Corrections to Scaling in the Phase-Ordering Dynamics of a Vector Order Parameter

Corrections to scaling, associated with deviations of the order parameter from the scaling morphology in the initial state, are studied for systems with O(n) symmetry at zero temperature in phase-ordering kinetics. Including corrections to scaling, the equal-time pair correlation function has the form C(r,t) = f_0(r/L) + L^{-omega} f_1(r/L) + ..., where L is the coarsening length scale. The correction-to-scaling exponent, omega, and the correction-to-scaling function, f_1(x), are calculated for both nonconserved and conserved order parameter systems using the approximate Gaussian closure theory of Mazenko. In general, omega is a non-trivial exponent which depends on both the dimensionality, d, of the system and the number of components, n, of the order parameter. Corrections to scaling are also calculated for the nonconserved 1-d XY model, where an exact solution is possible.Comment: REVTeX, 20 pages, 2 figure

Growth Laws for Phase Ordering

We determine the characteristic length scale, $L(t)$, in phase ordering kinetics for both scalar and vector fields, with either short- or long-range interactions, and with or without conservation laws. We obtain $L(t)$ consistently by comparing the global rate of energy change to the energy dissipation from the local evolution of the order parameter. We derive growth laws for O(n) models, and our results can be applied to other systems with similar defect structures.Comment: 12 pages, LaTeX, second tr

Corrections to Scaling in Phase-Ordering Kinetics

The leading correction to scaling associated with departures of the initial condition from the scaling morphology is determined for some soluble models of phase-ordering kinetics. The result for the pair correlation function has the form C(r,t) = f_0(r/L) + L^{-\omega} f_1(r/L) + ..., where L is a characteristic length scale extracted from the energy. The correction-to-scaling exponent \omega has the value \omega=4 for the d=1 Glauber model, the n-vector model with n=\infty, and the approximate theory of Ohta, Jasnow and Kawasaki. For the approximate Mazenko theory, however, \omega has a non-trivial value: omega = 3.8836... for d=2, and \omega = 3.9030... for d=3. The correction-to-scaling functions f_1(x) are also calculated.Comment: REVTEX, 7 pages, two figures, needs epsf.sty and multicol.st

Persistence in systems with algebraic interaction

Persistence in coarsening 1D spin systems with a power law interaction $r^{-1-\sigma}$ is considered. Numerical studies indicate that for sufficiently large values of the interaction exponent $\sigma$ ($\sigma\geq 1/2$ in our simulations), persistence decays as an algebraic function of the length scale $L$, $P(L)\sim L^{-\theta}$. The Persistence exponent $\theta$ is found to be independent on the force exponent $\sigma$ and close to its value for the extremal ($\sigma \to \infty$) model, $\bar\theta=0.17507588...$. For smaller values of the force exponent ($\sigma< 1/2$), finite size effects prevent the system from reaching the asymptotic regime. Scaling arguments suggest that in order to avoid significant boundary effects for small $\sigma$, the system size should grow as ${[{\cal O}(1/\sigma)]}^{1/\sigma}$.Comment: 4 pages 4 figure

Commensurate Fluctuations in the Pseudogap and Incommensurate spin-Peierls Phases of TiOCl

X-ray scattering measurements on single crystals of TiOCl reveal the presence of commensurate dimerization peaks within both the incommensurate spin-Peierls phase and the so-called pseudogap phase above T_c2. This scattering is relatively narrow in Q-space indicating long correlation lengths exceeding ~ 100 A below T* ~ 130 K. It is also slightly shifted in Q relative to that of the commensurate long range ordered state at the lowest temperatures, and it coexists with the incommensurate Bragg peaks below T_c2. The integrated scattering over both commensurate and incommensurate positions evolves continuously with decreasing temperature for all temperatures below T* ~ 130 K.Comment: To appear in Physical Review B: Rapid Communications. 5 page

Comment on ``Theory of Spinodal Decomposition''

I comment on a paper by S. B. Goryachev [PRL vol 72, p.1850 (1994)] that presents a theory of non-equilibrium dynamics for scalar systems quenched into an ordered phase. Goryachev incorrectly applies only a global conservation constraint to systems with local conservation laws.Comment: 2 pages LATeX (REVTeX macros), no figures. REVISIONS --- more to the point. microscopic example added, presentation streamlined, long-range interactions mentioned, to be published in Phys. Rev. Let

Suppression of the commensurate spin-Peierls state in Sc-doped TiOCl

We have performed x-ray scattering measurements on single crystals of the doped spin-Peierls compound Ti(1-x)Sc(x)OCl (x = 0, 0.01, 0.03). These measurements reveal that the presence of non-magnetic dopants has a profound effect on the unconventional spin-Peierls behavior of this system, even at concentrations as low as 1%. Sc-doping suppresses commensurate fluctuations in the pseudogap and incommensurate spin-Peierls phases of TiOCl, and prevents the formation of a long-range ordered spin-Peierls state. Broad incommensurate scattering develops in the doped compounds near Tc2 ~ 93 K, and persists down to base temperature (~ 7 K) with no evidence of a lock-in transition. The width of the incommensurate dimerization peaks indicates short correlation lengths on the order of ~ 12 angstroms below Tc2. The intensity of the incommensurate scattering is significantly reduced at higher Sc concentrations, indicating that the size of the associated lattice displacement decreases rapidly as a function of doping.Comment: 7 pages, 5 figure