207 research outputs found
K(I)-M(II) (Mâ=âCo, Mn) heterometallic-(perfluorinated) organic frameworks containing inorganic layered KâOâM linkages: synthesis, crystal structure, and magnetic properties
Influence of annealing on magnesioferrite nanoparticles synthesized by a sol-gel/combustion method
Complexes of Iron(II) with silylated pentalene ligands; building blocks for homo- and heterobimetallics
A range of iron(II) complexes incorporating the silylated pentalene ligands (Pnâ H = 1,4-{SiiPr3}2C8H5 and Pnâ = 1,4-{SiiPr3}2C8H4) have been investigated as model molecules/building blocks for metallocene-based polymers. Six complexes have been synthesised and extensively characterised by a range of techniques, including by cyclic voltammetry and X-ray diffraction studies. Amongst these compounds are the homobimetallic [CpâFe]2(ÎŒ-Pnâ ) which is a fused analogue of biferrocene, and the 3d/4s heterobimetallic [CpâFe(η5-Pnâ )][K] which forms an organometallic polymer in the solid state. DFT calculations on model mono-Fe(η5-Pn) compounds reveal the charge densities on the uncoordinated carbon atoms of the pentalene ligand, and hence the potential for incorporating these units into heteronuclear bimetallic complexes is assessed
Synthesis, Structure, and Bonding of Sc4MgxCu15-xGa~7.5 (x = 0, 0.5). Two Incommensurately Modulated Scandium Substitution Derivatives of Cubic Mg2Cu6Ga5
Preparation of UF4 by Carbochlorination of U3O8 and Solid-State Halogen Exchange Reaction
Synthesis, Crystal Structure and Catalytic Property of an Oxovanadium(V) Complex Derived from N'
Synthesis, Crystal Structure and Sulfoxidation of an Iron(III) Complex Derived From 3-Methoxysalicylaldehyde
Ring opening polymerization and copolymerization of Lâlactide and Éâcaprolactone by bis
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