16 research outputs found
A DFT based investigation into the electronic structure and properties of hydride rich rhodium clusters
CâC Ď complexes of rhodium
In this article, the complexes [Rh(Binor-Sâ˛)(PR(3))][BAr(4)(F)] (R = (i)Pr, Cy, C(5)H(9)) are described. A combination of x-ray crystallography, NMR spectroscopy, density functional theory, and âatoms in moleculesâ calculations unequivocally demonstrates that the complexes contain rare examples of metal¡¡¡C [Image: see text] C agostic interactions. Moreover, they are fluxional on the NMR time scale, undergoing rapid and reversible C [Image: see text] C activation. Kinetic data and calculations point to a bismetallacyclobutane, Rh(V), intermediate
Experimental charge density study into CâC Ď-interactions in a Binor-S rhodium complex
Transition-metal complexes containing (CâC)âM s-interactions have potential applications in both
catalysis and the activation and cleavage of CâC bonds. Fully characterising the bonding and
interactions in complexes containing such (CâC)âM s-interactions is vital to understand their
chemical behaviour. As a result a high-resolution experimental X-ray charge density study has been
undertaken on [Rh(Binor-S)(PCy3)][HCB11Me11] (Binor-S = 1,2,4,5,6,8-dimetheno-s-indacene) which
contains a (CâC)âRh interaction. The data are analysed using Baderâs âAtoms in Moleculesâ (AIM)
approach with particular attention paid to the interactions around the rhodium centre. The results
provide clear evidence for the s(CâC)âRh interaction in the solid-state which is classified as a weak
covalent interaction. These results are supported by theoretical calculations
High hydride count rhodium octahedra, Rh-6(PR3)(6)H-12 BAr4F (2): Synthesis, structures, and reversible hydrogen uptake under mild conditions
CCDC 275849: Experimental Crystal Structure Determination
An entry from the Cambridge Structural Database, the worldâs repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures
CCDC 603488: Experimental Crystal Structure Determination
An entry from the Cambridge Structural Database, the worldâs repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures
CCDC 603491: Experimental Crystal Structure Determination
An entry from the Cambridge Structural Database, the worldâs repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures
CCDC 603489: Experimental Crystal Structure Determination
An entry from the Cambridge Structural Database, the worldâs repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures
CCDC 652793: Experimental Crystal Structure Determination
An entry from the Cambridge Structural Database, the worldâs repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures
CCDC 652792: Experimental Crystal Structure Determination
An entry from the Cambridge Structural Database, the worldâs repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures