Towards finite-dimensional gelation

We consider the gelation of particles which are permanently connected by random crosslinks, drawn from an ensemble of finite-dimensional continuum percolation. To average over the randomness, we apply the replica trick, and interpret the replicated and crosslink-averaged model as an effective molecular fluid. A Mayer-cluster expansion for moments of the local static density fluctuations is set up. The simplest non-trivial contribution to this series leads back to mean-field theory. The central quantity of mean-field theory is the distribution of localization lengths, which we compute for all connectivities. The highly crosslinked gel is characterized by a one-to-one correspondence of connectivity and localization length. Taking into account higher contributions in the Mayer-cluster expansion, systematic corrections to mean-field can be included. The sol-gel transition shifts to a higher number of crosslinks per particle, as more compact structures are favored. The critical behavior of the model remains unchanged as long as finite truncations of the cluster expansion are considered. To complete the picture, we also discuss various geometrical properties of the crosslink network, e.g. connectivity correlations, and relate the studied crosslink ensemble to a wider class of ensembles, including the Deam-Edwards distribution.Comment: 18 pages, 4 figures, version to be published in EPJ

Lowest Landau level broadened by a Gaussian random potential with an arbitrary correlation length: An efficient continued-fraction approach

For an electron in the plane subjected to a perpendicular constant magnetic field and a homogeneous Gaussian random potential with a Gau{ss}ian covariance function we approximate the averaged density of states restricted to the lowest Landau level. To this end, we extrapolate the first 9 coefficients of the underlying continued fraction consistently with the coefficients' high-order asymptotics. We thus achieve the first reliable extension of Wegner's exact result [Z. Phys. B {\bf 51}, 279 (1983)] for the delta-correlated case to the physically more relevant case of a non-zero correlation length.Comment: 9 pages ReVTeX, three figure

The Fate of Lifshitz Tails in Magnetic Fields

We investigate the integrated density of states of the Schr\"odinger operator in the Euclidean plane with a perpendicular constant magnetic field and a random potential. For a Poisson random potential with a non-negative algebraically decaying single-impurity potential we prove that the leading asymptotic behaviour for small energies is always given by the corresponding classical result in contrast to the case of vanishing magnetic field. We also show that the integrated density of states of the operator restricted to the eigenspace of any Landau level exhibits the same behaviour. For the lowest Landau level, this is in sharp contrast to the case of a Poisson random potential with a delta-function impurity potential.Comment: 19 pages LaTe

Saddles on the potential energy landscape of a Lennard-Jones liquid

By means of molecular dynamics simulations, we study the stationary points of the potential energy in a Lennard-Jones liquid, giving a purely geometric characterization of the energy landscape of the system. We find a linear relation between the degree of instability of the stationary points and their potential energy, and we locate the energy where the instability vanishes. This threshold energy marks the border between saddle-dominated and minima-dominated regions of the energy landscape. The temperature where the potential energy of the Stillinger-Weber minima becomes equal to the threshold energy turns out to be very close to the mode-coupling transition temperature.Comment: Invited talk presented by A.C. at the Conference: Disordered and Complex Systems, King's College London, July 200

Anomalous stress relaxation in random macromolecular networks

Within the framework of a simple Rouse-type model we present exact analytical results for dynamical critical behaviour on the sol side of the gelation transition. The stress-relaxation function is shown to exhibit a stretched-exponential long-time decay. The divergence of the static shear viscosity is governed by the critical exponent $k=\phi -\beta$, where $\phi$ is the (first) crossover exponent of random resistor networks, and $\beta$ is the critical exponent for the gel fraction. We also derive new results on the behaviour of normal stress coefficients.Comment: 13 pages, 6 figures; contribution to the proceedings of the Minerva International Workshop on Frontiers In The Physics Of Complex Systems (25-28 March 2001) - to appear in a special issue of Physica

Continuous integral kernels for unbounded Schroedinger semigroups and their spectral projections

By suitably extending a Feynman-Kac formula of Simon [Canadian Math. Soc. Conf. Proc, 28 (2000), 317-321], we study one-parameter semigroups generated by (the negative of) rather general Schroedinger operators, which may be unbounded from below and include a magnetic vector potential. In particular, a common domain of essential self-adjointness for such a semigroup is specified. Moreover, each member of the semigroup is proven to be a maximal Carleman operator with a continuous integral kernel given by a Brownian-bridge expectation. The results are used to show that the spectral projections of the generating Schroedinger operator also act as Carleman operators with continuous integral kernels. Applications to Schroedinger operators with rather general random scalar potentials include a rigorous justification of an integral-kernel representation of their integrated density of states - a relation frequently used in the physics literature on disordered solids.Comment: 41 pages. Final version. Dedicated to Volker Enss on the occasion of his 60th birthda