What is semiquantum mechanics?

Semiclassical approximations to quantum dynamics are almost as old as quantum mechanics itself. In the approach pioneered by Wigner, the evolution of his quasiprobability density function on phase space is expressed as an asymptotic series in increasing powers of Planck's constant, with the classical Liouvillean evolution as leading term. Successive semiclassical approximations to quantum dynamics are defined by successive terms in the series. We consider a complementary approach, which explores the quantum-clssical interface from the other direction. Classical dynamics is formulated in Hilbert space, with the Groenewold quasidensity operator as the image of the Liouville density on phase space. The evolution of the Groenewold operator is then expressed as an asymptotic series in increasing powers of Planck's constant. Successive semiquantum approximations to classical dynamics are defined by successive terms in this series, with the familiar quantum evolution as leading term.Comment: Talk presented at IVth International Symposium on Quantum Theory and Symmetries, Varna, August, 2005. 13 pages, 4 figure

Differential equations of electrodiffusion: constant field solutions, uniqueness, and new formulas of Goldman-Hodgkin-Katz type

The equations governing one-dimensional, steady-state electrodiffusion are considered when there are arbitrarily many mobile ionic species present, in any number of valence classes, possibly also with a uniform distribution of fixed charges. Exact constant field solutions and new formulas of Goldman-Hodgkin-Katz type are found. All of these formulas are exact, unlike the usual approximate ones. Corresponding boundary conditions on the ionic concentrations are identified. The question of uniqueness of constant field solutions with such boundary conditions is considered, and is re-posed in terms of an autonomous ordinary differential equation of order $n+1$ for the electric field, where $n$ is the number of valence classes. When there are no fixed charges, the equation can be integrated once to give the non-autonomous equation of order $n$ considered previously in the literature including, in the case $n=2$, the form of Painlev\'e's second equation considered first in the context of electrodiffusion by one of us. When $n=1$, the new equation is a form of Li\'enard's equation. Uniqueness of the constant field solution is established in this case.Comment: 29 pages, 5 figure

Airy series solution of Painlev\'e II in electrodiffusion: conjectured convergence

A perturbation series solution is constructed in terms of Airy functions for a nonlinear two-point boundary-value problem arising in an established model of steady electrodiffusion in one dimension, for two ionic species carrying equal and opposite charges. The solution includes a formal determination of the associated electric field, which is known to satisfy a form of the Painlev\'e II differential equation. Comparisons with the numerical solution of the boundary-value problem show excellent agreement following termination of the series after a sufficient number of terms, for a much wider range of values of the parameters in the model than suggested by previously presented analysis, or admitted by previously presented approximation schemes. These surprising results suggest that for a wide variety of cases, a convergent series expansion is obtained in terms of Airy functions for the Painlev\'e transcendent describing the electric field. A suitable weighting of error measures for the approximations to the field and its first derivative provides a monotonically decreasing overall measure of the error in a subset of these cases. It is conjectured that the series does converge for this subset.Comment: 30 pages, 9 figures. Typos corrected, figures modified, extra references adde

Non-positivity of Groenewold operators

A central feature in the Hilbert space formulation of classical mechanics is the quantisation of classical Liouville densities, leading to what may be termed term Groenewold operators. We investigate the spectra of the Groenewold operators that correspond to Gaussian and to certain uniform Liouville densities. We show that when the classical coordinate-momentum uncertainty product falls below Heisenberg's limit, the Groenewold operators in the Gaussian case develop negative eigenvalues and eigenvalues larger than 1. However, in the uniform case, negative eigenvalues are shown to persist for arbitrarily large values of the classical uncertainty product.Comment: 9 pages, 1 figures, submitted to Europhysics Letter

Localizing the Relativistic Electron

A causally well-behaved solution of the localization problem for the free electron is given, with natural space-time transformation properties, in terms of Dirac's position operator. It is shown that, although this operator does not represent an observable in the usual sense, and has no positive-energy (generalized) eigenstates, the associated 4-vector density is observable, and can be localized arbitrarily precisely about any point in space, at any instant of time, using only positive-energy states. A suitable spin operator can be diagonalized at the same time.Comment: 19 pages including 1 figure (1 LatTex2e file, 1 postscript file). Uses package amssymb. Typos correcte

Quantum symmetries and the Weyl-Wigner product of group representations

In the usual formulation of quantum mechanics, groups of automorphisms of quantum states have ray representations by unitary and antiunitary operators on complex Hilbert space, in accordance with Wigner's Theorem. In the phase-space formulation, they have real, true unitary representations in the space of square-integrable functions on phase-space. Each such phase-space representation is a Weyl-Wigner product of the corresponding Hilbert space representation with its contragredient, and these can be recovered by `factorising' the Weyl-Wigner product. However, not every real, unitary representation on phase-space corresponds to a group of automorphisms, so not every such representation is in the form of a Weyl-Wigner product and can be factorised. The conditions under which this is possible are examined. Examples are presented.Comment: Latex2e file, 37 page

Non-positivity of the Wigner function and bounds on associated integrals

The Wigner function shares several properties with classical distribution functions on phase space, but is not positive-definite. The integral of the Wigner function over a given region of phase space can therefore lie outside the interval [0,1]. The problem of finding best-possible upper and lower bounds for a given region is the problem of finding the greatest and least eigenvalues of an associated Hermitian operator. Exactly solvable examples are described, and possible extensions are indicated.Comment: 5 pages, Latex2e fil