5 research outputs found
Three new infrared bands of the He-OCS complex
Three new infrared bands of the weakly-bound He-OCS complex are studied,
using tunable lasers to probe a pulsed supersonic slit jet expansion. They
correspond to the (0400) <-- (0000), (1001)<-- (0000), and (0401) <-- (0000)
transitions of OCS at 2105, 2918, and 2937 cm-1, respectively. The latter band
is about 7900 times weaker than the previously studied OCS nu1 fundamental.
Vibrational shifts relative to the free OCS monomer are found to be additive.
Since carbonyl sulfide has previously been shown to be a valuable probe of
superfluid quantum solvation effects in helium clusters and droplets, the
present results could be useful for future studies of vibrational effects in
such systems.Comment: 16 pages, 1 figure, 4 table