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Vanadium (β-(Dimethylamino)ethyl)cyclopentadienyl Complexes with Diphenylacetylene Ligands

Reduction of the V(III) (β-(dimethylamino)ethyl)cyclopentadienyl dichloride complex [η5:η1-C5H4(CH2)2NMe2]VCl2(PMe3) with 1 equiv of Na/Hg yielded the V(II) dimer {[η5:η1-C5H4(CH2)2NMe2]V(µ-Cl)}2 (2). This compound reacted with diphenylacetylene in THF to give the V(II) alkyne adduct [η5:η1-C5H4(CH2)2NMe2]VCl(η2-PhC≡CPh). Further reduction of 2 with Mg in the presence of diphenylacetylene resulted in oxidative coupling of two diphenylacetylene groups to yield the diamagnetic, formally V(V), bent metallacyclopentatriene complex [η5:η1-C5H4(CH2)2NMe2]V(C4Ph4).

Proceedings - University of Groningen

University of Groningen

ARTS repository - University of Groningen

University of Groningen Digital Archive

Dissertations of the University of Groningen

Nickel-Triflate Complexes as Precursors to Reactive Cations: Preparation and Reactivities of (1-R-indenyl)Ni(PPh 3

Author: Alias F. M.
Bayrakdarian M.
Bianchini C.
Bosnich B.
Braun T.
Braun T.
Britovesk G. J. P.
Drent E.
Dubois M.-A.
Dubuc I.
Eisch J. J.
Fontaine F.-G.
Fontaine F.-G.
Gottfried A. C.
Groux L. G.
Hermans J. P.
Hlatky G. G.
Huber T. A.
Huber T. A.
Ittel S. D.
Johnson L. K.
Jordan R. F.
Jordan R. F.
Jordan R. F.
Lawrance G. A.
Liaw W.
Mathew J. P.
Mecking S.
Park J.
PhSi
Schneider J. J.
Sen A.
Sen A.
Sheldrick G. M. SHELXL
Sheldrick G. M. SHELXS
Suzuki K.
Svejda S. A.
The
Treichel P. M.
Two
Vollmerhaus R.
Wang R.
Wang R.
Zargarian D.
Publication venue: 'American Chemical Society (ACS)'
Publication date
Field of study

Diamido-Ether Uranium(IV) Alkyl Complexes as Single-Component Ethylene Polymerization Catalysts

Coordination Chemistry of Silanedithiolato Ligands Derived from Cyclotrisilathiane: Synthesis and Structures of Complexes of Iron(II), Cobalt(II), Palladium(II), Copper(I), and Silver(I)

Ethylene Homopolymerization and Copolymerization with Functionalized 5-Norbornen-2-yl Monomers by a Novel Nickel Catalyst System

Author: Baek K.-Y.
Barnhart R. W.
Bauers F. M.
Bauers F. M.
Bazan G. C.
Benedikt G. M.
Blom R.
Boone H. W.
Breunig S.
Britovesk G. J. P.
Britovsek G. P. J.
Coates G. W.
Connor E. F.
Deming T. J.
Deng L.
Deng L.
Doi Y.
Doi Y.
Drent E.
For
For
For
For
Fukui Y.
Fukui Y.
Gibson V. C.
Gold L.
Goodall B. L.
Gottfried A. C.
Guan Z.
Hadjichristidis N.
Hagihara H.
Hasan T.
Heinicke J.
Held A.
Held A.
Hicks F. A.
Jayaratne K. C.
Jeon Y. M.
Johnson L. K.
Johnson L. K.
Keaton R. J.
Kennedy J. P.
Killian C. M.
Komon Z. J. A.
Komon Z. J. A.
Komon Z. J. A.
Lee B. Y.
Liu W.
Lou X.
Matthew J. P.
Matyjaszewski K.
Matyjaszewski K.
Mecking S.
Mehler C.
Mitani M.
Morton M.
Prabhu P.
Quirk R.
Quirk R. P.
Rieger B.
Schmid M.
Schrock R. R.
Schröder D. L.
Simms J. A.
Small B. L.
Stenzel-Rosenbaum M.
Svejda S. A.
Szwarc M.
Szwarc M.
Tshuva E. Y.
Wang C.
We
Yoshida Y.
Younkin T. R.
Publication venue: 'American Chemical Society (ACS)'
Publication date
Field of study

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