threats to human health and the eco-environment. Removal of most detectable antibiotics and hormones, such as sulfonamides (SAs), SMs, tetracyclines (TCs), macrolides, and estrogenic hormones from swine wastewater utilizing various biological processes were summarized and compared. In biological processes, biosorption and biodegradation are the two major removal mechanisms for antibiotics and hormones. The residuals in treated effluents and sludge of conventional activated sludge and anaerobic digestion processes can still pose risks to the surrounding environment, and the anaerobic processes’ removal efficiencies were inferior to those of aerobic processes. In contrast, membrane bioreactors (MBRs), constructed wetlands (CWs) and modified processes performed better because of their higher biodegradation of toxicants. Process modification on activated sludge, anaerobic digestion and conventional MBRs could also enhance the performance (e.g. removing up to 98% SMs, 88.9% TCs, and 99.6% hormones from wastewater). The hybrid process combining MBRs with biological or physical technology also led to better removal efficiency. As such, modified conventional biological processes, advanced biological technologies and MBR hybrid systems are considered as a promising technology for removing toxicants from swine wastewater