Magnetocaloric effect and magnetization in a Ni-Mn-Ga Heusler alloy in the vicinity of magnetostructural transition

The magnetic and thermodynamic properties of a Ni2.19Mn0.81Ga alloy with coupled magnetic and structural (martensitic) phase transitions were studied experimentally and theoretically. The magnetocaloric effect was measured by a direct method in magnetic fields 0-26 kOe at temperatures close to the magnetostructural transition temperature. For theoretical description of the alloy properties near the magnetostructural transition a statistical model is suggested, that takes into account the coexistence of martensite and austenite domains in the vicinity of martensite transformation point.Comment: presented at ICM-2003, to appear in JMM

Quantitative correlation of the in vitro biological effect with parameters of molecular complexation in mutagen-interceptor systems

According to the theory of interceptor-protector action a quantitative link between the physico-chemical parameters of molecular complexation and in vitro biological effect in aromatic drug-interceptor systems must exist. In the present communication such link between relative change in mutagenicity of IQ-type aromatic mutagens on addition of aromatic interceptor molecules with equilibrium hetero-association constants of mutagen-interceptor complexation has been found using the published in vitro data in bacteria cell system

General statistical-thermodynamical treatment of one-dimensional multicomponent molecular hetero-assembly in solution

A general treatment has been developed for the multicomponent one-dimensional non-covalent molec-ular hetero-assembly in solution using transfer matrix and sequence generating function approaches. The main result is set of equations, which allows one to obtain any thermodynamical quantities of the mul-ticomponent system and, in particular, experimental observable enabling one to get all equilibrium parameters of molecular interaction. The matrix form of presentation of the key equations allows their direct incorporation into matrix-oriented mathematical software, which leads to a two orders of magni-tude increase in speed of calculation of as compared to other known approache

Interceptor effect of C₆₀ fullerene on the in vitro action of aromatic drug molecules

In this work we are focusing on studying the influence of the pristine C₆₀ fullerene on biological activity of some aromatic drug molecules in human buccal epithelial cells. Assessment of the heterochromatin structure in the cell nucleus as well as the barrier function of the cell membrane was performed. The methods of cell microelectrophoresis and atomic force microscopy were also applied. A concentration-dependent restoration of the functional activity of the cellular nucleus after exposure to DNA -binding drugs (doxorubicin, proflavine and ethidium bromide) has been observed in human buccal epithelial cells upon addition of C₆₀ fullerene at a concentration of ~10−5

First Principles Investigation of Magnetic Properties of Fe-Ni-Mn-Al Heusler Alloys

AbstractThe composition dependences of crystal lattice parameters, magnetic moments and magnetic exchange parameters in FexNi2−xMn1+y Al1−y (0.0 ≤ x ≤ 2.0; 0.0 ≤ y ≤ 0.6) Heusler alloys are investigated with the help of first principles calculations. Our simulations have shown that crystal lattice parameter is decreased with Fe content (x) increasing. Our calculations show that increase of Fe content (x) leads increasing of magnetic exchange interactions between Mn atoms at regular positions and Mn atoms at Al positions and change of interaction sign from antiferromagnetic type to ferromagnetic one for Fe content x ≥ 1.4. Competitive behavior between ferromagnetic and antiferromagnetic interactions shows that these alloys have a complex magnetic structure. Calculated data for crystal lattice parameter, magnetic moment and magnetic exchange parameters for pure compounds (x = 0.0 and x = 2.0) are in an agreement with theoretical and experimental data